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In the study of open quantum systems, the polaron transformation has recently attracted a renewed interest as it offers the possibility to explore the strong system-bath coupling regime. Despite this interest, a clear and unambiguous…

量子物理 · 物理学 2016-05-04 Chee Kong Lee , Jeremy Moix , Jianshu Cao

We derive a many-site version of the non-Markovian time-convolutionless polaron master equation [S. Jang et al., J. Chem Phys. 129, 101104 (2008)] to describe electronic excitation dynamics in multichromophoric systems. By treating…

量子物理 · 物理学 2015-05-28 Avinash Kolli , Ahsan Nazir , Alexandra Olaya-Castro

Many optically active systems possess spatially asymmetric electron orbitals. These generate permanent dipole moments, which can be stronger than the corresponding transition dipole moments, significantly affecting the system dynamics and…

量子物理 · 物理学 2023-04-21 Adam Burgess , Marian Florescu , Dominic Michael Rouse

In the context of Frenkel exciton dynamics in aggregated molecules the polaron transformation technique facilitates a treatment where diagonal elements attributed to electronic excited-state populations are decoupled from fluctuations…

化学物理 · 物理学 2021-08-30 Joachim Seibt , Oliver Kühn

We apply the Dynamical Mean Field Theory to calculate the low-density limit of the optical conductivity in the Holstein model. This non perturbative treatment allows to span continuously from the weak-coupling quasi-free electron behaviour…

强关联电子 · 物理学 2007-05-23 S. Fratini F. de Pasquale S. Ciuchi

Unitary transformations can allow one to study open quantum systems in situations for which standard, weak-coupling type approximations are not valid. We develop here an extension of the variational (polaron) transformation approach to open…

Organic semiconductors have the remarkable property that their optical excitation not only generates charge-neutral electron-hole pairs (excitons) but also charge-separated polaron pairs with high yield. The microscopic mechanisms…

The main purpose of this paper is to obtain analytical solutions for radiative transfer equations related to the vertical structure of accretion discs with finite optical depth. In the non-gray atmosphere, we employ the optical-depth…

高能天体物理现象 · 物理学 2020-06-24 Maryam Samadi , Fahimeh Habibi , Shahram Abbassi

In this work, we develop an optomechanical formalism for macroscopic quantum states in exciton-polariton systems with strong exciton-phonon interactions. We show that polariton optomechanical interactions induce dynamical backaction,…

量子气体 · 物理学 2024-10-31 Vladislav Yu. Shishkov , Evgeny S. Andrianov , Anton V. Zasedatelev

Strong light-matter coupling to form exciton- and vibropolaritons is increasingly touted as a powerful tool to alter the fundamental properties of organic materials. It is proposed that these states and their facile tunability can be used…

Path-integral approach to the tight-binding polaron is extended to multiple optical phonon modes of arbitrary dispersion and polarization. The non-linear lattice effects are neglected. Only one electron band is considered. The…

强关联电子 · 物理学 2009-11-11 Pavel Kornilovitch

When a quantum system couples strongly to multiple baths then it is generally no longer possible to describe the resulting system dynamics by simply adding the individual effects of each bath. However, capturing such multi-bath system…

Hybridisation of the cavity modes and the excitons to polariton states together with the coupling to the vibrational modes determine the linear optical properties of organic semiconductors in microcavities. In this article we compute the…

We determine the phase diagram of a polaron model with mixed breathing-mode and Su-Schrieffer-Heeger couplings and show that it has two sharp transitions, in contrast to pure models which exhibit one (for Su-Schrieffer-Heeger coupling) or…

量子气体 · 物理学 2013-05-31 Felipe Herrera , Kirk W. Madison , Roman V. Krems , Mona Berciu

Polariton chemistry holds promise for facilitating mode-selective chemical reactions, but the underlying mechanism behind the rate modifications observed under vibrational strong coupling is not well understood. Using the recently developed…

化学物理 · 物理学 2023-08-22 Michelle C. Anderson , Esmae J. Woods , Thomas P. Fay , David J. Wales , David T. Limmer

Polaritons, mixed light-matter quasiparticles, undergo a transition to a condensed, macroscopically coherent state at low temperatures or high densities. Recent experiments show that coupling light to organic molecules inside a microcavity…

量子气体 · 物理学 2014-03-06 Justyna A. Cwik , Sahinur Reja , Peter B. Littlewood , Jonathan Keeling

We investigate the impact of the quantized mechanical motion of optically trapped atoms, arranged in proximity to a one-dimensional waveguide, on the propagation of polariton modes. Our study identifies a regime of resonant phonon-assisted…

量子气体 · 物理学 2024-11-28 Denis Ilin , Alexander S. Solntsev , Ivan Iorsh

We introduce an analytical framework for near-field radiative heat transfer in bulk plasmonic and polar media. Considering material dispersion, we derive a closed-form expression for the radiative thermal conductance, which disentangles the…

光学 · 物理学 2023-04-21 Mariano Pascale , Georgia T. Papadakis

The optical properties of polarons are studied in the framework of the Holstein model by applying the dynamical mean-field theory. This approach allows to enlighten important quantitative and qualitative deviations from the limiting…

强关联电子 · 物理学 2009-11-11 S. Fratini , S. Ciuchi

We present a fully microscopic approach to the transition rate of two exciton-photon polaritons. The non-trivial consequences of the polariton composite nature -- here treated exactly through a development of our composite-exciton many-body…

介观与纳米尺度物理 · 物理学 2009-11-13 M. Combescot , M. -A. Dupertuis , O. Betbeder-Matibet
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