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The entropy production is commonly interpreted as measuring the distance from equilibrium. However, this explanation lacks a rigorous description due to the absence of a natural equilibrium measure. The present analysis formalizes this…

统计力学 · 物理学 2025-10-23 David Andrieux

Markov chains are a natural and well understood tool for describing one-dimensional patterns in time or space. We show how to infer $k$-th order Markov chains, for arbitrary $k$, from finite data by applying Bayesian methods to both…

统计理论 · 数学 2009-11-13 Christopher C. Strelioff , James P. Crutchfield , Alfred W. Hubler

This paper considers the problem of testing whether there exists a solution satisfying certain non-negativity constraints to a linear system of equations. Importantly and in contrast to some prior work, we allow all parameters in the system…

Observing stochastic trajectories with rare transitions between states, practically undetectable on time scales accessible to experiments, makes it impossible to directly quantify the entropy production and thus infer whether and how far…

统计力学 · 物理学 2025-12-15 Marco Baiesi , Tomohiro Nishiyama , Gianmaria Falasco

We derive a Thermodynamic Uncertainty Relation bounding the mean squared displacement of a Gaussian process with memory, driven out of equilibrium by unbalanced thermal baths and/or by external forces. Our bound is tighter with respect to…

统计力学 · 物理学 2023-05-23 Andrea Plati , Andrea Puglisi , Alessandro Sarracino

Entropy production is a universal measure of irreversibility and energy dissipation in physical, chemical, and biological systems operating far from equilibrium. However, quantifying and spatiotemporally localising it in complex processes…

统计力学 · 物理学 2026-05-18 Biswajit Das , Sreekanth K Manikandan

What is the best description that we can construct of a thermodynamic system that is not in equilibrium, given only one, or a few, extra parameters over and above those needed for a description of the same system at equilibrium? Here, we…

统计力学 · 物理学 2007-07-05 Gavin E. Crooks

There are only a very few known relations in statistical dynamics that are valid for systems driven arbitrarily far-from-equilibrium. One of these is the fluctuation theorem, which places conditions on the entropy production probability…

统计力学 · 物理学 2009-09-25 Gavin E. Crooks

Entropy is one of the key thermodynamic variables reflecting changes in the state of matter. Unlike other thermodynamic variables, it is well-defined also for nonequilibrium steady states through its relation to information. Applying this…

统计力学 · 物理学 2026-04-15 Haim Diamant , Gil Ariel

A new method is proposed to numerically extract the diffusivity of a (typically nonlinear) diffusion equation from underlying stochastic particle systems. The proposed strategy requires the system to be in local equilibrium and have…

统计力学 · 物理学 2018-05-09 Peter Embacher , Nicolas Dirr , Johannes Zimmer , Celia Reina

The entropy production rate is central to the study of non-equilibrium systems. This parameter is closely connected to violation of time-reversal symmetry, energy consumption, efficiency, and other properties of interest; in short, it…

统计力学 · 物理学 2026-05-28 John W. Biddle

Closely related to the laws of thermodynamics, the detection and quantification of disequilibria are crucial in unraveling the complexities of nature, particularly those beneath observable layers. Theoretical developments in nonequilibrium…

统计力学 · 物理学 2024-07-23 Pedro E. Harunari

Mostof the existing literature on supervised machine learning problems focuses on the case when the training data set is drawn from an i.i.d. sample. However, many practical problems are characterized by temporal dependence and strong…

统计理论 · 数学 2023-01-23 Nikola Sandrić , Stjepan Šebek

In this paper we review various information-theoretic characterizations of the approach to equilibrium in biological systems. The replicator equation, evolutionary game theory, Markov processes and chemical reaction networks all describe…

信息论 · 计算机科学 2017-08-22 John C. Baez , Blake S. Pollard

We consider many-body quantum systems that exhibit quantum chaos, in the sense that the observables of interest act on energy eigenstates like banded random matrices. We study the time-dependent expectation values of these observables,…

统计力学 · 物理学 2009-10-31 Mark Srednicki

Measuring entropy production of a system directly from the experimental data is highly desirable since it gives a quantifiable measure of the time-irreversibility for non-equilibrium systems and can be used as a cost function to optimize…

统计力学 · 物理学 2024-07-16 Prashant Singh , Karel Proesmans

If the state space of a homogeneous continuous-time Markov chain is too large, making inferences - here limited to determining marginal or limit expectations - becomes computationally infeasible. Fortunately, the state space of such a chain…

概率论 · 数学 2018-06-01 Alexander Erreygers , Jasper De Bock

The thermodynamic definition of entropy can be extended to nonequilibrium systems based on its relation to information. To apply this definition in practice requires access to the physical system's microstates, which may be prohibitively…

统计力学 · 物理学 2020-08-21 Gil Ariel , Haim Diamant

Entropy production is arguably the most universally applicable measure of non-equilibrium behavior, particularly for systems coupled to a heat bath. This setting encompasses driven soft matter as well as biomolecular, biochemical, and…

统计力学 · 物理学 2025-12-09 Udo Seifert

The inference of thermodynamic quantities from the description of an only partially accessible physical system is a central challenge in stochastic thermodynamics. A common approach is coarse-graining, which maps the dynamics of such a…

统计力学 · 物理学 2022-08-19 Jann van der Meer , Benjamin Ertel , Udo Seifert
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