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We study mixtures of charged surfactants, which alone in solution form uni- and multilamellar vesicles, and oppositely charged polyelectrolytes (PEs). The phase behavior is investigated at fixed surfactant concentration as a function of the…

软凝聚态物质 · 物理学 2007-05-23 Laurence Ramos , Edith Vivares

Surfactant solutions exhibit multilamellar surfactant vesicles (MLVs) under flow conditions and in concentration ranges which are found in a large number of industrial applications. MLVs are typically formed from a lamellar phase and play…

流体动力学 · 物理学 2018-06-11 Angelo Pommella , Dario Donnarumma , Sergio Caserta , Stefano Guido

Polyelectrolyte-surfactant complexes (PESCs) have long been employed as oil-in-water (o/w) emulsions stabilizers, but never in the structure of colloidal complex coacervates providing a Pickering effect. The complexed state of PESCs could…

软凝聚态物质 · 物理学 2021-05-10 Sandrine Laquerbe , Alain Carvalho , Marc Schmutz , Alexandre Poirier , Niki Baccile , Ghazi Ben Messaoud

We present real-time observations by confocal microscopy of the dynamic behavior of multilamellar vesicles (MLVs), composed of charged synthetic lipids, when put in contact with oppositely charged polyelectrolyte (PE) molecules. We find…

软凝聚态物质 · 物理学 2007-10-01 Yuxia Luan , Laurence Ramos

Polyelectrolyte multilayers (PEM) in combination with good electrolyte solvents, e.g., ionic liquids (ILs) are potential candidates for the new generation of electrochemical separators. Swelling PEM with aqueous IL solutions is one way to…

化学物理 · 物理学 2018-11-20 Nagma Parveen , Pritam Kumar Jana , Monika Schoenhoff

Polypeptide-based diblock copolymers forming either well-defined self-assembled micelles or vesicles after direct dissolution in water or in dichloromethane, have been studied combining light and neutron scattering with electron microscopy…

Hydrophobic polyelectrolytes (HPE) can solubilize bilayer membranes, form micelles or can reversibly aggregate as a function of pH. The transitions are often remarkably sharp. We show that these cooperative transitions occur by a…

软凝聚态物质 · 物理学 2023-02-01 James L. Martin Robinson , Willem. K Kegel

The fabrication of polyelectrolyte multilayer films (PEMs) using the Layer-by-Layer (LbL) method is one of the most versatile approaches for manufacturing functional surfaces. This is the result of the possibility to control the assembly…

软凝聚态物质 · 物理学 2024-02-08 Eduardo Guzman , Ramon G. Rubio , Francisco Ortega

Poly(ethylene oxide)-$\textit{b}$-poly(butylmethacrylate) (PEO-$\textit{b}$-PBMA) copolymers have recently been identified as excellent building blocks for the synthesis of hierarchical nanoporous materials. Nevertheless, while experiments…

软凝聚态物质 · 物理学 2021-06-01 Gerardo Campos-Villalobos , Flor R. Siperstein , Arvin Charles , Alessandro Patti

This work presents a simply methodology for coating small unilamellar liposomes bearing different degrees of positive charge with polyelectrolyte multilayers using the sequential Layer-by-Layer (LbL) deposition method. The liposomes were…

Lipid vesicles consist of aqueous cores surrounded by a bilayer of phospholipids. Hybrid polymer-lipid vesicles incorporate both polymers and lipids, offering promising properties for developing pharmaceuticals, biosensors, and artificial…

In this paper, phase field models are developed for multi-component vesicle membranes with different lipid compositions and membranes with free boundary. These models are used to simulate the deformation of membranes under the elastic…

生物物理 · 物理学 2007-05-23 Xiaoqiang Wang , Qiang Du

Transition metal dichalcogenides (TMDs) host multiple competing structural and electronic phases, making them an ideal platform for constructing polytype heterostructures with emergent quantum properties. However, controlling phase…

Surfactant self-assembly at solid-liquid interfaces governs interfacial stability, transport, and reactivity across many technologies, yet resolving interfacial surfactant phases and their transition kinetics in situ remains challenging.…

Polyelectrolyte (PE) brushes have ubiquitous applications as surface modifiers which regulate various structural and dynamic properties. Here, we apply a continuous-space self-consistent field theory to study the structural heterogeneity in…

软凝聚态物质 · 物理学 2024-12-25 Takashi Yokokura , Chao Duan , Rui Wang

Polyelectrolyte surfactant mixtures and their interactions with fluid interfaces are an important research field due to their use in technological applications. Most of the existing knowledge on these systems is based on models in which the…

Colloidal photonic crystals display peculiar optical properties which make them particularly suitable for application in different fields. However, the low packing fraction of the targeted structures usually poses a real challenge in the…

软凝聚态物质 · 物理学 2017-09-28 Guido Avvisati , Tonnishtha Dasgupta , Marjolein Dijkstra

In this work, we study the adhesion of multi-component vesicle membrane to both flat and curved substrates, based on the conventional Helfrich bending energy for multi-component vesicles and adhesion potentials of different forms. A phase…

生物物理 · 物理学 2015-05-14 Yanxiang Zhao , Sovan Das , Qiang Du

We investigate multilayer systems of a normal insulator and a Weyl semimetal. We calculate the bulk band structure and determine phase diagrams by changing the thickness of the normal insulator and that of the Weyl semimetal layer using two…

介观与纳米尺度物理 · 物理学 2017-04-12 Kazuki Yokomizo , Shuichi Murakami

It is widely agreed that phase change materials (PCMs) are of high interest for sustainable energy future. Many of the applications require anti-leakage properties of PCM, that can be accomplished through PCM encapsulation. In this study,…

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