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High-entropy oxides (HEOs), as a new family of materials with five or more principal cations, have shown promising properties for various applications. In this work and inspired by inherent defective and strained structure of HEOs,…

High-entropy oxides (HEOs), containing at least five principal cations, have recently emerged as promising photocatalysts for hydrogen production via water splitting. Despite their high potential, the impact of the cation mixtures on…

材料科学 · 物理学 2024-05-31 Jacqueline Hidalgo-Jimenez , Taner Akbay , Tatsumi Ishihara , Kaveh Edalati

Photocatalytic hydrogen (H2) production and carbon dioxide (CO2) conversion to methane (CH4) are considered promising solutions for reducing CO2 emissions. However, the development of highly active photocatalysts is essential to efficiently…

材料科学 · 物理学 2025-10-23 Jacqueline Hidalgo-Jimenez , Taner Akbay , Tatsumi Ishihara , Kaveh Edalati

The formation of green energy carriers such as hydrogen (H2) and methane (CH4) via photocatalytic processes provides a clean method for addressing environmental and energy issues. To achieve highly efficient photocatalysts for H2 and CH4…

化学物理 · 物理学 2025-08-05 Ho Truong Nam Hai , Jacqueline Hidalgo-Jiménez , Kaveh Edalati

To enhance the activity of photocatalysts for hydrogen production and CO2 conversion, noble metal cocatalysts as electron traps and/or acceptors such as platinum or gold are usually utilized. This study hypothesizes that mixing elements…

Methane (CH4) formation from photocatalytic carbon dioxide (CO2) conversion in water is currently of interest because methane is a fuel, and it can also be transformed into other useful hydrocarbons. However, achieving high selectivity to…

Simultaneous catalytic hydrogen (H2) production and plastic waste degradation under light, known as photoreforming, is a novel approach to green fuel production and efficient waste management. Here, we use a high-entropy oxide (HEO), a new…

材料科学 · 物理学 2024-12-03 Thanh Tam Nguyen , Kaveh Edalati

CO$_2$ photoreduction on photocatalysts is a nature-friendly solution to decrease the CO$_2$ amount, but the method still has low efficiency because of difficult separation and easy recombination of charge carriers in available catalysts.…

High-entropy materials have emerged as a promising class of catalysts, driven by their high configurational entropy originating from structural disorder in single-phase multicomponent systems. Despite their potential, the catalytic…

材料科学 · 物理学 2025-12-23 Anjali Varshney , Aishwery J. Verma , Ritesh Dubey , Sushil Kumar , Tapas Goswami , Samar Layek

Visible-light photocatalyst titanium dioxide (TiO2) was successfully prepared via a novel and facile single-mode microwave assisted synthesis process. In this one-step synthesis, Ti as target material selectively oxides in magnetic field…

应用物理 · 物理学 2022-02-04 Kunihiko Katoa , Sebastien Vaucher , Patrik Hoffmann , Yunzi Xin , Takashi Shirai

Ammonia, a critical chemical fertilizer and a potential hydrogen carrier, can be sustainably synthesized from atmospheric nitrogen and water under ambient conditions through photocatalysis. In this study, high-entropy oxides with d0 and…

化学物理 · 物理学 2025-08-19 Thanh Tam Nguyen , Jacqueline Hidalgo-Jimenez , Kaveh Edalati

High-entropy oxide (HEO) thermodynamics transcend temperature-centric approaches, spanning a multidimensional landscape where oxygen chemical potential plays a decisive role. Here, we experimentally demonstrate how controlling the oxygen…

Achieving both broad solar-spectrum absorption and strong redox capability is critical for semiconductor photocatalysts in environmental remediation and energy conversion. Herein, an S-scheme heterojunction photocatalyst is constructed by…

材料科学 · 物理学 2026-03-31 Xiaoyi Zhou , Min Zhang , Qiushi Wang , Shiwen Du , Xuedong Jing , Zhenyi Zhang

The vast compositional and structural landscape of high-entropy oxides (HEOs) grants them a wide range of potentially valuable physicochemical properties. However, the elemental immiscibility and crystal complexity limit their controllable…

材料科学 · 物理学 2025-04-14 Peng wei , Yiwen Liu , Hao Bai , Lei Zhuang , Hulei Yu , Yanhui Chu

Bandgap engineering has attracted increasing interest in the field of semiconductive materials with specific electrical and optical characteristics for various applications, such as solar energy harvesting, energy-related applications, and…

材料科学 · 物理学 2022-02-15 Kunihiko Kato , Takashi Shirai

The persistent existence of plastic waste causes serious problems for the environment, directly and indirectly affecting the health of organisms and humans. Photoreforming is a nature-friendly method that only uses solar energy to convert…

The shape-controlled synthesis of cuprous oxide (Cu$_2$O) photocatalysts with both low or high index crystal planes has received increasing attention due to their unique facet-dependent properties. Since they are cheap and earth abundant,…

材料科学 · 物理学 2022-12-09 Sourav Rej , Matteo Bisetto , Alberto Naldoni , Paolo Fornasiero

TiO2 nanotube arrays grown by anodization were coated with thin layers of polydopamine as visible light sensitizer. The PDA-coated TiO2 scaffolds were used as photocatalyst for selective oxidation of benzyl alcohol under monochromatic…

材料科学 · 物理学 2016-10-18 Jyotsna Tripathy , Gabriel Loget , Marco Altomare , Patrik Schmuki

Zr/N co-doped TiO2 nanostructures were successfully synthesized using nanotubular titanic acid (NTA) as precursors by a facile wet chemical route and subsequent calcination. These Zr/N-doped TiO2 nanostructures made by NTA precursors show…

材料科学 · 物理学 2013-12-31 Min Zhang , Xinluan Yu , Dandan Lu , Jianjun Yang

The production of hydrogen from water using only a catalyst and solar energy is one of the most challenging and promising outlets for the generation of clean and renewable energy. Semiconductor photocatalysts for solar hydrogen production…

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