相关论文: Determining Reaction Pathways at Low Temperatures …
Isotope effects in reactions between Mg+ in the 3p 2P3/2 excited state and molecular hydrogen at thermal energies are studied through single reaction events. From only ~250 reactions with HD, the branching ratio between formation of MgD+…
Recent studies of neutral gas-phase reactions characterized by barriers show that certain complex forming processes involving light atoms are enhanced by quantum mechanical tunneling at low temperature. Here, we performed kinetic…
In this tutorial we review physical implementation of quantum computing using a system of cold trapped ions. We discuss systematically all the aspects for making the implementation possible. Firstly, we go through the loading and confining…
We use quantum and classical adiabatic capture theories to study the chemical reaction Li + CaH -> LiH + Ca. Using a recently developed ab initio potential energy surface, which provides an accurate representation of long-range interactions…
We measure chemical reactions between a single trapped $^{174}$Yb$^+$ ion immersed in an ultracold bath of $^6$Li atoms containing trace amounts of Li$_2$ dimers. This produces LiYb$^+$ molecular ions that we detect via mass spectrometry.…
A mixed system of cooled and trapped, ions and atoms, paves the way for ion assisted cold chemistry and novel many body studies. Due to the different individual trapping mechanisms, trapped atoms are significantly colder than trapped ions,…
The triatomic hydrogen ion H3+ is one of the most important species for the gas phase chemistry of the interstellar medium. Observations of H3+ are used to constrain important physical and chemical parameters of interstellar environments.…
Hybrid systems of laser-cooled trapped ions and ultracold atoms combined in a single experimental setup have recently emerged as a new platform for fundamental research in quantum physics. This paper reviews the theoretical and experimental…
We study the thermodynamical properties of crystals of trapped ions which are laser cooled to two different temperatures in two separate regions. We show that these properties strongly depend on the structure of the ion crystal. Such…
Cryogenic buffer gas sources are ubiquitous for producing cold, collimated molecular beams for quantum science, chemistry, and precision measurements. The molecules are typically produced by laser ablating a metal target in the presence of…
We report on a study of the exchange tunneling reaction D+HD$\rightarrow$D$_{2}$+H in a pure solid HD matrix and in a D$_{2}$ matrix with 0.23$\%$ HD admixture at temperatures between 130$\,$mK and 1.5$\,$K. We found that the exchange…
We present a combined experimental and theoretical study of cold reactive collisions between laser-cooled Ca+ ions and Rb atoms in an ion-atom hybrid trap. We observe rich chemical dynamics which are interpreted in terms of non-adiabatic…
Sympathetic cooling of trapped ions has become an indispensable tool for quantum information processing and precision spectroscopy. In the simplest situation a single Doppler-cooled ion sympathetically cools another ion which typically has…
We review recent progress in the field of cold trapped molecular ions. A new generation of collision and cold chemistry experiments between atoms and ions has emerged, where cold atoms and ions are brought into contact in a controlled way…
We have measured the reaction of O + H3+ forming OH+ and H2O+. This is one of the key gas-phase astrochemical processes initiating the formation of water molecules in dense molecular clouds. For this work, we have used a novel merged…
Aims. The purpose of this study is to examine the prediction that the deuterated H3+ ion, H2D+, can be found exclusively in the coldest regions of molecular cloud cores. This is also a feasibility study for the detection of the ground-state…
We investigate the interaction of a laser-cooled trapped ion (Ba$^+$ or Rb$^+$) with an optically confined $^{87}$Rb Bose-Einstein condensate (BEC). The system features interesting dynamics of the ion and the atom cloud as determined by…
Atomic oxygen in its first excited singlet state, O(1 D), is an important species in the photochemistry of several planetary atmospheres and has been predicted to be a potentially important reactive species on interstellar ices. Here, we…
Water dimer $(\text{H}_2\text{O})_2$ -- a vital component of the earth's atmosphere -- is an important prototypical hydrogen-bonded system. It provides direct insight into fundamental chemical and biochemical processes, e.g., proton…
We present a theoretical investigation of the hydrated hydroxide anion clusters OH(H$_{2}$O)$_{n}^{-}$ and of the collisional complexes H-OH(H$_{2}$O)$_{n}^{-}$ and Rb-OH(H$_{2}$O)$_{n}^{-}$ (with n$=1-4$). The MP2 and CCSD(T) methods are…