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We present results from molecular dynamics simulations of a spherically confined neutral polymer in the presence of crowding agents, studying polymer shapes and conformations as a function of the confining potential, solvent quality and the…

软凝聚态物质 · 物理学 2020-01-29 Kamal Tripathi , Gautam I. Menon , Satyavani Vemparala

Extensive molecular dynamics simulations were conducted to explore the conformational phase diagram of a neutral polymer in the presence of attractive crowders of varying sizes. For weakly self-attractive polymers, larger crowders induce a…

软凝聚态物质 · 物理学 2024-10-08 Hitesh Garg , Satyavani Vemparala

Extensive coarse grained molecular dynamics simulations are performed to investigate the conformational phase diagram of a neutral polymer in the presence of attractive crowders. We show that, for low crowded densities, the polymer…

软凝聚态物质 · 物理学 2023-03-29 Hitesh Garg , R Rajesh , Satyavani Vemparala

Solutions of semiflexible polymers confined by repulsive planar walls are studied by density functional theory and Molecular Dynamics simulations, to clarify the competition between the chain alignment favored by the wall and the depletion…

软凝聚态物质 · 物理学 2016-05-25 Sergei A. Egorov , Andrey Milchev , Peter Virnau , Kurt Binder

Using molecular dynamics simulations, we investigate the aggregation behavior of neutral stiff (rod-like) and flexible polymer chains mediated by attractive crowders. Attractive crowders serve as bridging agents, inducing aggregation…

软凝聚态物质 · 物理学 2025-04-02 Hitesh Garg , Satyavani Vemparala

The structure and function of polymers in confined environments, e.g., biopolymers in the cytoplasm of a cell, are strongly affected by macromolecular crowding. To explore the influence of solvent quality on conformations of crowded…

软凝聚态物质 · 物理学 2018-09-27 Wyatt J. Davis , Alan R. Denton

Semiflexible polymers are ubiquitous in natural and artificial systems, where their intermediate rigidity gives rise to rich structural and dynamical behavior. Confinement plays a central role in these behaviors, as spatial restrictions can…

软凝聚态物质 · 物理学 2026-03-31 Nasir Amiri , Jonathan P. Singer , Xin Yong

Monte Carlo computer simulations are used to study the segregation behaviour of two polymers under cylindrical confinement. Using a multiple-histogram method, the conformational free energy, F, of the polymers was measured as a function of…

软凝聚态物质 · 物理学 2018-05-24 James M. Polson , Deanna R. -M. Kerry

The conformational properties of flexible and semiflexible polymers exposed to active noise are studied theoretically. The noise may originate from the interaction of the polymer with surround- ing active (Brownian) particles or from the…

软凝聚态物质 · 物理学 2024-06-03 Thomas Eisenstecken , Gerhard Gompper , Roland G. Winkler

We have generalized the Edwards' method of collective description of dense polymer systems in terms of effective potentials to polymer blends in the presence of a surface. With this method we have studied conformationally asymmetric…

软凝聚态物质 · 物理学 2009-11-11 Semjon Stepanow , Andrei A. Fedorenko

We introduce a class of models of semiflexible polymers. The latter are characterized by a strong rigidity, the correlation length associated to the gradient-gradient correlations, called the persistence length, being of the same order as…

概率论 · 数学 2011-08-25 Ostap Hryniv , Yvan Velenik

The non-equilibrium structural and dynamical properties of semiflexible polymers confined to two dimensions are investigated by molecular dynamics simulations. Three different scenarios are considered: The force-extension relation of…

软凝聚态物质 · 物理学 2013-01-08 A. Lamura , R. G. Winkler

We study structural properties of a ring polymeric melt confined in a film in comparison to a linear counterpart using molecular dynamics simulations. Local structure orderings of ring and linear polymers in the vicinity of the surface are…

软凝聚态物质 · 物理学 2015-10-21 Eunsang Lee , YounJoon Jung

We consider directed semiflexible polymers embedded in a fluctuating surface which is governed by either surface tension or bending rigidity. The attractive interactions induced by the fluctuations of the surface reduce the rigidity of the…

凝聚态物理 · 物理学 2009-10-28 Ramin Golestanian

Confinement is a versatile and well-established tool to study the properties of polymers either to understand biological processes or to develop new nano-biomaterials. We investigate the conformations of a semiflexible polymer ring in weak…

软凝聚态物质 · 物理学 2010-06-25 Katja Ostermeir , Karen Alim , Erwin Frey

We explore the effect of an attractive interaction between parallel-aligned polymers, which are perpendicularly grafted on a substrate. Such an attractive interaction could be due to, e.g., reversible cross-links. The competition between…

软凝聚态物质 · 物理学 2013-10-08 Panayotis Benetatos , Eugene M. Terentjev , Annette Zippelius

The properties of semiflexible polymers tethered by one end to an impenetrable wall and exposed to oscillatory shear flow are investigated by mesoscale simulations. A polymer, confined in two dimensions, is described by a linear bead-spring…

软凝聚态物质 · 物理学 2021-12-14 Antonio Lamura , Roland G. Winkler , Gerhard Gompper

We study analytically a model of a two dimensional, partially directed, flexible or semiflexible polymer, attached to an attractive wall which is perpendicular to the preferred direction. In addition, the polymer is stretched by an…

统计力学 · 物理学 2015-05-13 Pui-Man Lam , Yi Zhen , Haijun Zhou , Jie Zhou

The interplay of topological constraints and persistence length of ring polymers in their own melt is investigated by means of dynamical Monte Carlo simulations of a three dimensional lattice model. We ask if the results are consistent with…

统计力学 · 物理学 2009-10-31 M. Muller , J. P. Wittmer , M. E. Cates

We study conformational properties of diluted dumbbell polymers which consist of two rings that are attached to both ends of a linear spacer segment by using analytical methods of field theory and bead-spring coarse-grained molecular…

软凝聚态物质 · 物理学 2023-03-22 Khristine Haydukivska , Viktoria Blavatska , Jaroslaw Paturej
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