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The one-photon absorption cross section of nanocrystals (NCs) of the inorganic perovskite CsPbBr$_{3}$ is studied theoretically using a multiband $\mathbf{k}\cdot\mathbf{p}$ envelope-function model combined with a treatment of intercarrier…

介观与纳米尺度物理 · 物理学 2020-05-11 T. P. T. Nguyen , S. A. Blundell , C. Guet

Because of their conveniently tunable optoelectronic properties, semiconductor nanocrystals have become established components for new devices and emergent technologies, in a broad range of applications which include agriculture, medicine,…

介观与纳米尺度物理 · 物理学 2024-10-01 Carlos A. Bohórquez-Quincos , Julián G. Cordero-Niño , Hanz Y. Ramírez-Gómez

Atomistically detailed computational studies of nanocrystals, such as those derived from the promising lead-halide perovskites, are challenging due to the large number of atoms and lack of symmetries to exploit. Here, focusing on…

材料科学 · 物理学 2022-10-05 Giulia Biffi , Yeongsu Cho , Roman Krahne , Timothy C. Berkelbach

We calculate the shift in emission frequency of the trion and biexciton (relative to that of the single exciton) for nanocrystals (NCs) of inorganic perovskites CsPbBr3 and CsPbI3. The calculations use an envelope-function k.p model…

介观与纳米尺度物理 · 物理学 2020-03-26 T. P. T. Nguyen , S. A. Blundell , C. Guet

Understanding exciton-exciton interaction in multiply-excited nanocrystals is crucial to their utilization as functional materials. Yet, for lead halide perovskite nanocrystals, which are promising candidates for nanocrystal-based…

Excitons consist of electrons and holes held together by their attractive Coulomb interaction. Although excitons are neutral excitations, spatial fluctuations in their charge density couple with the ions of the crystal lattice. This…

材料科学 · 物理学 2024-01-18 Zhenbang Dai , Chao Lian , Jon Lafuente-Bartolome , Feliciano Giustino

We present a theory of highly excited interacting carriers confined in a semiconductor nanostructure, incorporating Auger coupling between excited states with different number of excitations. The Coulomb matrix elements connecting exciton,…

介观与纳米尺度物理 · 物理学 2015-05-30 Marek Korkusinski , Oleksandr Voznyy , Pawel Hawrylak

The optical spectra of CdSe nanocrystals up to 55 A in diameter are analyzed in a wide range of energies from the fine structure of the low-energy excitations to the so-called high-energy transitions. We apply a symmetry-based method in two…

介观与纳米尺度物理 · 物理学 2009-11-07 J. Perez-Conde , A. K. Bhattacharjee

We derive the matrix elements of Coulomb interaction between states with different number of electrons and holes in a semiconductor nanocrystal within the 8-band $\mathbf{k}\cdot\mathbf{p}$ theory. These matrix elements are responsible for…

介观与纳米尺度物理 · 物理学 2015-06-11 Maryam Azizi , Paweł Machnikowski

We report on a multiband microscopic theory of many-exciton complexes in self-assembled quantum dots. The single particle states are obtained by three methods: single-band effective-mass approximation, the multiband $k\cdot p$ method, and…

材料科学 · 物理学 2009-11-10 Weidong Sheng , Shun-Jen Cheng , Pawel Hawrylak

We propose a method for calculating Coulomb matrix elements between exciton and biexciton states in semiconductor nanocrystals based on the envelope function formalism. We show that such a calculation requires proper treatment of the Bloch…

介观与纳米尺度物理 · 物理学 2015-06-11 Piotr Kowalski , Łukasz Marcinowski , Paweł Machnikowski

A Hartree-Fock and Hartree-Fock-Bogoliubov study of a few body system of spatially separated charge carriers was carried out. Using these variational states, we compute an approximation to the correlation energy of a finite system of…

介观与纳米尺度物理 · 物理学 2009-11-30 Ian Mondragon-Shem , Francisco E. Lopez , Boris A. Rodriguez

Excitons in the weakly interacting regime can be well-described by many-body perturbation theories such as the Bethe-Salpeter equation formalism. However, for materials such as transition metal dichalcogenides moir\'e heterostructures under…

材料科学 · 物理学 2026-03-16 Fangzhou Zhao , Carlos Mejuto-Zaera , Angel Rubio , Vojtěch Vlček

Single-walled carbon nanotubes are strongly correlated systems with large Coulomb repulsion between two electrons occupying the same $p_z$ orbital. Within a molecular Hamiltonian appropriate for correlated $\pi$-electron systems, we show…

材料科学 · 物理学 2009-02-15 Zhendong Wang , Demetra Psiachos , Roberto F. Badilla , Sumit Mazumdar

Colloidal semiconductor nanoplatelets, in which carriers are strongly confined only along one dimension, present fundamentally different excitonic properties than quantum dots, which support strong confinement in all three dimensions. In…

介观与纳米尺度物理 · 物理学 2020-01-08 Daniel Amgar , Gaoling Yang , Ron Tenne , Dan Oron

Lead halide perovskite nanocrystals are promising materials for classical and quantum light emission. To understand these outstanding properties, a thorough analysis of the band-edge exciton emission is needed which is not reachable in…

介观与纳米尺度物理 · 物理学 2023-04-07 Mohamed-Raouf Amara , Zakaria Said , Caixia Huo , Aurélie Pierret , Christophe Voisin , Weibo Gao , Qihua Xiong , Carole Diederichs

Exciton-phonon interactions govern the energy level spectrum and thus the optical response in semiconductors. In this respect, lead-halide perovskite nanocrystals represent a unique system, for which the interaction with optical phonons is…

The description of carrier dynamics in spatially confined semiconductor nanocrystals (NCs), which have enhanced electron-hole and exciton-phonon interactions, is a great challenge for modern computational science. These NCs typically…

材料科学 · 物理学 2022-11-01 Dipti Jasrasaria , Daniel Weinberg , John P. Philbin , Eran Rabani

Coherent manipulation of the exciton wave function in a single semiconductor colloidal nanocrystal (NC) has been actively pursued in the past decades without any success, mainly due to the bothersome existences of the spectral diffusion and…

介观与纳米尺度物理 · 物理学 2019-07-24 Yan Lv , Chunyang Yin , Chunfeng Zhang , William W. Yu , Xiaoyong Wang , Yu Zhang , Min Xiao

We use a configuration interaction approach within the envelope function approximation to study the nature of the excitonic resonance in nano-hybrids, composite nanoparticles (NPs) combining a semiconducting and a metallic segment in…

介观与纳米尺度物理 · 物理学 2011-07-25 Juan I. Climente , Jose L. Movilla , Guido Goldoni , Josep Planelles
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