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Photoelectron circular dichroism (PECD) is a method whereby randomly oriented chiral molecules are irradiated by circularly-polarized light, photoionizing electrons, which are measured in a momentum-resolved manner. This scheme permits…

化学物理 · 物理学 2025-05-23 Ofer Neufeld

Chiral metal halide perovskites have emerged as promising optoelectronic materials for emission and detection of circular polarized visible light. Despite chirality being realized by adding chiral organic cations or ligands, the chiroptical…

材料科学 · 物理学 2023-09-26 Sofia Apergi , Geert Brocks , Shuxia Tao

The helical distribution of the electronic density in chiral molecules, such as DNA and bacteriorhodopsin, has been suggested to induce a spin-orbit coupling interaction that may lead to the so-called chirality-induced spin selectivity…

介观与纳米尺度物理 · 物理学 2020-01-01 Miguel A. Sierra , David Sanchez , Rafael Gutierrez , Gianaurelio Cuniberti , Francisco Dominguez-Adame , Elena Diaz

The chiral-induced spin selectivity (CISS) effect, whereby chiral molecules preferentially transmit electrons of one spin orientation, remains one of the most intriguing and debated phenomena at the interface of spintronics, molecular…

介观与纳米尺度物理 · 物理学 2025-10-27 Subhajit Sarkar , Amos Sharoni , Oliver L. A. Monti , Yonatan Dubi

The photoionization of chiral molecules prepared in a coherent superposition of excited states can give access to the underlying chiral coherent dynamics in a procedure known as photoexcitation induced photoelectron circular dichroism…

原子与分子团簇 · 物理学 2018-08-29 Alex G Harvey , Zdeněk Mašín , Olga Smirnova

The observation of spin-dependent transmission of electrons through chiral molecules has led to the discovery of chiral-induced spin selectivity (CISS). The remarkably high efficiency of the spin polarizing effect has recently gained…

We present a unified description of several methods of chiral discrimination based exclusively on electric-dipole interactions. It includes photoelectron circular dichroism (PECD), enantio-sensitive microwave spectroscopy (EMWS),…

原子物理 · 物理学 2019-01-02 Andres F. Ordonez , Olga Smirnova

The Chirality-Induced Spin Selectivity (CISS) effect describes the ability of chiral molecules and crystals to transmit spin-polarized currents, a phenomenon first identified in 1999. Although this effect holds great promise for a broad…

介观与纳米尺度物理 · 物理学 2025-01-08 Sushant Kumar Behera , Ruggero Sala , Abhirup Roy Karmakar , Matteo Moioli , Rocco Martinazzo , Matteo Cococcioni

Chirality-induced spin selectivity (CISS) has been extensively studied over the past two decades. While current-induced spin polarization in chiral molecules is widely recognized as the fundamental principle of the CISS, only a few studies…

材料科学 · 物理学 2023-08-25 Kouta Kondou , Shinji Miwa , Daigo Miyajima

Chiral materials display a property called optical activity, which is the capability to interact differentially with left and right circularly polarised light. This leads to the ability to manipulate the polarisation state of light, which…

Molecular chirality detection and enantiomer discrimination are very important issues for many areas of science and technology, prompting intensive investigations via optical methods. However, these methods are hindered by the intrinsically…

Chiral light-matter interactions have traditionally been understood in terms of electric-magnetic dipolar interference driven by light with spin angular momentum. Here, we show that optical chirality can also originate from the orbital…

光学 · 物理学 2025-08-13 Shun Hashiyada , An'an Wu , Yoshito Y. Tanaka

We study the generic interaction of a monochromatic electromagnetic field with bi-isotropic nanoparticles. Such an interaction is described by dipole-coupling terms associated with the breaking of dual, P- and T-symmetries, including the…

光学 · 物理学 2014-07-23 Konstantin Y. Bliokh , Yuri S. Kivshar , Franco Nori

Chirality is a fundamental property of great importance in physics, chemistry, and biology, and has recently been found to generate unexpected spin polarization for electrons passing through organic molecules, known as chirality-induced…

介观与纳米尺度物理 · 物理学 2024-01-25 Qun Yang , Yongkang Li , Claudia Felser , Binghai Yan

Spin-orbit coupling gives rise to a range of spin-charge interconversion phenomena in non-magnetic systems where certain spatial symmetries are reduced or absent. Chirality-induced spin selectivity (CISS), a term that generically refers to…

介观与纳米尺度物理 · 物理学 2023-04-25 W. Dednam , M. A. García-Blázquez , Linda A. Zotti , E. B. Lombardi , C. Sabater , S. Pakdel , J. J. Palacios

Identifying the handedness of chiral molecules is of fundamental importance in chemistry, biology, pharmacy, and medicine. Nanophotonic structures allow us to control light at the nanoscale and offer powerful tools for chiral sensing,…

Chiral spin textures at the interface between ferromagnetic and heavy nonmagnetic metals, such as Neel-type domain walls and skyrmions, have been studied intensively because of their great potential for future nanomagnetic devices. The…

The interaction between circularly polarized (CP) light and matter is governed by two fundamental quantities: spin angular momentum (SAM) and optical chirality (OC). While these quantities are inseparable in free space, they can be…

Chiral molecules have attracted significant multidisciplinary interest and extensive research owing to their remarkable ability to achieve charge-to-spin conversion, known as the chiral-induced spin selectivity (CISS). A recent experiment…

化学物理 · 物理学 2025-09-05 Tian-Yi Zhang , Peng-Yi Liu , Ai-Min Guo , Qing-Feng Sun

Electronic circular dichroism (ECD) is a powerful spectroscopical method for investigating chiral properties at the molecular level. ECD calculations with the commonly used linear-response time-dependent density functional theory (LR-TDDFT)…