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Transient photovoltage (TPV) and voltage dependent charge extraction (CE) measurements were applied to poly(3-hexylthiophene)(P3HT):[6,6]-phenyl-C61 butyric acid methyl ester (PCBM) bulk heterojunction solar cells to analyze the limitations…

材料科学 · 物理学 2012-08-23 Markus Gluecker , Alexander Foertig , Vladimir Dyakonov , Carsten Deibel

Radiative and non-radiative charge carrier recombination in thin-film diodes plays a key role in determining the efficiency of electronic devices made of next generation semiconductors such as organic, perovskite and nanocrystals. In this…

应用物理 · 物理学 2019-08-06 Oskar J. Sandberg , Ardalan Armin

Zinc phosphide (Zn3P2) has had a long history of scientific interest largely because of its potential for earth-abundant photovoltaics. To realize high-efficiency Zn3P2 solar cells, it is critical to understand and control point defects in…

材料科学 · 物理学 2023-11-01 Zhenkun Yuan , Yihuang Xiong , Geoffroy Hautier

In this work an overall electronic structure including the position and formation energies of various intrinsic defects are computed for anatase using Density Functional Theory aided by Hubbard correction (DFT+U). The intrinsic point…

Note: This paper has been published in Physical Chemistry Chemical Physics, which can be viewed at the following URL: http://doi.org/10.1039/C5CP03102H Cs2SnI6, a rarely studied perovskite variant material, is recently gaining a lot of…

计算物理 · 物理学 2015-06-26 Zewen Xiao , Yuanyuan Zhou , Hideo Hosono , Toshio Kamiya

The presence of interface recombination in a complex multilayered thin-film solar structure causes a disparity between the internal open-circuit voltage (VOC,in), measured by photoluminescence, and the external open-circuit voltage (VOC,ex)…

The Shockley-Queisser (SQ) limit provides a convenient metric for predicting light-to-electricity conversion efficiency of a solar cell based on the band gap of the light-absorbing layer. In reality, few materials approach this radiative…

计算物理 · 物理学 2020-05-22 Sunghyun Kim , José A. Márquez , Thomas Unold , Aron Walsh

Recombination losses contribute to reduce $J_{SC}$, $V_{OC}$ and the fill factor of organic solar cells. Recent advances in non-fullerene organic photovoltaics have shown, nonetheless, that efficient charge generation can occur under small…

材料科学 · 物理学 2022-11-24 Artur M. Andermann , Luis G. C. Rego

We report on the role of plasmonic resonances in determining the delicate balance between scattering and absorption of light in nanometric particle arrays applied to the front surface of solar cells. Strong parasitic absorption is shown to…

The thermodynamic limit of photovoltaic efficiency for a single-junction solar cell can be readily predicted using the bandgap of the active light absorbing material. Such an approach overlooks the energy loss due to non-radiative…

应用物理 · 物理学 2021-06-21 Sunghyun Kim , Aron Walsh

The ability to absorb light is indispensable for high efficient solar power generation. This places conflicting requirements on the structure of a solar cell: On one hand, it needs to have thick active layers to absorb more of the available…

光学 · 物理学 2019-10-23 Ido Frenkel , Shilpi Shital , Avi Niv

Exposure to environmental factors is generally expected to cause degradation in perovskite films and solar cells. Herein, we show that films with certain defect profiles can display the opposite effect, healing upon exposure to oxygen under…

Due to their tailorable optical properties, organic semiconductors show considerable promise for use in indoor photovoltaics (IPVs), which present a sustainable route for powering ubiquitous "Internet-of-Things" devices in the coming…

Solar cells manufactured on top of Ge substrates suffer from inherent drawbacks that hinder or limit their potential. The most deleterious ones are heavy weight, high bulk recombination, lack of photon confinement and an increase of the…

应用物理 · 物理学 2020-06-29 Iván Lombardero , Mario Ochoa , Naoya Miyashita , Yoshitaka Okada , Carlos Algora

The improvement of light absorption in Si/BeSe$_{0.41}$Te$_{0.59}$ heterostructures for solar cell applications is studied theoretically. First, using simple approaches we found that light absorption could be improved in a single…

介观与纳米尺度物理 · 物理学 2007-05-23 T. Sandu , W. P. Kirk

Organic solar cells (OSCs) are uniquely suited for semitransparent applications due to their adjustable absorption spectrum. However, most high-performance semitransparent cells reported to date are based on materials that have shown high…

Reverse biasing triple-junction GaInP/Ga(In)As/Ge solar cells may affect their performance by the formation of permanent shunts even if the reverse breakdown voltage is not reached. In previous works, it was observed that, amid the three…

An isolated single-junction solar cell's temperature in outer space depends only on its radiation exchange with its environment. We consider a cell with zero emissivity below its bandgap and unity above it -- an idealization so far…

应用物理 · 物理学 2021-01-07 Ido Frenkel , Avi Niv

Implementation of an optically active material on silicon has been a persistent technological challenge. For tandem photovoltaics using a Si bottom cell, as well as for other optoelectronic applications, there has been a longstanding need…

A combination of transient photovoltage (TPV), voltage dependent charge extraction (CE) and time delayed collection field (TDCF) measurements is applied to poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl]…

应用物理 · 物理学 2021-06-21 A. Foertig , J. Kniepert , M. Gluecker , T. Brenner , V. Dyakonov , D. Neher , C. Deibel