相关论文: Determining Reaction Pathways at Low Temperatures …
Trapped ions have emerged as a front runner in quantum information processing due to their identical nature, all-to-all connectivity, and high fidelity quantum operations. As current trapped ion technologies are scaled, it will be important…
The gas-phase reaction of $\mathrm{O}+\mathrm{H}_3^+$ has two exothermic product channels, $\mathrm{OH}^+ +\mathrm{H}_2$ and $\mathrm{H}_2\mathrm{O}^+ +\mathrm{H}$. In the present study, we analyze experimental data from a merged-beams…
The formation of $^{40}$Ca$_2^+$ molecular ions is observed in a hybrid $^{40}$Ca magneto-optical and ion trap system. The molecular ion formation process is determined to be two-photon photo-associative ionization of ultracold $^{40}$Ca…
A prerequisite for laser cooling a molecular anion, which has not been achieved so far, is the precise knowledge of the relevant transition frequencies in the cooling scheme. To determine these frequencies we present a versatile method that…
Highly efficient, nearly deterministic, and isotope selective generation of Yb$^+$ ions by 1- and 2-color photoionization is demonstrated. State preparation and state selective detection of hyperfine states in \ybodd is investigated in…
We report the sympathetic cooling and Coulomb crystallization of molecular ions above the surface of an ion-trap chip. N$_2^+$ and CaH$^+$ ions were confined in a surface-electrode radiofrequency ion trap and cooled by the interaction with…
Astrochemical models of interstellar clouds, the sites of stars, and planet formation require information about spin-state chemistry to allow quantitative comparison with spectroscopic observations. In particular, it is important to know if…
We investigate the dynamics of an ion sympathetically cooled by another laser-cooled ion or small ion crystal. To this end, we develop simple models of the cooling dynamics in the limit of weak Coulomb interactions. Experimentally, we…
We produce large numbers of low-energy ions by photoionization of laser-cooled atoms inside a surface-electrode-based Paul trap. The isotope-selective trap loading rate of $4\times10^{5}$ Yb$^{+}$ ions/s exceeds that attained by…
Irradiation of isolated water molecules by few-cycle pulses of intense infrared laser light can give rise to ultrafast rearrangement resulting in formation of the H2+ ion. Such unimolecular reactions occur on the potential energy surface of…
The electronic structure of the (LiYb)$^+$ molecular ion is investigated with two variants of the coupled cluster method restricted to single, double, and noniterative or linear triple excitations. Potential energy curves for the ground and…
We study inelastic processes in the hybrid quantum system constituted by a carbon nanotube (CNT) in contact with an ultracold quantum gas, such as a cloud of thermal atoms or a Bose-Einstein condensate (BEC). We present a parameter-free…
The present study experimentally demonstrated that solid H2O is formed through the surface reaction OH + H2 at 10 K. This is the first experimental evidence of solid H2O formation using hydrogen in its molecular form at temperatures as low…
The formation of interstellar water has been commonly accepted to occur on the surfaces of icy dust grains in dark molecular clouds at low temperatures (10-20 K), involving hydrogenation reactions of oxygen allotropes. As a result of the…
We investigate the Bose-Einstein condensation (BEC, superfluidity) of particle-hole pairs in ultracold Fermionic atoms with repulsive interactionsand arbitrary polarization, which are trapped within optical lattices. Near a Feshbach…
We study cold heteronuclear atom ion collisions by immersing a trapped single ion into an ultracold atomic cloud. Using ultracold atoms as reaction targets, our measurement is sensitive to elastic collisions with extremely small energy…
Recently, the principle of \textit{passivity} has been used to set bounds on the evolution of a microscopic quantum system with a thermal initial state. In this work, we experimentally demonstrate the utility of two passivity based…
We study ultracold collisions of ions with neutral atoms in traps. Recently, ultracold atom-ion systems are becoming available in experimental setups, where their quantum states can be coherently controlled. This allows for an…
Cryogenic 22-pole ion traps have found many applications in ion-molecule reaction kinetics and in high resolution molecular spectroscopy. For most of these applications it is important to know the translational and internal temperatures of…
We experimentally demonstrate cooling of trapped ions by collisions with co-trapped, higher mass neutral atoms. It is shown that the lighter $^{39}$K$^{+}$ ions, created by ionizing $^{39}$K atoms in a magneto-optical trap (MOT), when…