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Hybrid organic-inorganic perovskites (HOIPs) have become an important class of semiconductors for solar cells and other optoelectronic applications. Electron-phonon coupling plays a critical role in all optoelectronic devices, and although…

The hybrid organic-inorganic halide perovskite (HOIP), for example MAPbBr3, exhibits extended spin lifetime and apparent spin lifetime anisotropy in experiments. The underlying mechanisms of these phenomena remain illusive. By utilizing our…

Methylammonium lead triiodine (MAPbI$_3$) is a material representative of the hybrid organic-inorganic lead halide perovskites which attract currently great attention due to their photovoltaic efficiency and bright optoelectronic…

材料科学 · 物理学 2022-06-08 E. Kirstein , D. R. Yakovlev , E. A. Zhukov , J. Höcker , V. Dyakonov , M. Bayer

We have developed a multi-scale model for organic-inorganic hybrid perovskites (HPs) that applies quantum mechanical (QM) calculations of small HP supercell models to large coarse-grained structures. With a mixed quantum-classical hopping…

材料科学 · 物理学 2018-10-12 Jari Järvi , Jingrui Li , Patrick Rinke

We present an experimental and theoretical viewpoint on the electronic carrier mobilities of typical hybrid organic-inorganic perovskites (HOIPs). While these mobilities are often quoted as high, a review of them shows that although…

材料科学 · 物理学 2018-07-17 Thomas M. Brenner , David A. Egger , Andrew M. Rappe , Leeor Kronik , Gary Hodes , David Cahen

Using muon spin relaxation ($\mu$SR) measurements on formamidinium lead iodide [FAPbI$_3$, where FA denotes HC(NH$_2)_2$] we show that, among the five structurally distinct phases of FAPbI$_3$ exhibited through two different temperature…

材料科学 · 物理学 2023-08-07 M. Hiraishi , A. Koda , H. Okabe , R. Kadono , K. A. Dagnall , J. J. Choi , S. -H. Lee

Organic-inorganic hybrid perovskite architecture could serve as a robust platform for materials design to realize functionalities beyond photovoltaic applications. We explore caloric effects in organometal halide perovskites, taking…

材料科学 · 物理学 2016-04-21 Shi Liu , Ronald E. Cohen

The outstanding performance of organic-inorganic metal trihalide solar cells benefits from the exceptional photo-physical properties of both electrons and holes in the material. Here, we directly probe the free-carrier dynamics in Cs-doped…

介观与纳米尺度物理 · 物理学 2021-09-01 Xuejian Ma , Fei Zhang , Zhaodong Chu , Ji Hao , Xihan Chen , Jiamin Quan , Zhiyuan Huang , Xiaoming Wang , Xiaoqin Li , Yanfa Yan , Kai Zhu , Keji Lai

The high performance of hybrid perovskite based devices is attributed to its excellent bulk-transport properties. However, carrier dynamics, especially at the metal-perovskite interface, and its influence on device operation are not widely…

材料科学 · 物理学 2022-02-25 N. Ganesh , A. Z. Ashar , Sumukh Purohit , K. L. Narasimhan , K. S. Narayan

The hybrid perovskite CH3NH3PbI3 (MAPI) exhibits long minority-carrier lifetimes and diffusion lengths. We show that slow recombination originates from a spin-split indirect-gap. Large internal electric fields act on spin-orbit-coupled band…

Organic-inorganic hybrid perovskites such as methylammonium lead iodide (CH3NH3PbI3) are game-changing semiconductors for solar cells and light-emitting devices owing to their exceptionally long carrier lifetime and diffusion length.…

Organic-inorganic semiconductors, which adopt the perovskite crystal structure, have perturbed the landscape of contemporary photovoltaics research. In this Account, we discuss the internal motion of methylammonium lead iodide…

材料科学 · 物理学 2016-05-31 Jarvist M. Frost , Aron Walsh

The high efficiency of lead organo-metal-halide perovskite solar cells has raised many questions about the role of the methylammonium (MA) molecules in the Pb-I framework. Experiments indicate that the MA molecules are able to 'freely' spin…

Transient opto-electrical measurements of methylammonium lead iodide (MALI) perovskite solar cells (PSCs) are performed and analyzed in order to elucidate the operating mechanisms. The current response to a light pulse or voltage pulse…

材料科学 · 物理学 2016-11-22 Martin Thomas Neukom

Due to their exceptional photovoltaic properties, metal halide perovskites (MHPs) are extensively studied for their potential applications in solar cells. In recent years, the power conversion efficiencies of MHPs-based solar cells rapidly…

材料科学 · 物理学 2022-08-12 A. Bojtor , S. Kollarics , B. G. Markus , A. Sienkiewicz , M. Kollar , L. Forro , F. Simon

Two-dimensional hybrid organic-inorganic perovskites (HOIPs) have emerged as promising materials for light-emitting diode applications. In this study, by using time-of-flight neutron spectroscopy we identified and quantitatively separated…

Hybrid organic-inorganic perovskites (HOIPs) have recently emerged as highly promising solution-processable materials for photovoltaic (PV) and other optoelectronic devices. HOIPs represent a broad family of materials with properties highly…

Solar cells based on metal-halide perovskite absorber layers have resulted in outstanding photovoltaic devices with long non-radiative lifetimes as a crucial feature enabling high efficiencies. Long non-radiative lifetimes occur if the…

材料科学 · 物理学 2018-09-21 Thomas Kirchartz , Tom Markvart , Uwe Rau , David A. Egger

Perovskite-based solar cells are promising due to their rapidly improving efficiencies, but suffer from instability issues. Recently it has been claimed that one of the key contributors to the instability of perovskite solar cells is ion…

应用物理 · 物理学 2019-04-29 Boris Rivkin , Paul Fassl , Qing Sun , Alexander D. Taylor , Zhuoying Chen , Yana Vaynzof

The outstanding photovoltaic performances of lead halide perovskite (LHP) thin film solar cells are due in particular to the large diffusion length of photocarriers. The mechanism behind this property and its dependence on the various…

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