相关论文: Determining Reaction Pathways at Low Temperatures …

We have performed chemical probing spectroscopy of H3+ ions trapped in a cryogenic 22-pole ion trap. The ions were buffer-gas cooled to 55K by collisions with helium and argon. Excitation to states above the barrier to linearity was…

The formation of CO2 in quiescent regions of molecular clouds is not yet fully understood, despite CO2 having an abundance of around 10-34 % H2O. We present a study of the formation of CO2 via the non-energetic route CO + OH on non-porous…

The efficiency of laser-cooling relies on the existence of an almost closed optical-transition cycle in the energy spectrum of the considered species. In this respect rare-earth elements exhibit many transitions which are likely to induce…

The $^{133}\mathrm{Ba}^+$ ion is a promising candidate as a high-fidelity qubit, and the $^{137}\mathrm{Ba}^+$ isotope is promising as a high-fidelity qudit ($d>2$). Barium metal is very reactive, and $^{133}\mathrm{Ba}^+$ is radioactive…

Ultracold hybrid ion-atom traps offer the possibility of microscopic manipulation of quantum coherences in the gas using the ion as a probe. However, inelastic processes, particularly charge transfer can be a significant process of ion loss…

We report on the production of cold, state-selected H$_2^+$ molecular ions in a linear RF trap. The ions are produced by (3+1) resonance-enhanced multi-photon ionisation (REMPI) of H$_2$, and sympathetically cooled by laser-cooled Be$^+$…

The thermal fit to preliminary HADES data of Au+Au collisions at $\sqrt{s_{_{NN}}}=2.4$ GeV shows two degenerate solutions at $T\approx50$ MeV and $T\approx70$ MeV. The analysis of the same particle yields in a transport simulation of the…

The formation of Li$_2^+$ and subsequently Li$^+$ ions, during the excitation of $^7$Li atoms to the $3S_{1/2}$ state in a $^7$Li magneto optical trap (MOT), is probed in an ion-atom hybrid trap. Associative ionization occurs during the…

We calculated reaction rate constants including atom tunneling for the hydrogen abstraction reaction CH3OH+H -> CH2OH+H2 with the instanton method. The potential energy was fitted by a neural network, that was trained to…

Complex organic molecules (COMs) have been observed not only in the hot cores surrounding low- and high- mass protostars, but also in cold dark clouds. Therefore, it is interesting to understand how such species can be formed without the…

Trapping of atoms and molecules in electrostatic, magnetic and optical traps has enabled studying atomic and molecular interactions on a timescale of many seconds, allowing observations of ultra-cold collisions and reactions. Here we report…

The study of cold and controlled molecular ions is pivotal for fundamental research in modern physics and chemistry. Investigations into cooling molecular anions, in particular, have proven to be of key consequence for the production of…

Resolved sideband cooling is a standard technique for cooling trapped ions below the Doppler limit to near their motional ground state. Yet, the most common methods for sideband cooling implicitly rely on low Doppler-cooled temperatures and…

Molecular dynamics calculations have been performed to study the ultraviolet photodissociation of D2O in an amorphous D2O ice surface at 10-90 K, in order to investigate the influence of isotope effects on the photodesorption processes. As…

The most sensitive direct neutrino mass searches today are based on measurement of the endpoint of the beta spectrum of tritium to infer limits on the mass of the unobserved neutrino. To avoid the smearing associated with the distribution…

The interaction of CO with the Fe3O4(001)-(rt2xrt2)R45{\deg} surface was studied using temperature programmed desorption (TPD), scanning tunneling microscopy (STM) and x-ray photoelectron spectroscopy (XPS), the latter both under ultrahigh…

We report quantum dynamics calculations of the O + OH -> H + O2 reaction on two different representations of the electronic ground state potential energy surface (PES) using a time-independent quantum formalism based on hyperspherical…

Atoms and molecules often react at different rates depending on their internal quantum states. Thus, controlling which internal states are populated can be used to manipulate the reactivity and can lead to a more detailed understanding of…

We present a study of vibrational quenching and chemical processes of molecular ions immersed in an ultracold atomic gas by means of the quasi-classical trajectory (QCT) method. In particular, BaRb$^+(v)$ + Rb collisions are studied at cold…

The H3+ ion plays a key role in the chemistry of dense interstellar gas clouds where stars and planets are forming. The low temperatures and high extinctions of such clouds make direct observations of H3+ impossible, but lead to large…