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Obtaining adiabatic processes that connect equilibrium states in a given time represents a challenge for mesoscopic systems. In this paper, we explicitly show how to build these finite-time adiabatic processes for an overdamped Brownian…

介观与纳米尺度物理 · 物理学 2020-04-01 C. A. Plata , D. Guéry-Odelin , E. Trizac , A. Prados

The past twenty years have seen a resurgence of interest in nonequilibrium thermodynamics, thanks to advances in the theory of stochastic processes and in their thermodynamic interpretation. Fluctuation theorems provide fundamental…

统计力学 · 物理学 2017-11-16 Robert Marsland , Jeremy England

We consider a detailed-balance violating dynamics whose stationary state is a prescribed Boltzmann distribution. Such dynamics have been shown to be faster than any equilibrium counterpart. We quantify the gain in convergence speed for a…

统计力学 · 物理学 2022-05-27 Federico Ghimenti , Frédéric van Wijland

We study diffusion-controlled processes in nonequilibrium steady states, where standard rate theory assumptions break down. Using transition path theory, we generalize the relations between reactive probability fluxes and measures of the…

化学物理 · 物理学 2025-06-02 Seokjin Moon , David T. Limmer

Lack of knowledge about the detailed many-particle motion on the microscopic scale is a key issue in any theoretical description of a macroscopic experiment. For systems at or close to thermal equilibrium, statistical mechanics provides a…

统计力学 · 物理学 2016-03-03 Peter Reimann

The dynamics and structure of nonequilibrium liquids, driven by non-conservative forces which can be either external or internal, generically hold the signature of the net dissipation of energy in the thermostat. Yet, disentangling…

统计力学 · 物理学 2019-11-06 Laura Tociu , Étienne Fodor , Takahiro Nemoto , Suriyanarayanan Vaikuntanathan

We consider an isolated point defect embedded in a homogeneous crystalline solid. We show that, in the harmonic approximation, a periodic supercell approximation of the formation free energy as well as of the transition rate between two…

概率论 · 数学 2018-12-11 Julian Braun , Manh Hong Duong , Christoph Ortner

Sampling the Boltzmann distribution using forces that violate detailed balance can be faster than with the equilibrium evolution, but the acceleration depends on the nature of the nonequilibrium drive and the physical situation. Here, we…

软凝聚态物质 · 物理学 2023-12-20 Federico Ghimenti , Ludovic Berthier , Grzegorz Szamel , Frédéric van Wijland

The temperature in the transient climate response is lower than the equilibrium temperature for the same amount of forcing. The degree of disequilibrium is not constant in time and depends on various climate parameters. We derive intuition…

大气与海洋物理 · 物理学 2026-03-03 Boriana Chtirkova

The dynamics near the top of a potential barrier is studied in the temperature region where quantum effects become important. The time evolution of the density matrix of a system that deviates initially from equilibrium in the vicinity of…

chem-ph · 物理学 2009-10-28 Joachim Ankerhold , Hermann Grabert

In the context of driven diffusive systems, for thermodynamic transformations over a large but finite time window, we derive an expansion of the energy balance. In particular, we characterize the transformations which minimize the energy…

统计力学 · 物理学 2018-06-11 L. Bertini , A. De Sole , D. Gabrielli , G. Jona-Lasinio , C. Landim

Biomolecular machines transduce between different forms of energy. These machines make directed progress and increase their speed by consuming free energy, typically in the form of nonequilibrium chemical concentrations. Machine dynamics…

统计力学 · 物理学 2018-10-05 Aidan I Brown , David A Sivak

Based on a variational expression for the steady-state entropy production rate in overdamped Langevin dynamics, we derive concrete upper bounds on the entropy production rate in various physical settings. For particles in a thermal…

统计力学 · 物理学 2023-10-30 Andreas Dechant

A sweep through a quantum phase transition by means of a time-dependent external parameter (e.g., pressure) entails non-equilibrium phenomena associated with a break-down of adiabaticity: At the critical point, the energy gap vanishes and…

量子物理 · 物理学 2015-05-18 Ralf Schützhold

Research in quantum information science aims to surpass the scaling limitations of classical information processing. From a physicist's perspective, performance improvement involves a physical speedup in the quantum domain, achieved by…

量子物理 · 物理学 2024-07-10 Farha Yasmin , Jan Sperling

Diverse physical systems are characterized by their response to small perturbations. Near thermodynamic equilibrium, the fluctuation-dissipation theorem provides a powerful theoretical and experimental tool to determine the nature of…

统计力学 · 物理学 2020-03-25 Jeremy A. Owen , Todd R. Gingrich , Jordan M. Horowitz

Just as transition rates in a canonical ensemble must respect the principle of detailed balance, constraints exist on transition rates in driven steady states. I derive those constraints, by maximum information-entropy inference, and apply…

统计力学 · 物理学 2009-11-10 R. M. L. Evans

Any physical system evolves at a finite speed that is constrained not only by the energetic cost but also by the topological structure of the underlying dynamics. In this Letter, by considering such structural information, we derive a…

量子物理 · 物理学 2023-01-06 Tan Van Vu , Keiji Saito

This work inspects the thermally activated transfer of solute particles across the interface between two interstitial solid solution phases that equilibrate internally by fast diffusion on conserved arrays of sites. When each phase is…

材料科学 · 物理学 2026-01-30 Jörg Weissmüller

Reducing work fluctuation and dissipation in heat engines or, more generally, information heat engines that perform feedback control is vital to maximize their efficiency. The same problem arises when we attempt to maximize the efficiency…

统计力学 · 物理学 2016-01-06 Ken Funo , Masahito Ueda