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Oil has become a prevalent global pollutant, stimulating the research to improve the techniques to separate oil from water. Materials with special wetting properties - primarily those that repel water while attracting oil - have been…

We calculate the ion distributions around an interface in fluid mixtures of highly polar and less polar fluids (water and oil) for two and three ion species. We take into account the solvation and image interactions between ions and…

软凝聚态物质 · 物理学 2009-11-13 Akira Onuki

We study the role of surface topology, surface chemistry, and wall superheat temperature on the onset of boiling, bubble nucleation and growth, and the possible formation of an insulating vapour film by means of large-scale MD simulations.…

软凝聚态物质 · 物理学 2020-07-10 Armin Shahmardi , Outi Tammisola , Mauro Chinappi , Luca Brandt

The hydrodynamic slippage at a solid-liquid interface is currently at the center of our understanding of fluid mechanics. For hundreds of years this science has relied upon no-slip boundary conditions at the solid-liquid interface that has…

软凝聚态物质 · 物理学 2015-03-17 Olga I. Vinogradova , Aleksey V. Belyaev

Tree frogs possess soft structured toe pads with channels that help squeeze out fluid from the region between the toe pad and the contacting surfaces. This structure enables them to walk on wet and rough surfaces. We present our preliminary…

软凝聚态物质 · 物理学 2022-04-28 Rohini Gupta , Joelle Frechette

The tendency of amphiphilic molecules to form micelles in aqueous solution is a consequence of the hydrophobic effect. The fundamental difference between micelle assembly and macroscopic phase separation is the stoichiometric constraint…

软凝聚态物质 · 物理学 2007-05-23 Lutz Maibaum , Aaron R. Dinner , David Chandler

The hydrophobic effect (HE) is commonly associated with the demixing of oil and water at ambient conditions and plays the leading role in determining the structure and stability of biomolecular assembly in aqueous solutions. On the…

统计力学 · 物理学 2012-02-07 Aljaz Godec , Franci Merzel

Water near hydrophobic surfaces is like that at a liquid-vapor interface, where fluctuations in water density are substantially enhanced compared to that in bulk water. Here we use molecular simulations with specialized sampling techniques…

Using concepts from perturbation and local molecular field theories of liquids we divide the potential of the SPC/E water model into short and long ranged parts. The short ranged parts define a minimal reference network model that captures…

统计力学 · 物理学 2015-05-28 Richard C. Remsing , Jocelyn M. Rodgers , John D. Weeks

The relation between the contact angle of a liquid drop and the morphological parameters of self-affine solid surfaces have been investigated. We show experimentally that the wetting property of a solid surface crucially depends on the…

材料科学 · 物理学 2009-06-16 S. Sarkar , S. Patra , N. Gayathri , S. Banerjee

The interfacial resistance to evaporation, in particular for the case of water, is a longstanding issue. The previous data on its main characterizing parameter, the accommodation coefficient, manifest a dispersion over three orders of…

Direct Numerical Simulations of two superposed fluids in a channel with a textured surface on the lower wall have been carried out. A parametric study varying the viscosity ratio between the two fluids has been performed to mimic both {\bf…

流体动力学 · 物理学 2019-05-22 I. Arenas , E. Garcia , M. K. Fu , P. Orlandi , M. Hultmark , S. Leonardi

Hydrophobic molecules such as oils and certain drugs can be encapsulated between the two leaflets of an amphiphilic bilayer in both lipid and polymer systems. We investigate the case where the hydrophobic molecules are incompatible with the…

软凝聚态物质 · 物理学 2012-07-02 M. J. Greenall , C. M. Marques

The physics of air-water interfaces plays a central role in modern theories of the hydrophobic effect. Implementing these theories, however, has been hampered by the difficulty of addressing fluctuations in the shape of such soft…

统计力学 · 物理学 2016-05-27 Suriyanarayanan Vaikuntanathan , Phillip L Geissler

We have developed a classical two- and three-body interaction potential to simulate the hydroxylated, natively oxidised Si surface in contact with water solutions, based on the combination and extension of the Stillinger-Weber potential and…

材料科学 · 物理学 2008-07-22 Daniel J. Cole , Mike C. Payne , Gabor Csanyi , S. Mark Spearing , L. Colombi Ciacchi

The mechanism of the collapse of the superhydrophobic state is elucidated for submerged nanoscale textures forming a three-dimensional interconnected vapor domain. This key issue for the design of nanotextures poses significant simulation…

软凝聚态物质 · 物理学 2017-03-31 Matteo Amabili , Alberto Giacomello , Simone Meloni , Carlo Massimo Casciola

The local hydration around tetrameric Hb in its T$_0$ and R$_4$ conformational substates is analyzed based on molecular dynamics simulations. Analysis of the local hydrophobicity (LH) for all residues at the $\alpha_1 \beta_2$ and $\alpha_2…

化学物理 · 物理学 2022-12-09 Seyedeh Maryam Salehi , Marco Pezzella , Adam Willard , Markus Meuwly , Martin Karplus

Under partial wetting conditions, making a substrate uniformly rougher enhances the wetting characteristics of the corresponding smooth substrate {--} hydrophilic systems become even more hydrophilic and hydrophobic systems even more…

软凝聚态物质 · 物理学 2012-01-05 Zhenwei Yao , Mark J. Bowick

To track rapid changes within our water sector, Global Water Models (GWMs) need to realistically represent hydrologic systems' response patterns - such as baseflow fraction - but are hindered by their limited ability to learn from data.…

A millimetre-size superhydrophobic sphere impacting on the free surface of a quiescent bath can be propelled back into the air by capillary effects and dynamic fluid forces, whilst transferring part of its energy to the fluid. We report the…