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相关论文: Electronic-vibrational dynamics and coherence in x…

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Probing vibronic coherence in molecules has been a central topic in ultrafast science, as it is an essential prerequisite to monitoring electronic motion. While experiments have demonstrated that attosecond transient absorption spectroscopy…

原子物理 · 物理学 2023-08-02 C. H. Yuen , C. D. Lin

Tracing ultrafast processes induced by interaction of light with matter is often very challenging. In molecular systems, the initially created electronic coherence becomes damped by the slow nuclear rearrangement on a femtosecond timescale…

化学物理 · 物理学 2021-09-20 Nikolay V. Golubev , Jiří Vaníček , Alexander I. Kuleff

Attosecond transient absorption spectroscopy (ATAS) has emerged as a powerful technique within the field of attosecond science, combining extremely high temporal and excellent spectral resolution. So far, ATAS has been implemented in…

Transient absorption is a very powerful observable in attosecond experiments on atoms, molecules and solids and is frequently used in experiments employing phase-locked few-cycle infrared and XUV laser pulses derived from high harmonic…

原子物理 · 物理学 2020-08-26 Lorenz Drescher , Marc J. J. Vrakking , Jochen Mikosch

Photoinduced quantum dynamics in molecules have hierarchical temporal structures with different energy scales that are associated with electron and nuclear motions. Femtosecond-to-attosecond transient absorption spectroscopy (TAS) using…

Attosecond transient-absorption spectroscopy (ATAS) is an established method for exploring electron dynamics on the subfemtosecond time-scale. ATAS spectra contain certain ubiquitous features, such as oscillating fringes, light-induced…

原子物理 · 物理学 2017-08-02 Jørgen Johansen Rørstad , Jens E. Bækhøj , Lars Bojer Madsen

We investigate theoretically charge migration following prompt double ionization of a polyatomic molecule (C$_2$H$_4$BrI) and find that for double ionization, correlation-driven charge migration appears to be particularly prominent, i.e.,…

化学物理 · 物理学 2016-05-24 Maximilian Hollstein , Robin Santra , Daniela Pfannkuche

We investigate the ultrafast electron dynamics of a model of a wide-bandgap material with inner, valence, and conduction bands excited by an intense few-femtosecond pump and monitored by a delayed attosecond extreme-ultraviolet probe pulse.…

光学 · 物理学 2026-05-08 Stefano M. Cavaletto , Lars Bojer Madsen

Ultrafast laser excitation can trigger multiplex coherent dynamics in molecules. Here, we report attosecond transient absorption experiments addressing simultaneous probing of electronic and vibrational dynamics in a prototype molecule,…

We apply attosecond transient absorption spectroscopy (ATAS) to explore the effects of a nonzero permanent dipole on electron dynamics at the subfemtosecond scale, exemplified in the polar LiF molecule. In contrast with nonpolar systems, a…

原子物理 · 物理学 2018-11-14 Jørgen Johansen Rørstad , Nikolaj S. W. Ravn , Lun Yue , Lars Bojer Madsen

A coherent vibrational wavepacket is launched and manipulated in the symmetric stretch (a$_1$) mode of CBr$_4$, by impulsive stimulated Raman scattering from non-resonant 400 nm laser pump pulses with various peak intensities on the order…

Above-threshold ionization (ATI) is a strong-field-driven process where electrons absorb more photons than required for ionization. While ATI dynamics and outputs are well-understood when driven by classical, perfectly coherent light, the…

量子物理 · 物理学 2025-08-14 J. Rivera-Dean , P. Stammer , C. Figueira de Morisson Faria , M. Lewenstein

We investigate the time-dependent evolution of the dipole phase shift induced by strong-field ionization (SFI) using attosecond transient absorption spectroscopy (ATAS) for time-delays where the pump-probe pulses overlap. We study measured…

The electronic excitation occurring on adsorbates at ultrafast time scales from optical lasers that initiate surface chemical reactions is still an open question. Here, we report the ultrafast temporal evolution of X-ray absorption…

Air-lasing from single ionized N$_2^+$ molecules induced by laser filamentation in air has been intensively investigated and the mechanisms responsible for lasing are currently highly debated. We use ultrafast nitrogen K-edge spectroscopy…

We report on the observation, characterization, and control of the electron dynamics in ionized argon atoms. We utilized an intense mid-infrared (MIR) pulse to create a coherent superposition of the spin-orbit split ground state of the ion.…

Above-threshold ionization (ATI) results from strong field laser-matter interaction and it is one of the fundamental processes that may be used to extract electron structural and dynamical information about the atomic or molecular target.…

原子物理 · 物理学 2016-01-06 Noslen Suárez , Alexis Chacón , Marcelo Ciappina , Jens Biegert , Maciej Lewenstein

Ultrafast laser excitation can create coherent superpositions of electronic states in molecules and trigger ultrafast flow of electron density on few- to sub-femtosecond time scales. While recent attosecond experiments have addressed…

化学物理 · 物理学 2020-11-18 Yuki Kobayashi , Daniel M. Neumark , Stephen R. Leone

Quantum coherence in quantum optics is an essential part of optical information processing and light manipulation. Alkali metal vapors, despite the numerous shortcomings, are traditionally used in quantum optics as a working medium due to…

This article presents a study of the excited state relaxation dynamics of N-salycylidene-o-aminophenol (SOAP) in ethanol solution. Femtosecond transient absorption (TA) spectroscopy and theoretical calculations are used in combination to…

化学物理 · 物理学 2021-12-13 Nikolai Petkov , Anela Ivanova , Anton Trifonov , Ivan Buchvarov , Stanislav Stanimirov
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