相关论文: Terminal stage of highly viscous flow
The shear flow and the dielectric alpha-process in molecular glass formers is modeled in terms of local structural rearrangements which reverse a strong local shear. Using Eshelby's solution of the corresponding elasticity theory problem…
The recent theoretical treatment of irreversible jumps between inherent states with a constant density in shear space is extended to a full theory, attributing the shear relaxation to structural Eshelby rearrangements involving the creation…
The recent description of the highly viscous flow in terms of irreversible structural Eshelby rearrangements is extended to calculate the heat capacity of a glass former at a constant cooling rate through the glass transition. The result is…
The paper derives a relation for the viscosity of undercooled liquids on the basis of the pragmatical model concept of Eshelby relaxations with a finite lifetime. From accurate shear relaxation data in the literature, one finds that…
We study the rheology of a suspension of soft deformable droplets subjected to a pressure-driven flow. Through computer simulations, we measure the apparent viscosity as a function of droplet concentration and pressure gradient, and provide…
A recent description of the highly viscous flow ascribes it to irreversible thermally activated Eshelby transitions, which transform a region of the undercooled liquid to a different structure with a different elastic misfit to the…
The ratio between the couplings of a relaxational process to compression and shear, respectively, is calculated in the Eshelby picture of structural rearrangements within a surrounding elastic matrix, assuming a constant density of stable…
The asymmetry model for the highly viscous flow postulates thermally activated jumps from a practically undistorted ground state to strongly distorted, but stable structures, with a pronounced Eshelby backstress from the distorted…
Despite the viscosity of a fluid ranges over several orders of magnitudes and is extremely sensitive to microscopic structure and molecular interactions, it has been conjectured that its (opportunely normalized) minimum displays a universal…
The structure, thermodynamics and slow activated dynamics of the equilibrated metastable regime of glass-forming fluids remains a poorly understood problem of high theoretical and experimental interest. We apply a highly accurate…
In this paper we study the convergence of a power-law model for dilatant compressible fluids to a class of models exhibiting a maximum admissible shear rate, called thick compressible fluids. These kinds of problems were studied previously…
The glass transition in hydrogen-bonded glass formers differs from the glass transition in other glass formers. The Eshelby rearrangements of the highly viscous flow are superimposed by strongly asymmetric hydrogen bond rupture processes,…
Complex fluids exhibit time-dependent changes in viscosity that have been ascribed to both thixotropy and aging. However, there is no consensus for which phenomenon is the origin of which changes. A novel thixotropic model is defined that…
The properties of semidilute polymer solutions are investigated at equilibrium and under shear flow by mesoscale simulations, which combine molecular dynamics simulations and the multiparticle collision dynamics approach. In semidilute…
We analyze the behavior of supercooled fluids under shear both theoretically and numerically. Theoretically, we generalize the mode-coupling theory of supercooled fluids to systems under stationary shear flow. Our starting point is the set…
We study the fully nonlinear, nonlocal dynamics of two-dimensional multicomponent vesicles in a shear flow with matched viscosity of the inner and outer fluids. Using a nonstiff, pseudo-spectral boundary integral method, we investigate…
In this contribution we summarize recent progress in understanding the shear viscosity of strongly correlated dilute Fermi gases. We discuss predictions from kinetic theory, and show how these predictions can be tested using recent…
The deformation of an elastic micro-capsule in an infinite shear flow is studied numerically using a spectral method. The shape of the capsule and the hydrodynamic flow field are expanded into smooth basis functions. Analytic expressions…
Buoyancy-driven turbulent convection leads to a fully compressible flow with a strong top-down asymmetry of first- and second-order statistics when the adiabatic equilibrium profiles of temperature, density and pressure decay very strongly…
The recent Eshelby description of the highly viscous flow leads to the prediction of a factor of two different viscosities in stationary and alternating flow, in agreement with experimental evidence. The Kohlrausch barrier density increase…