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Metal-organic frameworks (MOFs) symbolize the particular class of hybrid crystalline, nano-porous materials made of either discrete metal ions or clusters with organic linkers. Past studies on MOFs-based materials largely focused on…

材料科学 · 物理学 2022-06-28 Ranjeev Kumar Parashar , Priyajit Jash , Prakash Chandra Mondal

Metal-organic frameworks (MOFs) are a specific class of hybrid, crystalline, nano-porous materials made of metal-ion-based nodes and organic linkers. Most of the studies on MOFs largely focused on porosity, chemical and structural…

Coordination polymerization leads to various metal-organic frameworks (MOFs) in which symmetrical metal nodes exposed to nano voids lead to unique physical properties and chemical functionalities. One of the challenges towards their…

介观与纳米尺度物理 · 物理学 2016-11-29 Hidetsugu Shiozawa , Bernhard C. Bayer , Herwig Peterlik , Jannik C. Meyer , Wolfgang Lang , Thomas Pichler

Finding new two-dimensional (2D) materials with novel quantum properties is highly desirable for technological innovations. In this work, we studied a series of metal-organic frameworks (MOFs) with different metal cores and discovered…

材料科学 · 物理学 2020-11-17 Jie Li , Ruqian Wu

The advent of pi-stacked layered metal-organic frameworks (MOFs) opened up new horizons for designing compact MOF-based devices as they offer unique electrical conductivity on top of permanent porosity and exceptionally high surface area.…

材料科学 · 物理学 2025-01-31 Zeyu Zhang , Dylan Valente , Yuliang Shi , Dil K. Limbu , Mohammad R. Momeni , Farnaz A. Shakib

Recently, the superconductivity in a metal-organic framework (MOF) has been discovered for the first time in copper(II) benzenehexathiolate ([Cu$_3$(C$_6$S$_6$)]$_n$, Cu-BHT). The Cu atoms form a two-dimensional perfect Kagome lattice,…

超导电性 · 物理学 2020-09-21 T. Takenaka , K. Ishihara , Y. Miao , X. Huang , W. Xu , D. Zhu , N. Su , J. -G. Cheng , T. Shibauchi

Despite the highly porous nature with significantly large surface area, metal organic frameworks (MOFs) can be hardly used in electronic, and optoelectronic devices due to their extremely poor electrical conductivity. Therefore, the study…

Metal-organic frameworks (MOFs), which are self-assemblies of metal ions and organic ligands, provide a tunable platform to search a new state of matter. A two-dimensional (2D) perfect kagome lattice, whose geometrical frustration is a key…

Metal-organic frameworks (MOFs) are promising materials for gas sensing but are often limited to single-use detection. We demonstrate a hybridization strategy synergistically deploying conductive MOFs (cMOFs) and conductive polymers (cPs)…

Nanoporous carbon materials containing small domains of sp2-carbon with highly disordered structures are promising for supercapacitor applications. Herein, we synthesize amorphous carbon nanofoam with 98% volumetric void fraction and low…

Outstanding functional tunability underpinning metal-organic framework (MOF) confers a versatile platform to contrive next-generation chemical sensors, optoelectronics, energy harvesters and converters. We report a rare exemplar of a porous…

材料科学 · 物理学 2019-08-27 Abhijeet K. Chaudhari , Ha Jin Kim , Intaek Han , Jin-Chong Tan

Addressing climate change calls for action to control CO$_2$ pollution. Direct air and ocean capture offer a solution to this challenge. Making carbon capture competitive with alternatives, such as forestation and mineralisation, requires…

Over the past decade, climate change has become an increasing problem with one of the major contributing factors being carbon dioxide (CO2) emissions; almost 51% of total US carbon emissions are from factories. Current materials used in CO2…

机器学习 · 计算机科学 2023-11-29 Neel Redkar

The combination of two-dimensional (2D) materials into vertical heterostructures has emerged as a promising path to designer quantum materials with exotic properties. Here, we extend this concept from inorganic 2D materials to 2D…

The extra CO2 that has already been released into the atmosphere has to be removed in order to create a world that is carbon neutral. Technologies have been created to remove carbon dioxide from wet flue gas or even directly from ambient…

Chemical looping methane partial oxidation provides an energy and cost effective route for methane utilization. However, there is considerable CO2 co-production in state-of-the-art chemical looping systems, rendering a decreased…

化学物理 · 物理学 2020-01-08 Yan Liu , Lang Qin , Zhuo Cheng , Josh W. Goetze , Fanhe Kong , Jonathan A. Fan , Liang-shih Fan

Metal-organic frameworks (MOFs) have emerged as promising materials for carbon capture applications due to their high CO2 capacities and tunable properties. Amongst the many possible MOFs, metal-substituted compounds based on M-DOBDC and…

材料科学 · 物理学 2016-03-11 Hyun Seung Koh , Malay Kumar Rana , Jinhyung Hwang , Donald J. Siegel

We report the field emission (FE) properties of Cu coated vertically aligned carbon nanotubes (VACNTs) before and after oxidation. The current density was found to be the maximum (20 mA/cm$^2$) for 3 nm thick Cu coated VACNTs after…

应用物理 · 物理学 2018-11-28 M. Sreekanth , S. Ghosh , P. Srivastava

We present a computational microscopy analysis (targeted molecular dynamics simulations) of the structure and performance of conductive metal organic framework (MOF) electrodes in supercapacitors with room temperature ionic liquids. The…

材料科学 · 物理学 2020-02-24 Sheng Bi , Ming Chen , Runxi Wang , Jiamao Feng , Mircea Dinca , Alexei A. Kornyshev , Guang Feng

Soft and flexible conductors are essential in the development of soft robots, wearable electronics, as well as electronic tissue and implants. However, conventional soft conductors are inherently characterized by a large change in…

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