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We address one of the main challenges to TiO2-photocatalysis, namely band gap narrowing, by combining nanostructural changes with doping. With this aim we compare TiO2's electronic properties for small 0D clusters, 1D nanorods and…

材料科学 · 物理学 2010-01-18 D. J. Mowbray , J. I. Martinez , J. M. García-Lastra , K. S. Thygesen , K. W. Jacobsen

We use first-principles calculations to investigate the adsorption and incorporation of non-metal impurities (N, C) at the anatase TiO$_2$(001)-(1$\times$4) reconstructed surface. We analyze in detail the influence of the surface structure…

材料科学 · 物理学 2015-06-11 Jun Hee Lee , Daniel Fernandez Hevia , Annabella Selloni

We show that the optical and electronic properties of nanocrystalline silicon can be efficiently tuned using impurity doping. In particular, we give evidence, by means of ab-initio calculations, that by properly controlling the doping with…

其他凝聚态物理 · 物理学 2009-11-13 Federico Iori , Elena Degoli , Rita Magri , Ivan Marri , G. Cantele , D. Ninno , F. Trani , O. Pulci , Stefano Ossicini

Black TiO2 nanoparticles with a crystalline-core and amorphous-shell structure exhibit superior optoelectronic properties in comparison with pristine TiO2. The fundamental mechanisms underlying these enhancements, however, remain unclear,…

Nanoporous structures play a promising role in the development of nanomechanical, nanoelectrical and biosensing devices. In addition, nanopores can be utilized as chemical and gas sensors. TiO2 is a semiconductor material, which can have a…

材料科学 · 物理学 2012-07-30 Subhasish Chatterjee , Miriam Ginzberg , Bonnie Gersten

2D materials hold transformative promise for next-generation nanoelectronics. However, successfully integrating these materials from laboratory-scale discoveries into real-world devices depends on precisely controlling their properties,…

The efforts in the optimization of the physical and chemical properties related to the photocatalytic efficiency of TiO2 nanoparticles relies mainly on defect engineering strategies, been the structural and the doping the most common ones.…

材料科学 · 物理学 2022-03-07 M. P. Ferreira , H. B. de Carvalho

Ion implantation is an interesting method to dope semiconducting materials such as zinc oxide provided that the implantation-induced defects can be subsequently removed. Nitrogen implantation followed by anneals under O2 were carried out on…

The doping of wide gap semiconductors is an interesting problem both from the scientific and technological point of view. A well known example of this problem is the doping of Cu$_2$O. The only element which has produced an order of…

材料科学 · 物理学 2013-10-22 F. Biccari , C. Malerba , A. Mittiga

This review work focuses on the milling process of titania (TiO2) nanopowder. TiO2 is a naturally available material. It is an inorganic semi-conducting oxide of titanium metal. Titanium oxide, titanium dioxide, and titanium (IV) oxide are…

材料科学 · 物理学 2017-04-05 T. Theivasanthi

The use of electrophoretic forces to tune friction at material-nanoparticle-liquid interfaces with static or low frequency (0.6-50 mHz) electric fields is reported for the first time. External electric fields were employed to reposition…

软凝聚态物质 · 物理学 2019-01-31 Biplav Acharya , Caitlin M. Seed , Donald W. Brenner , Alex I. Smirnov , Jacqueline Krim

Metal nano-aerogels combine a large surface area, a high structural stability, and a high catalytic activity towards a variety of chemical reactions. The performance of such nanostructures is underpinned by the atomic-level distribution of…

Titanium-based oxides are abundant, chemically stable, non-toxic, and highly versatile materials, with applications ranging from photovoltaics to catalysis. For rutile and anatase phases of Titanium dioxide (TiO2), the bandgap ranges from…

材料科学 · 物理学 2022-01-04 Lynet Allan , George O Amolo , Julius Mwabora , Silas Mureramanzi

The synthesis of materials with well-controlled composition and structure improves our understanding of their intrinsic electrical transport properties. Recent developments in atomically controlled growth have been shown to be crucial in…

Charge transfer between metal nanoparticles and the supported TiO2 surface is primarily important for catalytic applications as it greatly affects the catalytic activity and the thermal stability of the deposited nanoparticles on the…

材料科学 · 物理学 2013-12-24 Cai Yongqing , Bai Zhaoqiang , Chintalapati Sandhya , Zeng Qingfeng , Feng Yuan Ping

The superconducting radio-frequency (SRF) community has shown that introducing certain impurities into high-purity niobium can improve quality factors and accelerating gradients. We question why some impurities improve RF performance while…

加速器物理 · 物理学 2023-07-13 K. Howard , Y. -K. Kim , D. Bafia , A. Grassellino

Ti-O nanoparticles have been synthesized via hollow cathode sputtering in an Ar-O2 atmosphere using high power pulsing. It is shown that the stoichiometry and the size of the nanoparticles can be varied independently, the former through…

介观与纳米尺度物理 · 物理学 2018-10-09 Rickard Gunnarsson , Ulf Helmersson , Iris Pilch

Contaminations in the formation of two-dimensional heterostructures can hinder or generate desired properties. Recent advancements have highlighted the potential of tip-enhanced Raman spectroscopy (TERS) for studying materials in the 2D…

Nanostructures of Titanium oxide (TiO2) are being studied for many promising applications, e.g., solar photovoltaics, solar water splitting for H2 fuel generation etc., due to their excellent photo-catalytic properties. We have synthesized…

材料科学 · 物理学 2016-09-30 Gangadhar Das , Manoj Kumar , A. K. Biswas , Ajay Khooha , Puspen Mondal , M. K. Tiwari

Low-dose nitrogen implantation induces in TiO2 nanotubes a co-catalytic activity for photocatalytic H2-evolution. The use of an ion implantation process leads to a N-implanted zone only at the top part of the tubes. The coupling of this top…

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