相关论文: Solution to the two-body Smoluchowski equation wit…
We present a theoretical framework to investigate the microscopic structure of concentrated hard-sphere colloidal suspensions under strong shear flows by fully taking into account the boundary-layer structure of convective diffusion. We…
The pair correlation function of charge stabilized colloidal particles under strongly sheared conditions is studied using the analytical intermediate asymptotics method recently developed in [L. Banetta and A. Zaccone, Phys. Rev. E 99,…
Closed analytical expressions for scattering intensity and other global structure factors are derived for a new solvable model of polydisperse sticky hard spheres. The starting point is the exact solution of the ``mean spherical…
In the present article we introduce a variant of Smoluchowski's coagulation equation with both position and velocity variables taking a kinetic viewpoint arising as the scaling limit of a system of second-order (microscopic) coagulating…
We theoretically investigate general properties of driven (sheared) colloidal suspensions in confinement, based on methods of classical density functional theory. In the absence of an exact closed (Smoluchowski-) equation for the…
The Smoluchowski equation is a system of partial differential equations modelling the diffusion and binary coagulation of a large collection of tiny particles. The mass parameter may be indexed either by positive integers, or by positive…
We combine a heuristic theory of geometric percolation and the Smoluchowski theory of colloid dynamics to predict the impact of shear flow on the percolation threshold of hard spherical colloidal particles, and verify our findings by means…
We consider the dynamics of a small spherical particle driven through an unbounded viscoelastic shear flow by an external force. We give analytical solutions to both the mobility problem (velocity of forced particle) and the resistance…
We analyze the dynamics of concentrated polymer solutions modeled by a 2D Smoluchowski equation. We describe the long time behavior of the polymer suspensions in a fluid. When the flow influence is neglected the equation has a gradient…
The Smoluchowski approach to diffusion-controlled reactions is generalized to interacting substrate particles by including the osmotic pressure and hydrodynamic interactions of the nonideal particles in the Smoluchoswki equation within a…
In the vicinity of their glass transition, dense colloidal suspensions acquire elastic properties over experimental timescales. We investigate the possibility of a visco-elastic flow instability in curved geometry for such materials. To…
In this work we develop constitutive equations for a dense, sheared suspension of frictionally interacting rods by applying Onsager's variational method as formulated by Doi. We treat both solid friction, of the Amontons-Coulomb form; and…
We investigate the rheology, microscopic structure, and dynamics of an industrially relevant dispersion made of cationic surfactant vesicles, from dilute to concentrated conditions. We find that these suspensions exhibit a shear-thinning…
Using a novel approximation scheme within the convective diffusion (two body Smoluchowski) equation framework, we unveil the shear-driven aggregation mechanism at the origin of structure-formation in sheared colloidal systems. The theory,…
Flow behavior of a single-component yield stress fluid is addressed on the hydrodynamic level. A basic ingredient of the model is a coupling between fluctuations of density and velocity gradient via a Herschel-Bulkley-type constitutive…
Orientation and microstructure are investigated in sheared Brownian suspensions of hard dicolloidal particles, with the dicolloids modeled as two fused spheres of varying radii and center to center separations. Two different particle shapes…
We consider the nonlinear rheology of dense colloidal suspensions under a time-dependent simple shear flow. Starting from the Smoluchowski equation for interacting Brownian particles advected by shearing (ignoring fluctuations in fluid…
Determining the microstructure of colloidal suspensions under shear flows has been a challenge for theoretical and computational methods due to the singularly-perturbed boundary-layer nature of the problem. Previous approaches have been…
Application of shear flow to charge-stabilized aqueous colloidal suspensions is ubiquitous in industrial applications and as a means to achieve controlled field-induced assembly of nanoparticles. Yet, applying shear flow to a…
We analyze a suspension of deformable particles in a pressure-driven flow. The suspension is composed of neutrally buoyant initially spherical particles and a Newtonian carrier fluid, and the flow is solved by means of direct numerical…