相关论文: Transition states and entangled mass action law

Adaptive multilevel splitting algorithms have been introduced rather recently for estimating tail distributions in a fast and efficient way. In particular, they can be used for computing the so-called reactive trajectories corresponding to…

We present experimentally and numerically accessible quantities that can be used to differentiate among various families of random entangled states. To this end, we analyze the entanglement properties of bipartite reduced states of a…

The conflict between Quantum Mechanics (QM) and the intuitive concepts of Locality and Realism (LR) is manifest in the correlation between measurements performed in remote regions of a spatially spread entangled state. In this paper, it is…

In this paper mechanisms of reversion - momentum transition are considered. Two basic nonlinear mechanisms are highlighted: a slow and fast bifurcation. A slow bifurcation leads to the equilibrium evolution, preceded by stability loss delay…

For two molecules to react they first have to meet. Yet, reaction times are rarely on par with the first-passage times that govern such molecular encounters. A prime reason for this discrepancy is stochastic transitions between reactive and…

We use the master equation approach to calculate the energy level shifts of an atom in the presence of a general dielectric semi-infinite medium characterized by a dielectric constant $\epsilon(\omega)$. Particularly, we analyze the case of…

We develop a theory for inferring equilibrium transition rates from trajectories driven by a time dependent force using results from stochastic thermodynamics. Applying the Kawasaki relation to approximate the nonequilibrium distribution…

We discuss the connection between absorption, averages and fluctuations in nuclear reactions. The fluctuations in the entrance channel result in the compound nucleus, Hauser-Feshbach, cross section, the fluctuations in the intermediate…

The important, and often dominant, role of tunneling in low temperature kinetics has resulted in numerous theoretical explorations into the methodology for predicting it. Nevertheless, there are still key aspects of the derivations that are…

We investigate the asymptotic rates of entanglement transformations for bipartite mixed states by local operations and classical communication (LOCC). We analyse the relations between the rates for different transitions and obtain simple…

We find conditions required to achieve complete population transfer, via coherent population trapping, from an initial state to a designated final state at a designated time in a degenerate $n$-state atom, where transitions are caused by an…

The stability of high vs. low spin states of transition metal complexes has been interpreted by ligand field theory, which is a perturbation theory of the electron-electron interaction. The present first principles calculation of a series…

We show that entanglement-assisted transformations of bipartite entangled states can be more efficient than catalysis [D. Jonathan and M. B. Plenio, Phys. Rev. Lett. 83, 3566 (1999)}, i.e., given two incomparable bipartite states not only…

Predicting cellular metabolic states is a central problem in biophysics. Conventional approaches, however, sensitively depend on the microscopic details of individual metabolic systems. In this Letter, we derived a universal linear…

We show that the system entropy change for the transitions between non-equilibrium steady states arbitrarily far from equilibrium for any constituting process is given by the relative entropy of the distributions of these steady states.…

These lectures advocate the idea that quantum entanglement provides a unifying foundation for both statistical physics and high-energy interactions. I argue that, at sufficiently long times or high energies, most quantum systems approach a…

Many systems that can be described in terms of diffusion-limited `chemical' reactions display non-equilibrium continuous transitions separating active from inactive, absorbing states, where stochastic fluctuations cease entirely. Their…

A study is made of the power-law tail effect in the quantum particle distribution over momentum on the nuclear fusion reactions. Our results do not support the idea of averaging the fusion reaction cross-section over the momentum…

Transition path theory provides a statistical description of the dynamics of a reaction in terms of local spatial quantities. In its original formulation, it is limited to reactions that consist of trajectories flowing from a reactant set A…

Based on the monogamy of entanglement, we develop the technique of quantum conditioning to build an {\it additive} entanglement measure: the conditional entanglement of mutual information. Its {\it operational} meaning is elaborated to be…