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The photovoltaic reciprocity theory relates the electroluminescence spectrum of a solar cell under applied bias to the external photovoltaic quantum efficiency of the device as measured at short circuit conditions. Its derivation is based…

介观与纳米尺度物理 · 物理学 2017-06-21 Urs Aeberhard , Uwe Rau

Edge shunts are among the main factors causing reduction in solar cell open circuit voltage that is why their isolation is one of the main steps in solar cell manufacturing. Many techniques have been employed to achieve this goal, e.g.…

其他凝聚态物理 · 物理学 2007-08-31 I. M. Hamammu , K. Ibrahim

Radiative and non-radiative charge carrier recombination in thin-film diodes plays a key role in determining the efficiency of electronic devices made of next generation semiconductors such as organic, perovskite and nanocrystals. In this…

应用物理 · 物理学 2019-08-06 Oskar J. Sandberg , Ardalan Armin

We develop a new approach to calculate the obtainable limit of photoconversion efficiency of tandem solar cells (SCs) and applied it to SCs with both vertical and lateral designs at AM0 and AM1.5 conditions. To get the maximum efficiency,…

材料科学 · 物理学 2013-09-13 A. V. Sachenko , V. P. Kostylyov , N. P. Kulish , I. O. Sokolovskyi , A. I. Shkrebtii

The charge carrier dynamics of organic solar cells are strongly influenced by trapping and allow to draw conclusions on the loss mechanisms limiting the photovoltaic performance. In this study we derive the recombination order \Delta\ of…

材料科学 · 物理学 2013-07-26 Carsten Deibel , Daniel Rauh , Alexander Foertig

The open circuit voltage Voc and the corresponding charge carrier density were measured in dependence of temperature and illumination intensity by current-voltage and charge extraction measurements for P3HT:PCBM and P3HT:bisPCBM solar…

材料科学 · 物理学 2011-10-05 Daniel Rauh , Alexander Wagenpfahl , Carsten Deibel , Vladimir Dyakonov

Transient photovoltage (TPV) and voltage dependent charge extraction (CE) measurements were applied to poly(3-hexylthiophene)(P3HT):[6,6]-phenyl-C61 butyric acid methyl ester (PCBM) bulk heterojunction solar cells to analyze the limitations…

材料科学 · 物理学 2012-08-23 Markus Gluecker , Alexander Foertig , Vladimir Dyakonov , Carsten Deibel

The radiative open circuit voltage loss in a solar cell occurs because the absorptance spectrum near the band gap shows gradual increase rather than sharp step function like transition. This broadening effect has been attributed to band gap…

One of the most significant features of lead-halide perovskites are their ability to have comparably slow recombination despite the fact that these materials are mostly processed from solution at room temperature. The slow recombination…

应用物理 · 物理学 2019-07-26 Thomas Kirchartz

Apparent recombination orders exceeding the value of two expected for bimolecular recombination have been reported for organic solar cells in various publications. Two prominent explanations are bimolecular losses with a carrier…

软凝聚态物质 · 物理学 2012-08-23 D. Rauh , C. Deibel , V. Dyakonov

With increasing penetrations of single-phase, rooftop solar PV installations, the relative variations in per-phase loading and associated voltage unbalance are expected to increase. High voltage unbalance may increase network losses and…

系统与控制 · 电气工程与系统科学 2020-04-23 Kshitij Girigoudar , Line A. Roald

State of the art organic solar cells exhibit power conversion efficiencies of 18 % and above. These devices benefit from the suppression of free charge recombination with regard to the Langevin-limit of charge encounter in a homogeneous…

应用物理 · 物理学 2021-12-24 Guangzheng Zuo , Safa Shoaee , Martijn Kemerink , Dieter Neher

Solar cells manufactured on top of Ge substrates suffer from inherent drawbacks that hinder or limit their potential. The most deleterious ones are heavy weight, high bulk recombination, lack of photon confinement and an increase of the…

应用物理 · 物理学 2020-06-29 Iván Lombardero , Mario Ochoa , Naoya Miyashita , Yoshitaka Okada , Carlos Algora

Recently, much effort has been devoted to improve the efficiency of organic photovoltaic solar cells based on blends of donors and acceptors molecules in bulk heterojunction architecture. One of the major losses in organic photovoltaic…

材料科学 · 物理学 2013-03-05 Ye Zhang , Tek P. Basel , Bhoj R. Gautam , Xiaomei Yang , Debra J. Mascaro , Feng Liu , Z. Valy Vardeny

In organic bulk heterojunction solar cells, the open circuit voltage ($V_\mathrm{oc}$) suffers from an ultra-high loss at low temperatures. In this work we investigate the origin of the loss through calculating the $V_\mathrm{oc}-T$ plots…

材料科学 · 物理学 2017-06-09 Wenchao Yang , Yongsong Luo , Pengfei Guo , Haibin Sun , Yao Yao

Conduction and valence band-edge-property variations with position as well as defects giving rise to localized states in the energy gap can play a significant role in determining solar cell performance. Understanding their effects on a…

应用物理 · 物理学 2019-08-15 Yiming Liu , Stephen Fonash

Electrical transients enabled by optical excitation and electric detection provide a distinctive opportunity to study the charge transport, recombination and even the hysteresis of a solar cell in a much wider time window ranging from…

Thin film polycrystalline photovoltaics are a mature, commercially-relevant technology. However, basic questions persist about the role of grain boundaries in the performance of these materials, and the extent to which these defects may…

材料科学 · 物理学 2019-02-12 Benoit Gaury , Paul M. Haney

A combination of transient photovoltage (TPV), voltage dependent charge extraction (CE) and time delayed collection field (TDCF) measurements is applied to poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl]…

应用物理 · 物理学 2021-06-21 A. Foertig , J. Kniepert , M. Gluecker , T. Brenner , V. Dyakonov , D. Neher , C. Deibel

Carrier recombination is a process that significantly influences the performance of semiconductor devices such as solar cells, photodiodes, and light-emitting diodes (LEDs). Therefore, a model that can accurately describe and quantify the…

应用物理 · 物理学 2022-04-11 M. L. Inche Ibrahim , Anvar A. Zakhidov