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It has been shown that the crystal-field interactions can produce a non- magnetic singlet ground state for the highly-correlated d6 system situated in the quasi-octahedral crystal field (CEF) surrounding provided the spin-orbit interactions…

强关联电子 · 物理学 2009-10-31 R. J. Radwanski , Z. Ropka

Exchange bias properties are observed in a double perovskite compound, Sr2LuRuO6. The observed exchange bias properties have been analyzed on the basis of some of the available theoretical models. Detailed magnetization measurements show…

强关联电子 · 物理学 2010-09-17 Ravi. P. Singh , C. V. Tomy

Single-phase polycrystalline La2MnVO6 samples were synthesized by arc melting and characterized by X-ray diffraction, magnetization and resistivity measurements. We find that the compound has cubic (space group), partly ordered double…

材料科学 · 物理学 2009-11-07 J. Androulakis , N. Katsarakis , J. Giapintzakis

Double perovskite-based magnets wherein frustration and competition between emergent degrees of freedom are at play can lead to novel electronic and magnetic phenomena. Herein, we report the electronic structure and magnetic properties of…

Hole induced changes in the antiferromagnetic structure of a lightly Ca doped Gd:Y_{1-x}Ca_xBa_2Cu_3O_6 copper oxide single crystal with x~0.008 is investigated by Gd3+ electron spin resonance. Holes do not localize to Ca2+ ions above 2.5 K…

超导电性 · 物理学 2007-05-23 Andras Janossy , Titusz Feher , Andreas Erb

In the present investigation, some novel magnetic behaviors exhibited by double perovskite (DP) Eu2CoMnO6(ECMO) has been reported. XRD analysis of ECMO showed that it has a monoclinic crystal structure (space group P 21/n). A second-order…

材料科学 · 物理学 2019-09-30 Mohd Alam , Arkadeb Pal , Khyati Anand , Prajyoti Singh , Sandip Chatterjee

We present a comprehensive study on the magnetic structure, dynamics, and phase evolution in the single-phase double perovskite $La_2CoMnO_6$. The mixed valence state due to oxygen deficiency is verified by X-ray photoelectron spectroscopy,…

Magnetic refrigeration at room-temperature is a technology that could potentially be more environmentally-friendly, efficient and affordable than traditional refrigeration. The search for suitable materials for magnetocaloric refrigeration…

强关联电子 · 物理学 2019-03-13 C. Gauvin-Ndiaye , A. -M. S. Tremblay , R. Nourafkan

The exchange bias (EB) phenomenon has been found in Nd2/3Ca1/3MnO3 perovskite. The phenomenon manifests itself as a negative horizontal shift of magnetization hysteresis loops. The EB phenomenon is evident of an interface exchange coupling…

材料科学 · 物理学 2015-06-17 Elena Fertman , Sergiy Dolya , Vladimir Desnenko , Marcela Kajnakova , Alexander Feher

Hybrid transition metal oxides continue to attract attention due to their multiple degrees of freedom ($e.g.$, lattice, charge, spin, and orbital) and versatile properties. Here we investigate the magnetic and electronic properties of the…

强关联电子 · 物理学 2022-05-17 Ke Yang , Wenjing Xu , Di Lu , Yuxuan Zhou , Lu Liu , Yaozhenghang Ma , Guangyu Wang , Hua Wu

We report two solid solutions based on magnetic ion doping of the double perovskite oxide Sr2GaSbO6: Sr2Ga1-xCrxSbO6 (0.1 < x < 0.4) and Sr2Ga1-xFexSbO6 (0.1 < x < 0.4). All compositions crystallize in the same space group (I4/m) as their…

材料科学 · 物理学 2023-01-24 Lun Jin , Danrui Ni , Xin Gui , Daniel B. Straus , Qiang Zhang , Robert J. Cava

Despite the great technological and scientific importance, a well-controlled coupled behavior in magnetoelectric multiferroic materials at room temperature remains challenging. We demonstrate that the self-ordered A2BBO6 (e.g., A = La, B =…

材料科学 · 物理学 2015-05-14 M. P. Singh , K. D. Truong , S. Jandl , P. Fournier

We report the effect of La-substitution on the magnetic and magnetotransport properties of Brownmillerite-like bilayered compounds Ca2.5-xLaxSr0.5GaMn2O8 (x = 0, 0.05, 0.075, and 0.1) by using dc-magnetization, resistivity and…

材料科学 · 物理学 2010-03-16 A. K. Bera , S. M. Yusuf

We investigated the rare-earth transition metal oxide series, Ln2CuTiO6 (Ln=Y, Dy, Ho, Er and Yb), crystallizing in the hexagonal structure with non-centrosymmetric P63cm space group for possible occurrences of multiferroic properties. Our…

The magnetic ground state in the double perovskite system Sr2-xCaxCoOsO6 changes from an antiferromagnet (x = 0), to a spin glass (x = 1), to a ferrimagnet (x = 2) as the Ca content increases. This crossover is driven by chemical pressure…

We investigate the structural, magnetic and spin-state transitions, and magnetocaloric properties of Sr$_{2-x}$La$_x$CoNbO$_6$ ($x=$ 0--1) double perovskites. The structural transition from tetragonal to monoclinic phase at $x$ $\geqslant$…

材料科学 · 物理学 2020-04-21 Ajay Kumar , R. S. Dhaka

Effect of Co, Ru and Cu substitution at B and B' sites on the magnetic and transport properties of LaSrCoRuO$_6$ have been investigated. All the doped compositions crystallize in the monoclinic structure in the space group $P2_1/n$…

强关联电子 · 物理学 2010-11-12 P. S. Ramu Murthy , K. R. Priolkar , P. A. Bhobe , A. Das , P. R. Sarode , A. K. Nigam

We report the detailed analysis of specific heat [C$_{\rm P}$(T)] and ac-susceptibility for magnetically frustrated Sr$_{2-x}$La$_x$CoNbO$_6$ ($x=$ 0--1) double perovskites to understand low temperature complex magnetic interactions and…

强关联电子 · 物理学 2020-11-30 Ajay Kumar , B. Schwarz , H. Ehrenberg , R. S. Dhaka

Zero field cooled spontaneous exchange bias (SEB) is observed in epitaxial La0.7Sr0.3MnO3 (LSMO):NiO self-assembled nanocomposite thin films grown on (001) SrTiO3 single crystal substrate by pulsed laser deposition. SEB is displayed by the…

材料科学 · 物理学 2018-11-29 Gyanendra Panchal , R. J. Choudhary , Manish Kumar , D. M. Phase

Recently, the iridate double perovskite Sr$_2$YIrO$_6$ has attracted considerable attention due to the report of unexpected magnetism in this Ir$^{5+}$ (5d$^4$) material, in which according to the J$_{eff}$ model, a non-magnetic ground…