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We provide strong numerical evidence for a hidden multihyperuniform long-range order (MHLRO) in SiGeSn medium-entropy alloys (MEAs), in which the normalized infinite-wavelength composition fluctuations for all three atomic species are…

材料科学 · 物理学 2021-11-23 Duyu Chen , Xinyu Jiang , Duo Wang , Houlong Zhuang , Yang Jiao

Traditional metallic alloys are mixtures of elements where the atoms of minority species tend to distribute randomly if they are below their solubility limit, or lead to the formation of secondary phases if they are above it. Recently, the…

Recent research in multi-principal element alloys (MPEAs) has increasingly focused on the exploration and exploitation of short-range order (SRO) to enhance material performance. However, the understanding of SRO formation and the precise…

Chemical short-range order (SRO) refers to preference or avoidance between neighboring atomic species, which significantly impacts the properties of advanced alloys. However, quantifying and further controlling SRO remains a major…

Metallic alloys are routinely subjected to nonequilibrium processes during manufacturing, such as rapid solidification and thermomechanical processing. It has been suggested in the high-entropy alloy literature that chemical short-range…

材料科学 · 物理学 2025-10-10 Mahmudul Islam , Killian Sheriff , Yifan Cao , Rodrigo Freitas

Short-range ordering (SRO) tendency for disordered alloys is considered as competition between chemical ordering and geometric (mainly, difference in atomic radius for constituents) effects. Especially for multicomponent (including the…

材料科学 · 物理学 2019-05-22 Koretaka Yuge , Shouno Ohta

This paper studies short-range order (SRO) in the semiconductor alloy (GaN)$_{1-x}$(ZnO)$_x$. Monte Carlo simulations performed on a density functional theory (DFT)-based cluster expansion model show that the heterovalent alloys exhibit…

材料科学 · 物理学 2016-06-03 Jian Liu , Maria V. Fernández-Serra , Philip B. Allen

Metallic alloys often form phases - known as solid solutions - in which chemical elements are spread out on the same crystal lattice in an almost random manner. The tendency of certain chemical motifs to be more common than others is known…

材料科学 · 物理学 2024-06-21 Killian Sheriff , Yifan Cao , Tess Smidt , Rodrigo Freitas

High-entropy alloys (HEAs) composed of multiple principal elements have been shown to offer improved radiation resistance over their elemental or dilute-solution counterparts. Using NiCoFeCrMn HEA as a model, here we introduce carbon and…

材料科学 · 物理学 2023-01-03 Zhengxiong Su , Jun Ding , Miao Song , Li Jiang , Tan Shi , Zhiming Li , Sheng Wang , Fei Gao , Di Yun , Chenyang Lu , En Ma

In high-entropy alloys (HEAs), the local chemical fluctuations from disordered solute solution state into segregation, precipitation and ordering configurations are complex due to the large number of elements. In this work, the cluster…

材料科学 · 物理学 2017-05-05 A. Fernandez-Caballero , J. S. Wrobel , P. M. Mummery , D. Nguyen-Manh

High-entropy alloys (HEAs), which have been intensely studied due to their excellent mechanical properties, generally refer to alloys with multiple equimolar or nearly equimolar elements. According to this definition, Si-Ge-Sn alloys with…

材料科学 · 物理学 2020-01-08 D. Wang , L. Liu , W. Huang , H. L. Zhuang

We investigate the effect of short-range order (SRO) on the electronic structure in alloys from the theoretical point of view using density of states (DOS) data. In particular, the interaction between the atoms at different lattice sites is…

High-entropy alloys (HEAs) were presumed to have a configurational entropy as high as that of an ideally mixed solid solution (SS) of multiple elements in near-equal proportions. However, enthalpic interactions inevitably render such…

材料科学 · 物理学 2019-09-11 Qing-Jie Li , Howard Sheng , Evan Ma

Electrical and thermal transport properties of disordered materials have long been of both theoretical interest and engineering importance. As a new class of materials with an intrinsic compositional disorder, high/medium-entropy alloys…

材料科学 · 物理学 2020-09-07 Duo Wang , Lei Liu , Mohan Chen , Houlong Zhuang

We investigate the short-range order (SRO) and phase stability of the equiatomic CoCrFeMnNi high-entropy alloy using cluster expansion supplemented by an eigen-decomposition analysis of the SRO parameters. Our results reveal that the…

材料科学 · 物理学 2026-05-19 Wei Chen , Gian-Marco Rignanese , Geoffroy Hautier

Chemical short-range order (SRO) affects the distribution of elements throughout the solid-solution phase of metallic alloys, thereby modifying the background against which microstructural evolution occurs. Investigating such…

材料科学 · 物理学 2024-07-10 Yifan Cao , Killian Sheriff , Rodrigo Freitas

High-entropy alloys (HEAs) are an intriguing new class of metallic materials due to their unique mechanical behavior. Achieving a detailed understanding of structure-property relationships in these materials has been challenged by the…

材料科学 · 物理学 2018-10-24 Jun Ding , Qin Yu , Mark Asta , Robert O. Ritchie

The functional properties of semiconductors are typically controlled by tailoring their chemical composition and their state of strain, and by controlling their long-range structural order, including the presence of extended defects such as…

Medium- and high-entropy alloys (M/HEAs) mix multiple principal elements with near-equiatomic composition and represent a paradigm-shift strategy for designing new materials for metallurgy, catalysis, and other fields. One of the core…

An idealized high entropy oxide is characterized by perfect chemical disorder and perfect positional order. In this work, we investigate the extent to which short-range order (SRO) and local structural distortions impede that idealized…

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