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We have investigated the $R$-site randomness effect of $R$/Ba-ordered $R$BaMn$_{2}$O$_{6}$ ($R$ = rare earth) by using Y$_{1-y}$La$_y$BaMn$_2$O$_6$ (0 (\leq) $y$ (\leq) 1) in which $R$ (Y,La) and Ba are regularly arranged while Y and La…

强关联电子 · 物理学 2015-05-14 Y. Miyauchi , S. Fukushima , J. Tozawa , M. Akaki , H. Kuwahara , D. Akahoshi

We study experimentally and theoretically the electronic and magnetic properties of two insulating double perovskites that show similar atomic and electronic structure, but different magnetic properties. In magnetization measurements,…

The La2CoMnO6 (LCMO) perovskite has received a lot of attention due to its near room temperature magnetodielectric effect. Despite the recent efforts, the mechanism ruling the correlation between its magnetic and dielectric properties is…

We present an inelastic neutron scattering study of the low energy crystal-field excitations in the lightly doped cobalt perovskite La_0.998Sr_0.002CoO_3. In contrast to the parent compound LaCoO_3 an inelastic peak at energy transfer ~0.75…

强关联电子 · 物理学 2008-02-22 A. Podlesnyak , K. Conder , E. Pomjakushina , A. Mirmelstein , P. Allenspach , D. I. Khomskii

Among multifunctional double perovskite oxides, La2NiMnO6 has recently drawn significant attention due to its importance both in terms of understanding of fundamental physics and potential for device applications. The relative alteration in…

The magnetic field affects the motion of electrons and the orientation of spins in solids, but it is believed to have little impact on the crystal structure. This common perception has been challenged recently by ferromagnetic shape-memory…

超导电性 · 物理学 2009-11-07 A. N. Lavrov , Seiki Komiya , Yoichi Ando

We investigate the physical properties and electronic structure upon Cr-doping in the iron arsenide layers of BaFe2As2. This form of hole-doping leads to suppression of the magnetic/structural phase transition in BaFe2-xCrxAs2 for x > 0,…

Rare earth based cobalt-ruthenium double perovskites A$_2$CoRuO$_6$ (A = La, Pr, Nd and Sm) were synthesized and investigated for their structural and magnetic properties. All the compounds crystallize in the monoclinic $P2_1/n$ structure…

材料科学 · 物理学 2019-07-24 Manjil Das , Prabir Dutta , Saurav Giri , Subham Majumdar

The synthesis and characterization of the previously unknown material LaCaScIrO$_6$ is reported. LaCaScIrO$_6$ presents a new example of the rare case of a double perovskite with the strongly spin-orbit coupled 5\textit{d}-ion Ir$^{4+}$ as…

We report the magnetic susceptibility and NMR studies of a spin-gapped layered compound Na2Cu2TeO6 (the spin gap $\Delta\sim$ 250 K), the hole doping effect on the Cu2TeO6 plane via a topochemical Na deficiency by soft chemical treatment,…

强关联电子 · 物理学 2016-08-31 K. Morimoto , Y. Itoh , K. Yoshimura , M. Kato , K. Hirota

We have investigated the structure and electronic properties of ferrimagnetic double perovskites, A2FeReO6 (A= Ca, Sr, Ba). The A=Ba phase is cubic (Fm3m) and metallic, while the A=Ca phase is monoclinic (P21/n) and nonmetallic. 57Fe…

We synthesized single crystals for Mn2-xZnxSb and studied their magnetic and electronic transport properties. This material system displays rich magnetic phase tunable with temperature and Zn composition. In addition, two groups of distinct…

Double perovskites provide a unique opportunity to induce and control multiferroic behaviors in oxide systems. The appealing possibility to design materials with a strong coupling between the magnetization and the polarization fields may be…

材料科学 · 物理学 2009-04-06 M. P. Singh , K. D. Truong , P. Fournier , P. Rauwel , E. Rauwel , L. P. Carignan , D. Menard

We report on the structural, magnetic, and electronic properties of two new double-perovskites synthesized under high pressure; Pb2CaOsO6 and Pb2ZnOsO6. Upon cooling below 80 K, Pb2CaOsO6 simultaneously undergoes a metal--insulator…

The hope that copper doped lead apatite Pb$_9$Cu(PO$_4$)$_6$O is a room-temperature superconductor has largely been dashed by global research efforts. Nevertheless, according to the current state of knowledge, the material has interesting…

强关联电子 · 物理学 2023-08-29 Makoto Shimizu , Junya Otsuki , Harald O. Jeschke

We present elastic and quasielastic neutron scattering measurements characterizing peculiar short-range charge-orbital and spin order in the layered perovskite material La1.5Sr0.5CoO4. We find that below Tc~750 K holes introduced by Sr…

强关联电子 · 物理学 2009-10-31 I. A. Zaliznyak , J. P. Hill , J. M. Tranquada , R. Erwin , Y. Moritomo

Spin and orbital magnetic moments of Re in AA'FeReO6 double perovskites (A,A' = Ba, Sr, Ca) have been directly probed employing XMCD spectroscopy at the Re L2,3-edges. A considerable orbital magnetic moment is observed in all the studied…

We have studied the atomic ordering of B-site transition metals and magnetic properties in the pulsed-laser deposited films of La2CrFeO6 (LCFO) and La2VMnO6 (LVMO), whose bulk materials are known to be single perovskites with random…

We performed susceptibility, magnetization, specific heat, and single crystal neutron diffraction measurements on single crystalline BaMn$_2$Si$_2$O$_7$. Based on the results, we revisited its spin structure with a more accurate solution…

强关联电子 · 物理学 2019-07-31 G. H. Wang , C. Y. Xu , H. B. Cao , T. Hong , Q. Huang , Q. Y. Ren , J. Q. Xu , H. D. Zhou , W. D. Luo , D. Qian , J. Ma

B-site ordered A$_2$B'B''O$_6$ double perovskites have a variety of applications as magnetic materials. Here we show that diamagnetic $d^{10}$ and $d^0$ B'' cations have a significant effect on the magnetic interactions in these materials.…