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The van der Waals (vdW) dispersion interaction between two finite neutral objects typically follows the standard nonretarded $d^{-6}$ law. Here, we reveal an anomalous $d^{-10}$ scaling law between nanostructures with strong geometric or…

介观与纳米尺度物理 · 物理学 2025-07-01 Hui Pan , Yuhua Ren , Jian-Sheng Wang

Van der Waals interactions are ubiquitous and they play an important role for the stability of materials. Current understanding of this type of coupling is based on linear response theory, while optical nonlinearities are rarely considered…

材料科学 · 物理学 2024-08-27 Dai-Nam Le , Pablo Rodriguez-Lopez , Lilia M. Woods

Within the frame of macroscopic quantum electrodynamics in causal media, the van der Waals interaction between an atomic system and an arbitrary arrangement of dispersing and absorbing dielectric bodies including metals is studied. It is…

量子物理 · 物理学 2007-05-23 Stefan Yoshi Buhmann , Ho Trung Dung , Dirk-Gunnar Welsch

We study the dispersion interaction of the van der Waals and Casimir-Polder (vdW-CP) type between a neutral atom and the surface of a metal by allowing for nonlocal electrodynamics, i.e. electron diffusion. We consider two models: (i) bulk…

原子物理 · 物理学 2014-07-23 Elad Eizner , Baruch Horovitz , Carsten Henkel

Dispersion interactions such as the van der Waals interaction between atoms or molecules derive from quantum fluctuations of the electromagnetic field and can be understood as the exchange of virtual photons between the interacting…

量子物理 · 物理学 2015-06-11 Harald R. Haakh , Stefan Scheel

We present a series of calculations of van der Waals (vdW) forces that show non-additive behavior. The results reveal effects of geometrical dependences of the dispersion forces, that are in strong contradictions to the results from…

量子物理 · 物理学 2008-05-13 Carlos E Roman-Velazquez , Bo E Sernelius

The van der Waals interaction between two polarizable atoms is considered. In three dimensions the standard form with an attractive $1/|R|^6$ potential is obtained from second-order quantum perturbation theory. When the electron motion is…

量子物理 · 物理学 2015-01-22 A. C. Ipsen , K. Splittorff

We use a general theory of the fluctuating electromagnetic field to calculate the friction force acting on a small neutral particle, e.g., a physisorbed molecule, or a nanoscale object with arbitrary dispersive and absorptive dielectric…

材料科学 · 物理学 2009-11-11 A. I. Volokitin , B. N. J. Persson

Noncovalent van der Waals (vdW) interactions are responsible for a wide range of phenomena in matter. Popular density-functional methods that treat vdW interactions use disparate physical models for these intricate forces, and as a result…

材料科学 · 物理学 2020-04-15 Jan Hermann , Alexandre Tkatchenko

Understanding static and dynamic phenomena in complex materials at different length scales requires reliably accounting for van der Waals (vdW) interactions, which stem from long-range electronic correlations. While the important role of…

材料科学 · 物理学 2022-03-23 Paul Hauseux , Alberto Ambrosetti , Stéphane P. A. Bordas , Alexandre Tkatchenko

It is an undisputed textbook fact that non-retarded van der Waals (vdW) interactions between isotropic dimers are attractive, regardless of the polarizability of the interacting systems or spatial dimensionality. The universality of vdW…

介观与纳米尺度物理 · 物理学 2017-05-31 Mainak Sadhukhan , Alexandre Tkatchenko

To investigate the role of long-range van der Waals interactions in static friction, we derive an analytic expression for the coefficient of static friction $\mu_s$ between two thin layers of polarizable materials under zero load. For…

介观与纳米尺度物理 · 物理学 2022-09-14 Ram Narayanan , Prachi Parashar , K. V. Shajesh , S. Vijayakumar

The dispersion component of the van der Waals (vdW) interaction in low-dimensional metals is known to exhibit anomalous "Type-C non-additivity" [Int. J. Quantum Chem. 114, 1157 (2014)]. This causes dispersion energy behavior, at…

介观与纳米尺度物理 · 物理学 2023-08-24 John F. Dobson , Alberto Ambroselli

Interactions induced by electromagnetic fluctuations, such as van der Waals and Casimir forces, are of universal nature present at any length scale between any types of systems with finite dimensions. Such interactions are important not…

Filamentary objects such as nano-wires, nanotubes and DNA are of current interest in physics, nanoscience, chemistry, biology and medicine. They can interact via strong, exceptionally long-ranged many-object van der Waals (vdW, dispersion)…

材料科学 · 物理学 2026-02-24 Subhojit Pal , John F. Dobson , Mathias Boström

We study the thermal Casimir effect between two thick slabs composed of plane-parallel layers of random dielectric materials interacting across an intervening homogeneous dielectric. It is found that the effective interaction at long…

统计力学 · 物理学 2011-12-30 David S. Dean , Ron R. Horgan , Ali Naji , Rudolf Podgornik

Mutual Coulomb interactions between electrons lead to a plethora of interesting physical and chemical effects, especially if those interactions involve many fluctuating electrons over large spatial scales. Here, we identify and study in…

Dispersion interactions are long-range interactions between neutral ground-state atoms or molecules, or polarizable bodies in general, due to their common interaction with the quantum electromagnetic field. They arise from the exchange of…

量子物理 · 物理学 2018-12-13 Roberto Passante

The van der Waals (vdW) density functional (vdW-DF) method [ROPP 78, 066501 (2015)] describes dispersion or vdW binding by tracking the effects of an electrodynamic coupling among pairs of electrons and their associated exchange-correlation…

强关联电子 · 物理学 2018-02-21 Yang Jiao , Elsebeth Schröder , Per Hyldgaard

The quantum theory of the fluctuations of the van der Waals (vdW) force between macroscopic bodies is developed. Unlike the mean vdW force that is determined by all quantum states that contribute to the optical absorption, the energies of…

材料科学 · 物理学 2007-05-23 Shulim Kogan
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