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Zinc-blende CdSe semiconducting nanoplatelets (NPL) show outstanding quantum confinement properties thanks to their small, atomically-controlled, thickness. For example, they display extremely sharp absorption peaks that make them very…

应用物理 · 物理学 2019-12-09 Ivan Dozov , Claire Goldmann , Patrick Davidson , Benjamin Abécassis

Colloidal semiconductor nanoplatelets combine weak lateral confinement with strong Coulomb interactions, enhanced by dielectric confinement. When the platelets are charged with carriers of the same sign, this results in severe Coulomb…

介观与纳米尺度物理 · 物理学 2021-06-01 Jordi Llusar , Juan I. Climente

We show theoretically that carriers confined in semiconductor colloidal nanoplatelets (NPLs) sense the presence of neighbor, cofacially stacked NPLs in their energy spectrum. When approaching identical NPLs, the otherwise degenerate energy…

介观与纳米尺度物理 · 物理学 2020-04-21 Jose L. Movilla , Josep Planelles , Juan I. Climente

Single-molecule photoluminescence (PL) spectroscopy of semiconductor nanocrystals (NCs) reveals the nature of exciton-phonon interactions in NCs. Understanding the narrow line shapes at low temperatures and the significant broadening as…

介观与纳米尺度物理 · 物理学 2023-08-22 Kailai Lin , Dipti Jasrasaria , Jason J. Yoo , Moungi Bawendi , Hendrik Utzat , Eran Rabani

We propose and demonstrate a method for the construction of highly uniform, multilayered, orientation-controlled superstructures of CdSe/CdZnS core/shell colloidal nanoplatelets (NPLs) using bi-phase liquid interface. These atomically-flat…

Colloidal Cadmium Selenide (CdSe) nanoplatelets (NPLs) are a recently developed class of efficient luminescent nanomaterial suitable for optoelectronic device applications. A change in temperature greatly affects their electronic…

介观与纳米尺度物理 · 物理学 2017-10-26 Sumanta Bose , Sushant Shendre , Zhigang Song , Vijay Kumar Sharma , Dao Hua Zhang , Cuong Dang , Weijun Fan , Hilmi Volkan Demir

Luminescent colloidal CdSe nanorings are a new type of semiconductor structure that have attracted interest due to the potential for unique physics arising from their non-trivial toroidal shape. However, the exciton properties and dynamics…

The optoelectronic properties of metal chalcogenide colloidal nanoplatelets are often interpreted in terms of excitonic states. However, recent spectroscopic experiments evidence the presence of trion states, enabled by the slow Auger…

介观与纳米尺度物理 · 物理学 2021-05-06 David F. Macías-Pinilla , Josep Planelles , Iván Mora-Seró , Juan I. Climente

We present a theoretical description of excitons and positively and negatively charged trions in "giant" CdSe/CdS core-shell nanocrystals (NCs). The developed theory provides the parameters describing the fine structure of excitons in…

材料科学 · 物理学 2015-06-12 A. Shabaev , A. V. Rodina , Al. L. Efros

Colloidal semiconductor nanoplatelets (NPLs) with electronic structure as quantum wells have recently emerged as exciting materials for optoelectronic applications. Here we investigate how morphology affects important photoluminescence (PL)…

介观与纳米尺度物理 · 物理学 2018-03-23 Zhongjian Hu , Ajay Singh , Serguei V. Goupalov , Jennifer A. Hollingsworth , Han Htoon

Spontaneous strain and spontaneous folding of thin nanoplatelets are known phenomena whose microscopic mechanisms are still debating. In this work, first-principles calculations are used to study the mechanical stresses that arise in Janus…

材料科学 · 物理学 2024-05-21 Alexander I. Lebedev

CdSe nanoplatelets show perfectly quantized thicknesses of few monolayers. They present a situation of extreme, yet well defined quantum confinement. Due to large dielectric contrast between the semiconductor and its ligand environment,…

Colloidal nanoplatelets (NPLs) are promising materials for lasing applications. The properties are usually discussed in the framework of 2D materials, where strong excitonic effects dominate the optical properties near the band edge. At the…

Recently, the fabrication of CdSe nanoplatelets became an important research topic. Nanoplatelets are often described as having a similar electronic structure as 2D dimensional quantum wells and are promoted as colloidal quantum wells with…

介观与纳米尺度物理 · 物理学 2017-06-28 Marten Richter

Colloidal semiconductor nanocrystals are promising materials for classical and quantum light sources due to their versatile chemistry and efficient photoluminescence (PL) properties. While visible emitters are well-established, the pursuit…

Colloidal semiconductor nanocrystals are promising building blocks for optoelectronics due to their solution processability, spectral tunability, and ability to self-assemble into complex architectures. However, their use in lasing…

We investigated the nonlinear optical properties of CdSe/CdS nanoplatelets in the vicinity of heavy hole and light hole exciton resonances. The two color pump-probe technique was applied. The first intense pulse created non-equilibrium…

We show that the finite lateral sizes of ultrathin CdSe nanoplatelets strongly affect both their photoluminescence and optical absorption spectra. This is in contrast to the situation in quantum wells, in which the large lateral sizes may…

Two-dimensional colloidal nanoplatelets (NPLs) with atomically defined thickness exhibit unique physical properties, yet understanding their formation mechanism and assembly remains essential for tuning their collective behavior. We report…

Atomically flat semiconductor nanostructures have sharp photoluminescence emission, short radiative lifetimes and a well-defined planar structure. However, these nanostructures lack the optical and electronic fine-tuning that justify…

材料科学 · 物理学 2015-09-29 Sébastien Lamarre , Étienne Rochette , Samuel Tremblay , Claudine Nì. Allen
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