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We used microcontact printing to pattern a silicon surface with an iron-containing catalytic solution. Multi-wall carbon nanotubes were subsequently grown on the patterned areas by chemical vapor deposition at temperatures between 650 and…

材料科学 · 物理学 2015-07-20 Christian Klinke , Ralph Kurt , Jean-Marc Bonard , Klaus Kern

Electrocatalysis is greatly influenced by the local reaction environment, which is governed by the structure of the catalyst, the distribution of the electrolyte, and the local electric field. In catalytic systems comprised of complex…

化学物理 · 物理学 2026-04-24 Dustin Vivod , Binny A. Davis , Tobias Binninger , Michael Eikerling

Nanoscopic heterogeneities in composition and structure are quintessential for the properties of electrocatalyst materials. Here, we present a semiclassical model to study the electrochemical properties of supported electrocatalyst…

材料科学 · 物理学 2025-02-27 Yufan Zhang , Tobias Binninger , Jun Huang , Michael Eikerling

Carbon nanotubes (CNTs) are a one-dimensional material system with intriguing physical properties that lead to emerging applications. While CNTs are unusually strain resistant compared to bulk materials, their optical-absorption spectrum is…

计算物理 · 物理学 2019-02-22 Christian Wagner , Jörg Schuster , André Schleife

Electrospinning in controlled nitrogen atmosphere is developed for the realization of active polymer nanofibers. Fibers electrospun under controlled atmospheric conditions are found to be smoother and more uniform than samples realized by…

材料科学 · 物理学 2015-11-17 Vito Fasano , Maria Moffa , Andrea Camposeo , Luana Persano , Dario Pisignano

Identifying the three-dimensional (3D) crystal-plane and strain-field distributions of nanocrystals is essential for optical, catalytic, and electronic applications. Here, we developed a methodology for visualizing the 3D information of…

High electric fields can significantly alter catalytic environments and the resultant chemical processes. Such fields arise naturally in biological systems but can also be artificially induced through localized excitations at nanoscale.…

This work describes a methodology for producing high quality metallic surfaces from uranium primarily for characterisation and investigations involving electron backscatter diffraction. Electrochemical measurements have been conducted to…

材料科学 · 物理学 2018-03-16 JE Sutcliffe , JR Petherbridge , T Cartwright , R Springell , TB Scott , JE Darnbrough

The activity and stability of a platinum nanoparticle (NP) is not only affected by its size but additionally depends on its shape. To this end, simulations can identify structure-property relationships to make a priori decisions on the most…

化学物理 · 物理学 2022-03-25 Björn Kirchhoff , Christoph Jung , Hannes Jónsson , Donato Fantauzzi , Timo Jacob

Near Ambient Pressure Scanning Photoelectron Microscopy adds to the widely used photoemission spectroscopy and its chemically selective capability two key features: (i) the possibility to chemically analyse samples in a more realistic…

The influence of triaxial in-plane strain on the electronic properties of a hexagonal boron-nitride sheet is investigated using density functional theory. Different from graphene, the triaxial strain localizes the molecular orbitals of the…

介观与纳米尺度物理 · 物理学 2013-09-13 M. Neek-Amal , J. Beheshtian , A. Sadeghi , K. H. Michel , F. M. Peeters

Supported metal nanoparticle (NP) catalysts are vital for the sustainable production of chemicals, but their design and implementation are limited by the ability to identify and characterize their structures and atomic sites that are…

Undoubtedly, Raman spectroscopy is one of the most elaborated spectroscopy tools in materials science, chemistry, medicine and optics. However, when it comes to the analysis of nanostructured specimens, accessing the Raman spectra resulting…

Controlling the spatial distribution of liquid droplets on surfaces via surface energy patterning can be used to control material delivery to specified regions via selective liquid/solid wetting. While studies of the equilibrium shape of…

软凝聚态物质 · 物理学 2007-05-23 Gary S. Grest , David R. Heine , Edmund B. Webb

Strain has emerged as a promising approach for tuning electrocatalytic properties, yet its role in sputter-deposited thin films remains poorly understood. In this work, magnetron-sputtered platinum (Pt) thin films with different stress…

Functional properties of nanomaterials strongly depend on their surface atomic structure, but they often become largely different from their bulk structure, exhibiting surface reconstructions and relaxations. However, most of the surface…

材料科学 · 物理学 2021-10-01 Juhyeok Lee , Chaehwa Jeong , Yongsoo Yang

The local variation in inter-atomic distances, or local lattice strain often influences significantly material properties of nanoparticles. Strain measurement with ~1% precision is provided by recent atomic-resolution electron microscopy.…

材料科学 · 物理学 2021-07-09 Kohei Aso , Jens Maebe , Xuan Quy Tran , Tomokazu Yamamoto , Yoshifumi Oshima , Syo Matsumura

Near-field enhanced, nano-Raman spectroscopy has been successfully used to probe the surface chemistry of silicon prepared using standard wafer cleaning and processing techniques. The results demonstrate the utility of this measurement for…

材料科学 · 物理学 2010-02-16 P. G. Spizzirri , J. -H. Fang , S. Rubanov , E. Gauja , S. Prawer

A magnetite (Fe3O4) single crystal (111) surface has been studied at various oxygen-iron surface stoichiometries. The stoichiometry was modified by controlling the in-situ sample anneal conditions. We have found the conditions that lead to…

软凝聚态物质 · 物理学 2007-05-23 N. Berdunov , S. Murphy , G. Mariotto , I. V. Shvets

Microplasmas can be used for a wide range of technological applications and to improve our understanding of fundamental physics. Scanning electron microscopy, on the other hand, provides insights into the sample morphology and chemistry of…