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Fundamental electronic processes such as charge-carrier transport and recombination play a critical role in determining the efficiency of hybrid perovskite solar cells. The presence of mobile ions complicates the development of a clear…

材料科学 · 物理学 2020-12-17 Sebastian Reichert , Katelyn Goetz , Christopher Wöpke , Yana Vaynzof , Carsten Deibel

Using density functional theory (DFT)-based calculations, we propose a family of metastable, as-yet unmade V5+ and Cr6+ double perovskite compounds with low band gaps spanning much of the visible region of the solar spectrum. Through…

材料科学 · 物理学 2012-11-07 Robert F. Berger , Jeffrey B. Neaton

The organic-inorganic hybrid lead trihalide perovskites have been emerging as the most attractive photovoltaic material. As regulated by Shockley-Queisser theory, a formidable materials science challenge for the next level improvement…

Most traditional semiconductor materials are based on the control of doping densities to create junctions and thereby functional and efficient electronic and optoelectronic devices. The technology development for halide perovskites had…

材料科学 · 物理学 2021-12-08 Basita Das , Irene Aguilera , Uwe Rau , Thomas Kirchartz

The unique aspect of the hybrid perovskites is their tunability, allowing to engineer the bandgap via substitution. From application viewpoint, this allows creation of the tandem cells between perovskites and silicon, or two or more…

We report a proof-of-concept two-terminal perovskite/Cu(In, Ga)Se2 (CIGS) monolithic thin-film tandem solar cell grown on ultra-thin (30-microns thick), light-weight, and flexible polyimide foil with a steady-state power conversion…

Owing to their high energy-conversion efficiency and inexpensive fabrication routes, solar cells based on metal-organic halide perovskites have rapidly gained prominence as a disruptive technology. An attractive feature of perovskite…

材料科学 · 物理学 2015-02-17 Marina R. Filip , Giles E. Eperon , Henry J. Snaith , Feliciano Giustino

Halide double perovskites have gained significant attention, owing to their composition of low-toxicity elements, stability in air and long charge-carrier lifetimes. However, most double perovskites, including Cs2AgBiBr6, have wide…

Interpreting the impedance response of perovskite solar cells (PSC) is significantly more challenging than for most other photovoltaics. This is for a variety of reasons, of which the most significant are the mixed ionic-electronic…

Understanding and quantifying the main loss factors affecting the power conversion efficiency of perovskite solar cells are urgently needed. In this work, based on semiconductor physics, the expressions of bulk and surface recombination…

介观与纳米尺度物理 · 物理学 2021-03-23 Ting Xu , Zi-Shuai Wang , Xuan-Hua Li , Wei E. I. Sha

Photovoltaics (PV) is the most important energy conversion technology for cost-efficient climate change mitigation. To reach the international climate goals, the annual PV module production capacity must be expanded to multi-terawatt scale.…

Tandem solar cells can better harness the energy of the solar spectrum. Chalcopyrite solar cells have drawn attention, being the only highly efficient devices with bandgap around 1.0 eV, suitable for bottom cells. In the quest for better…

Halide perovskites excel in the pursuit of highly efficient thin film photovoltaics, with power conversion efficiencies reaching 25.5% in single junction and 29.5% in tandem halide perovskite/silicon solar cell configurations. Operational…

Despite the exciting recent research on perovskite based solar cells, the design space for further optimization and the practical limits of efficiency are not well known in the community. In this manuscript, we address these aspects through…

介观与纳米尺度物理 · 物理学 2015-09-29 Sumanshu Agarwal , Pradeep R. Nair

One of the most significant features of lead-halide perovskites are their ability to have comparably slow recombination despite the fact that these materials are mostly processed from solution at room temperature. The slow recombination…

应用物理 · 物理学 2019-07-26 Thomas Kirchartz

Nearly perfect photon recycling helped GaAs cells achieve the highest efficiency ever reported for a solar cell. Recent reports of photon recycling in perovskite solar cells suggest that, once optimized, it may as well achieve GaAs-like…

介观与纳米尺度物理 · 物理学 2016-12-21 Mohammad Ryyan Khan , Xufeng Wang , Reza Asadpour , Mark Lundstrom , Muhammad A. Alam

Hybrid organic-inorganic halide perovskites have emerged as a disruptive new class of materials, exhibiting optimum properties for a broad range of optoelectronic applications, most notably for photovoltaics. The first report of highly…

材料科学 · 物理学 2018-08-21 Marina R. Filip , George Volonakis , Feliciano Giustino

The development of scalable 1.25 eV mixed Pb-Sn perovskite solar modules by blade coating lags behind Pb-based perovskites due to limited understanding of solution-substrate interaction of the perovskite ink on PEDOT:PSS and subsequent gas…

Metal halide perovskites are of great interest for application in semitransparent solar cells due to their tunable bandgap and high performance. However, fabricating high-efficiency perovskite semitransparent devices with high average…

Single junction Si solar cells dominate photovoltaics but are close to their efficiency limits. This paper presents ideal limiting efficiencies for tandem and triple junction multijunction solar cells subject only to the constraint of the…

材料科学 · 物理学 2013-12-11 J. P. Connolly , D. Mencaraglia , C. Renard , D. Bouchier