相关论文: Ultrafast Fluorescence Depolarization in Conjugate…
The theoretical description and the properties of Frenkel excitons in non-covalently bonded molecular aggregates are reviewed from a multi-exciton perspective of dissipative quantum dynamics. First, the photophysical and quantum chemical…
Based on the Frenkel-charge transfer (CT) mixing model of singlet fission (SF), we incorporate both the local and nonlocal phonon baths in the Hamiltonian and adopt the algorithm of time-dependent density matrix renormalization group to…
Phonon interactions in solid-state photonics systems cause intrinsic quantum decoherence and often present the limiting factor in emerging quantum technology. Due to recent developments in nanophotonics, exciton-cavity structures with very…
Understanding the ultrafast coupling and relaxation mechanisms between valleys in transition metal dichalcogenide semiconductors is of crucial interest for future valleytronic devices. Recent ultrafast pump-probe experiments showed an…
In the primary step of light-harvesting, the energy of a photon is captured in antenna chlorophyll as an exciton. Its efficient conversion to stored chemical potential occurs in the special pair reaction center, which has to be reached by…
Photoionization using attosecond pulses can lead to the formation of coherent superpositions of the electronic states of the parent ion. However, ultrafast electron ejection triggers not only electronic but also nuclear dynamics---leading…
Equations of motion for weakly coupled excitonic complexes are derived. The description allows to treat the system in the basis of electronic states localized on individual chromophores, while at the same time accounting for experimentally…
Excitons in the weakly interacting regime can be well-described by many-body perturbation theories such as the Bethe-Salpeter equation formalism. However, for materials such as transition metal dichalcogenides moir\'e heterostructures under…
Recently, systems with strong coupling between electronic and vibrational degrees of freedom attract a great attention. In this work, we consider the transient dynamics of the system consisting of strongly coupled vibron and exciton driven…
The effect of a number of mechanisms designed to suppress decoherence in open quantum systems are studied with respect to their effectiveness at slowing down the loss of entanglement. The effect of photonic band-gap materials and frequency…
We explore non-analytic quantum phase dynamics of dipolar exciton condensates formed in a system of 1D quantum layers subjected to voltage quenches. We map the exciton condensate physics on to the pseudospin ferromagnet model showing an…
In the context of Frenkel exciton dynamics in aggregated molecules the polaron transformation technique facilitates a treatment where diagonal elements attributed to electronic excited-state populations are decoupled from fluctuations…
Within quantum information frameworks, managing decoherence stands as a pivotal task. The present work delves into decoherence dynamics of a dressed qubit, represented by a spinless fermion hopping between two lattice sites that are…
We quantify the excitonic coupling in the homodimer of dimeric Venus fluorescent protein using a quantum-classical hybrid workflow. Employing a transition-density coupling formalism, we calculate $J = 74.38~\mathrm{cm^{-1}}$, which is 5.6…
Coupling between exciton states across the Brillouin zone in monolayer transition metal dichalcogenides can lead to ultrafast valley depolarization. Using time- and angle-resolved photoemission, we present momentum- and energy-resolved…
The Frenkel exciton Hamiltonian is at the heart of many simulations of excitation energy transfer in molecular aggregates. It separates the aggregate into Coulomb-coupled monomers. Here it is shown that the respective parameters, i.e.…
Simulating the irreversible quantum dynamics of exciton and electron transfer problems poses a nontrivial challenge. Because the irreversibility of the system dynamics is a result of quantum thermal activation and dissipation caused by the…
Excitons are key quasiparticles determining the optical properties of solids. As such, they can be utilized to coherently control the electronic structure of materials using optical femtosecond pulses. Identifying the decoherence mechanism…
Coupled many-body quantum systems give rise to rich emergent physics and abundance of both stationary and dynamical behaviours. Designing platforms with tunable and distinct forms of coupling gives new insight into the collective behaviour…
We study the collective interaction of excitons in closely spaced artificial molecules and arrays of nearly identical quantum dots with the electromagnetic modes. We discuss how collective fluorescence builds up in the presence of a small…