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We report, for the first time, some experimental observations regarding a new type of long range interaction between rigid particles that prevails when they are suspended in an soft elastic gel. A denser particle submerges itself to a…

软凝聚态物质 · 物理学 2014-01-29 Aditi Chakrabarti , Manoj K. Chaudhury

Ionic microgels are soft colloidal particles, composed of crosslinked polymer networks, that ionize and swell when dispersed in a good solvent. Swelling of these permeable, compressible particles involves a balance of electrostatic,…

软凝聚态物质 · 物理学 2020-01-29 Alan R. Denton , Mohammed O. Alziyadi

When sheared, most elastic solids such as metals, rubbers and polymer hydrogels dilate in the direction perpendicular to the shear plane. This well-known behaviour known as the Poynting effect is characterized by a positive normal stress.…

A theoretical model of electromigrative, diffusive and convectivetransport polymer-gel composites is presented. Bulk properties are derived from the standard electrokinetic model with an impenetrable charged sphere embedded in an…

软凝聚态物质 · 物理学 2007-05-23 Reghan J. Hill

The functionality of adhesives relies on their response under the application of a load. Yet, it has remained a challenge to quantitatively relate the macroscopic dynamics of peeling to the dissipative processes inside the adhesive layer.…

软凝聚态物质 · 物理学 2019-09-04 Hugo Perrin , Antonin Eddi , Stefan Karpitschka , Jacco H. Snoeijer , Bruno Andreotti

We report an experimental study on the manipulation of colloidal particles in a drop sitting on a hydrogel. The manipulation is achieved by diffusiophoresis, which describes a directed motion of particles induced by solute gradients. By…

软凝聚态物质 · 物理学 2017-10-17 François Boulogne , Sangwoo Shin , Julien Dervaux , Laurent Limat , Howard A. Stone

Hydrogels have had a profound impact in the fields of tissue engineering, drug delivery, and materials science as a whole. Due to the network architecture of these materials, imbibement with water often results in uniform swelling and…

Electro- and diffusio- phoresis of particles correspond respectively to the transport of particles under electric field and solute concentration gradients. Such interfacial transport phenomena take their origin in a diffuse layer close to…

软凝聚态物质 · 物理学 2020-04-22 Sophie Marbach , Hiroaki Yoshida , Lydéric Bocquet

Current theories of diffusiophoresis in porous media are limited to a porous medium saturated with a valence symmetric electrolyte. A predictive model for diffusiophoresis in porous media saturated with a valence asymmetric electrolyte, or…

软凝聚态物质 · 物理学 2024-12-03 Siddharth Sambamoorthy , Henry C. W. Chu

In the classic theory of solid adhesion, surface energy drives deformation to increase contact area while bulk elasticity opposes it. Recently, solid surface stress has been shown also to play an important role in opposing deformation of…

软凝聚态物质 · 物理学 2016-02-17 K. E. Jensen , R. Sarfati , R. W. Style , R. Boltyanskiy , A. Chakrabarti , M. K. Chaudhury , E. R. Dufresne

Porous gels -- gels with solvent-filled pores that are much larger than their mesh size -- are widely used in engineering and biomedical applications due to their tunable mechanics, high water content, and selective permeability. Among…

软凝聚态物质 · 物理学 2025-08-22 Yanxia Feng , Noel Ringeisen , Eric R. Dufresne , Lucio Isa , Robert W. Style

Ionic microcapsules are hollow shells of hydrogel, typically 10-1000 nm in radius, composed of cross-linked polymer networks that become charged and swollen in a good solvent. The ability of microcapsules to swell/deswell in response to…

软凝聚态物质 · 物理学 2023-12-18 Mohammed O. Alziyadi , Alan R. Denton

Tissues are subjected to large external forces and undergo global deformations during morphogenesis. We use synthetic analogues of tissues to study the impact of cell-cell adhesion on the response of cohesive cellular assemblies under such…

We report contactless measurements of the viscoelastic rheological properties of soft gels. The experiments are performed using a colloidal-probe Atomic Force Microscope (AFM) in a liquid environment and in dynamic mode. The mechanical…

We study the electrophoretic flow of suspensions of charged colloids with a mesoscopic method that allows to model generic experimental conditions. We show that for highly charged colloids their electrophoretic mobility increases…

软凝聚态物质 · 物理学 2015-05-28 Giovanni Giupponi , Ignacio Pagonabarraga

Historical monuments, outdoor stone sculptures and artworks made of porous materials are exposed to chemical and physical degradation over time. Presently, the most promising route for consolidation of weakened porous materials is the…

We make use of continuum elasticity theory to investigate the collective modes that propagate along the edge of a two-dimensional electron liquid or crystal in a magnetic field. An exact solution of the equations of motion is obtained with…

介观与纳米尺度物理 · 物理学 2009-10-31 Irene D'Amico , Giovanni Vignale

We propose and analyze a mathematical model of the mechanics of gels, consisting of the laws of balance of mass and linear momentum. We consider a gel to be an immiscible and incompressible mixture of a nonlinearly elastic polymer and a…

偏微分方程分析 · 数学 2012-10-17 Brandon Chabaud , Maria-Carme Calderer

Hydrogel consists of a crosslinked polymer matrix imbibed with a solvent such as water at volume fractions that can exceed 90\%. They are important in many scientific and engineering applications due to their tunable physiochemical…

软凝聚态物质 · 物理学 2020-06-11 Nicholas L. Cuccia , Suraj Pothineni , Brady Wu , Joshua Méndez-Harper , Justin C. Burton

Polymer gels are comprised of a three-dimensional, cross-linked network that can typically withstand the mechanical deformation associated with both swelling and de-swelling. Thus, gels can be designed with smart behaviors that require both…

软凝聚态物质 · 物理学 2024-06-24 Alyssa VanZanten , Shih-Yuan Chen , Michelle M. Driscoll , Caroline R. Szczepanski