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One effective way to prevent toxicity and improve the stability of materials for photovoltaic applications is to exclude lead and organic molecules from perovskite materials. Specifically, the CsSn1-xGexI3 appears to be a promising…

The extraction of photogenerated charge carriers and the generation of a photovoltage belong to the fundamental functionalities of any solar cell. These processes happen not instantaneously but rather come with finite time constants, e.g.,…

材料科学 · 物理学 2023-02-08 Lisa Krückemeier , Zhifa Liu , Thomas Kirchartz , Uwe Rau

BaZrS3, a prototypical chalcogenide perovskite, has been shown to possess a direct band gap, an exceptionally strong near band edge light absorption, and good carrier transport. Coupled with its great stability, non-toxicity with earth…

One of the critical challenges in enhancing the performance of perovskite solar cells is reducing the density of trap states in the light-absorbing perovskite layer. These trap states lead to increased charge carrier recombination, thus…

介观与纳米尺度物理 · 物理学 2025-12-23 Atena mohamadnezhad , Alireza Fathi-Beiraghvandi , Mahmoud Samadpour

Perovskite solar cells employing self assembled monolayers such as Me-4PACz as hole transport layer has been reported to demonstrate high device efficiency. However, the poor perovskite wetting on the Me-4PACz caused by poor perovskite ink…

We simulated photovoltaic characteristics of single heterojunction solar cell with Cu2ZnSnS4 and Cu2ZnSnSe4 absorber layer numerically using one dimensional solar cell capacitance simulator (SCAPS-1D). n-CdS/ZnO double buffer layer is used…

应用物理 · 物理学 2018-01-26 Goutam K Gupta , Ambesh Dixit

In this article, we demonstrate CdSe-CuSbSe2-based double junction two-terminal tandem solar cells simulated with SCAPS-1D. The highest performance of the tandem cell has been confirmed by optimizing the electrical and optical properties of…

The enhancement of the fill factor in the current generation of perovskite solar cells is the key for further efficiency improvement. Thus, methods to quantify the fill factor losses are urgently needed. A classical method to quantify Ohmic…

应用物理 · 物理学 2022-07-07 David Grabowski , Zhifa Liu , Gunnar Schöpe , Uwe Rau , Thomas Kirchartz

Perovksite semiconductors have shown promise for low-cost solar cells, lasers and photodetectors, yet their fundamental photophysical properties are not well understood. Recent observations of a low ($\sim$few meV) exciton binding energy…

We demonstrate the critical role of surface recombination in mixed-cation, mixed-halide perovskite, FA0.83Cs0.17Pb(I0.85Br0.15)3. By passivating non-radiative defects with the polymerizable Lewis base (3-aminopropyl)trimethoxysilane (APTMS)…

Mixing iodide and bromide in halide perovskite semiconductors is an effective strategy to tune their bandgap, therefore mixed-halide perovskites hold great promise for color-tunable LEDs and tandem solar cells. However, the bandgap of…

The thermodynamic limit of photovoltaic efficiency for a single-junction solar cell can be readily predicted using the bandgap of the active light absorbing material. Such an approach overlooks the energy loss due to non-radiative…

应用物理 · 物理学 2021-06-21 Sunghyun Kim , Aron Walsh

Halide double perovskites have recently been proposed as potential environmentally friendly alternatives to organic group and lead based hybrid halide perovskites. In particular, Cs2BiAgX6 have been synthesized and found to exhibit tunable…

应用物理 · 物理学 2019-05-03 Yunting Liang

Organic-inorganic hybrid perovskite solar cells (PSC) have demonstrated impressive performance improvement. Among the various characteristics, the time-dependent current-voltage (J-V) hysteresis allows a direct exploration of various…

材料科学 · 物理学 2024-12-23 Abhimanyu Singareddy , Pradeep R. Nair

In single-junction photovoltaic (PV) devices, the maximum achievable power conversion efficiency (PCE) is mainly limited by thermalization and transmission losses, because polychromatic solar irradiation cannot be matched to a single…

The establishment of a rigorous theory on thermodynamics of light management in photovoltaics that accommodates various loss mechanisms as well as wave-optical effects in the absorption and reemission of light is at stake in this…

In perovskite solar cells, photovoltaic action is created by charge transport layers (CTLs) either side of the light-absorbing metal halide perovskite semiconductor. Hence, the rates for desirable charge extraction and unwanted interfacial…

The transition to sustainable energy has accelerated research into perovskite solar cells (PSCs) as promising candidates for next-generation photovoltaics. Despite their remarkable efficiencies, the commercialization of PSCs is hindered by…

材料科学 · 物理学 2025-08-07 Nassim Mahammedi

In the previous decade, there has been a significant advancement in the performance of perovskite solar cells (PSCs), characterized by a notable increase in efficiency from 3.8% to 25%. Nonetheless, PSCs face many problems when we…