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The interlayer sliding energy landscape of hexagonal boron nitride (h-BN) is investigated via a van der Waals corrected density functional theory approach. It is found that the main role of the van der Waals forces is to "anchor" the layers…

Improving the film quality in the synthesis of large-area hexagonal boron nitride films (h-BN) for two-dimensional material devices remains a great challenge. The measurement of electrical breakdown dielectric strength (EBD) is one of the…

材料科学 · 物理学 2017-01-04 Yoshiaki Hattori , Takashi Taniguchi , Kenji Watanabe , Kosuke Nagashio

A systematic analysis of phonon-plasmon coupled excitations in three-dimensional (3D) polar systems is provided through the prism of both raw and integrated electron energy loss spectroscopy (EELS) and phonon spectra in the whole relevant…

强关联电子 · 物理学 2022-09-02 J. Krsnik , O. S. Barišić

Strong electron-electron interactions are known to significantly modify the electron-phonon coupling relative to the predictions of density functional theory, but this effect is challenging to calculate with realistic theories of strongly…

强关联电子 · 物理学 2025-07-21 David J. Abramovitch , Jennifer Coulter , Sophie Beck , Andrew Millis

The Raman peak position and linewidth provide insight into phonon anharmonicity and electron-phonon interactions (EPI) in materials. For monolayer graphene, prior first-principles calculations have yielded decreasing linewidth with…

材料科学 · 物理学 2022-01-27 Zherui Han , Xiaolong Yang , Sean E. Sullivan , Tianli Feng , Li Shi , Wu Li , Xiulin Ruan

In this paper, we investigate the electronic band structure, lattice dynamics and electron-phonon interaction in $\delta$-NbN, $\varepsilon$-NbN and WC-NbN by performing systematic ab initio calculations based on DFT-GGA. The calculated…

超导电性 · 物理学 2019-03-27 K. Ramesh Babu , Guang-Yu Guo

Electron-phonon interaction (EPI) is presumably detrimental for thermoelectric performance in semiconductors because it limits carrier mobility. Here we show that enhanced EPI with strong energy dependence offers an intrinsic pathway to…

材料科学 · 物理学 2019-11-06 Yi Xia , Junsoo Park , Vidvuds Ozoliņš , Chris Wolverton

Using a controlled analytic treatment, we derive a model that generically describes cooperative strong electron-phonon interaction (EPI) in one-band and two-band Jahn-Teller (JT) systems. The model involves a {\em next-nearest-neighbor}…

强关联电子 · 物理学 2008-03-04 Sudhakar Yarlagadda

The total energy is a fundamental characteristic of solids, molecules, and nanostructures. In most first-principles calculations of the total energy, the nuclear kinetic operator is decoupled from the many-body electronic Hamiltonian and…

材料科学 · 物理学 2026-02-17 Samuel Poncé , Xavier Gonze

Cubic boron nitride (cBN) is a wide-bandgap polymorph of boron nitride whose optical response remains only partially understood due to the coexistence of indirect electronic transitions and strong exciton-phonon coupling. Using…

The equilibrium structure, energy bands, phonon dispersions, and s- and d-channel electron-phonon interactions (EPIs) are calculated for the infinite-layer superconductor CaCuO2 doped with 0.24 holes per CuO2. The LDA and the…

超导电性 · 物理学 2009-10-30 O. K. Andersen , S. Y. Savrasov , O. Jepsen , A. I. Liechtenstein

A qualitative study of the electron-phonon interaction (EPI) spectra in $2H-NbS{{e}_{2}}$ is carried out by the method of point-contact spectroscopy in the superconducting state. Anisotropy of the EPI spectra for contacts oriented in the…

超导电性 · 物理学 2016-03-09 N. L. Bobrov , L. F. Rybal'chenko , M. A. Obolenskii , V. V. Fisun

Using finite temperature Raman spectroscopy, we investigate the electron-phonon interactions (EPI) and phonon-phonon scattering dynamics in the Dirac semimetal Cd3As2 in different fre quency regimes. Strong softening of the Raman shifts…

强关联电子 · 物理学 2025-03-04 Debasmita Swain , Akash Dey , Anushree Roy , Kush Saha , Sitikantha D. Das

When two-dimensional atomic layers of different materials are brought into close proximity to form van der Waals (vdW) heterostructures, interactions between adjacent layers significantly influence their physicochemical properties. These…

Biomolecules are complex systems stabilized by a delicate balance of weak interactions, making it important to assess all energetic contributions in an accurate manner. However, it is a priori unclear which contributions make more of an…

化学物理 · 物理学 2016-11-22 Mariana Rossi , Wei Fang , Angelos Michaelides

The origin of the charge density wave (CDW) in transition metal dichalcognides has been in hot debate and no conclusive agreement has been reached. Here, we propose an ab-initio framework for an accurate description of both Fermi surface…

材料科学 · 物理学 2022-08-16 Zishen Wang , Chuan Chen , Jinchao Mo , Jun Zhou , Kian Ping Loh , Yuan Ping Feng

Using high resolution angle-resolved photoemission data in conjunction with that from neutron and other probes, we show that electron-phonon (el-ph) coupling is strong in cuprates superconductors and it plays an important role in pairing.…

超导电性 · 物理学 2009-11-07 Z. -X. Shen , A. Lanzara , S. Ishihara , N. Nagaosa

Quantum emitters in two-dimensional hexagonal boron nitride (h-BN) have generated significant interest due to observations of ultra-bright emission made at room temperature. The expectation that solid-state emitters exhibit broad…

Van der Waals heterostructures, vertical stacks of layered materials, offer newopportunities for novel quantum phenomena which are absent in their constituent components. Here we report the emergence of polaron quasiparticles at the…

In systems with linear electron-phonon interaction (EPI), bound states of polarons, or bipolarons, form by gaining energy from the lattice deformation. The quadratic EPI case is fundamentally different: bipolarons form because electrons…

强关联电子 · 物理学 2025-01-14 Zhongjin Zhang , Anatoly Kuklov , Nikolay Prokof'ev , Boris Svistunov