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Thermoelectric (Bi1-x Sbx)2Te3 (BST-x) compounds with x=0.2, 0.7 and 0.9 have been studied using synchrotron angle-dispersive powder x-ray diffraction in a diamond anvil cell up to 25 GPa (at room temperature). The results clearly indicate…

BaFe2Se3 (Pnma, CsAg2I3-type structure), recently assumed to show superconductivity at ~ 11 K, exhibits a pressure-dependent structural transition to the CsCu2Cl3-type structure (Cmcm space group) around 60 kbar, as evidenced from…

This article reports the synthesis of a single crystalline mixed topological insulator (TI) BiSbTe$_3$ and its detailed structural and magneto-transport properties. The single crystalline samples of BiSbTe$_3$ are grown by the melt-growth…

材料科学 · 物理学 2025-06-02 Dinesh Kumar , Kapil Kumar , N. K. Karn , Ganesh Gurjar , V. P. S. Awana , Sudesh

Single crystals of Bi$_{2} $Rh$ _{3}$S$ _{2}$ and Bi$_{2} $Rh$ _{3.5}$S$ _{2}$ were synthesized by solution growth and the crystal structures, thermodynamic and transport properties of both compounds were studied. In the case of Bi$_{2}…

The reliable calculation of electronic structures and understanding of electrical properties depends on an accurate model of the crystal structure. Here, we have reinvestigated the crystal structure of the high-zT thermoelectric material…

材料科学 · 物理学 2018-08-14 I. Loa , S. R. Popuri , A. D. Fortes , J. W. G. Bos

We report a thermal transport study of IrSbSe, which crystallizes in a noncentrosymmetric cubic structure with the $P2_13$ space group and shows a narrow-gap semiconducting behavior. The large discrepancy between the activation energy for…

强关联电子 · 物理学 2022-11-08 Yu Liu , Milinda Abeykoon , Niraj Aryal , David Graf , Zhixiang Hu , Weiguo Yin , C. Petrovic

We report electrical and thermal transport properties of polycrystalline ZrTe3. The polycrystalline sample shows semiconducting behavior in contrast to the established semi-metallic character of the compound. However the charge density wave…

强关联电子 · 物理学 2019-01-23 M. K. Hooda , T. S. Tripathi , C. S. Yadav

The glassy thermal conductivities observed in crystalline inorganic perovskites such as Cs$_3$Bi$_2$I$_6$Cl$_3$ is perplexing and lacking theoretical explanations. Here, we first experimentally measure such its thermal transport behavior…

Topological Kondo insulator SmB6 has attracted quite a lot of attentions from condensed matter physics community. A number of unique electronic properties, including low- temperature resistivity anomaly, 1D electronic transport and 2D Fermi…

材料科学 · 物理学 2016-07-07 Zengji Yue , Qinjun Chen , Xiaolin Wang

Magnetoresistance and Hall resistance measurements have been carried out in fastcooled single crystals of Bi2Se3-xTex (x: 0 to 2) in 4 to 300 K temperature range, under magnetic fields up to 15 T. The variation of resistivity with…

材料科学 · 物理学 2016-02-17 E. P. Amaladass , T. R. Devidas , Shilpam Sharma , C. S. Sundar , A. Bharathi , Awadhesh Mani

Polycrystalline Sb 2 Te 3-x Se x (0.0 < x < 1.0) samples were synthesized by the solid state reaction method. The structural analysis showed that up to the maximal concentration of Se, the samples possess the Rhombohedral crystal symmetry…

Thermal variation of structural property, linear thermal expansion coefficient, resistivity, thermopower and power factor of polycrystalline Bi1-xSbx (x=0.10, 0.14) samples are reported. Temperature-dependent powder diffraction experiments…

材料科学 · 物理学 2013-12-16 K. Malik , Diptasikha Das , S. Bandyopadhyay , P. Mandal , A. K. Deb , Velaga Srihari , Aritra Banerjee

We report the characterization of the misfit compound (Pb1-xSnxSe2)1.16(TiSe2)2, in which a [100] rocksalt bilayer of Pb1-xSnxSe, which is a topological crystalline insulator in bulk form, alternates with a double layer of the normally…

超导电性 · 物理学 2016-05-25 Huixia Luo , Kai Yan , Weiwei Xie , Brendan F. Phelan , R. J. Cava

Structural and thermoelectric properties of metallic and semiconducting Sb2Te3 are reported. X-Ray diffraction and Raman spectroscopy studies reveal that semiconducting sample have higher defect density. Nature and origin of possible…

材料科学 · 物理学 2015-07-14 Diptasikha Das , K. Malik , A. K. Deb , Sandip Dhara , S. Bandyopadhyay , Aritra Banerjee

Ternary (Bi1-xSbx)2Te3 films with an Sb content between 0 and 100% were deposited on a Si(111) substrate by means of molecular beam epitaxy. X-ray diffraction measurements confirm single crystal growth in all cases. The Sb content is…

Temperature dependent crystal structures of the quasi-one-dimensional ladder material BaFe2Se3 are examined. Combining the optical second harmonic generation (SHG) experiments and neutron diffraction measurements, we elucidate the crystal…

We report on the synthesis and extensive characterization of layered Bi4O4S3 superconductor. This is the optimally doped sample with Tc ~5.3 K out of a series of Bi6O4S4(SO4)_1-x samples synthesized by solid state reaction. The series was…

超导电性 · 物理学 2013-04-17 P. Srivatsava , Shruti , S. Patnaik

Highly-strained BiFeO3 exhibits a "tetragonal-like, monoclinic" crystal structure found only in epitaxial films (with an out-of-plane lattice parameter exceeding the in-plane value by >20%). Previous work has shown that this phase is…

材料科学 · 物理学 2011-08-17 Wolter Siemons , Michael D. Biegalski , Joong Hee Nam , Hans M. Christen

Measurements of the electrical and thermal conductivities, thermopower and paramagnetic susceptibility have been performed on single crystal samples of Bi1/2Sr1/2MnO3 and complemented with the X-ray powder diffraction data. A pronounced…

强关联电子 · 物理学 2009-11-07 J. Hejtmanek , K. Knizek , Z. Jirak , M. Hervieu , C. Martin , M. Nevriva , P. Beran

Thermoelectric materials allow the direct conversion of waste heat into electricity, and novel materials are being investigated for this purpose. Recently, doped Bi$_2$O$_2$Se has shown high application potential. In this study, we discuss…

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