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Highly oxygen defective cerium oxide, e.g. Gd-doped ceria is a sustainable non-classical electrostrictor with electromechanical properties that are superior to lead-based piezoelectric metal oxides. Here, we report electrostriction in…

应用物理 · 物理学 2020-06-17 Ahsanul Kabir , Jacob R. Bowen , Maxim Varenik , Igor Lubomirsky , Vincenzo Esposito

In this report, the effect of the cold sintering process (CSP) on the electro-chemo-mechanical properties of 10 mol% Gd-doped ceria (GDC) is investigated. High purity nanoscale GDC powder is sintered via a cold sintering process (CSP) in…

材料科学 · 物理学 2020-06-17 Ahsanul Kabir , Daoyao Ke , Salvatore Grasso , Benoit Merle , Vincenzo Esposito

Some oxygen defective metal oxides, such as cerium and bismuth oxides, have recently shown exceptional electrostrictive properties that are even superior to the best performing lead-based electrostrictors, e.g. lead-magnesium-niobates…

Rare earth cerium oxide (ceria) nanoparticles are stabilized using end-functional phosphonated-PEG oligomers. The complexation process and structure of the resulting hybrid core-shell singlet nanocolloids are described, characterized and…

软凝聚态物质 · 物理学 2008-04-23 L. Qi , A. Sehgal , J. -C. Castaing , J. -P. Chapel , J. Fresnais , J. -F. Berret , F. Cousin

In light of the recent discovery of giant electrostriction in defective fluorites, here we investigate the interplay between mechanical, electrochemical and electromechanical properties of oxygen defective ceria compositions as the effect…

应用物理 · 物理学 2020-02-18 Ahsanul Kabir , Jin Kyu Han , Benoit Merle , Vincenzo Esposito

The current work studies the effect of sintering conditions on the densification behavior, microstructure, and electrochemical performance of 6 mol% Sc2O3, 1 mol% CeO2 co-doped ZrO2 (6Sc1CeZr) for solid-state electrolyte applications. The…

材料科学 · 物理学 2022-11-01 Pooya Elahi , Elizabeth Winterholler , Taylor D. Sparks

CeO$_x$-based nanoforms are widely used in catalysis, or biomedical applications due to their redox activity and oxygen storage capacity. The key parameters determining their surface chemistry are the Ce$^{3+}$/Ce$^{4+}$ ratio and the…

Eutectics of Sapphire/Yttrium-Aluminum garnet and Ce-doped Sapphire/Yttrium-Aluminum garnet (Ce up to 1 at.%) with a Chinese script microstructure were obtained by the method of horizontal directional crystallization in a carbon-containing…

材料科学 · 物理学 2024-12-10 L. O. Hryn , Yu. V. Siryk , V. V. Baranov , O. M. Vovk , S. V. Naydenov , S. V. Nizhankovsky

The study investigates the density, phase composition, microstructure and mechanical properties (microhardness, fracture toughness) of binderless WC + SiC and WC + SiC + C ceramics obtained by Spark Plasma Sintering (SPS). Nanopowders of…

The defect induced magnetism has initiated a lot of interest in field of spintronics. In this regard, SiC is a promising material because of its unique properties under extreme conditions. Hence it will be very much interesting to…

材料科学 · 物理学 2019-10-29 Gyanti Prakash Moharana , Rahul Kothari , S. K. Singh , N. Harish Kumar

We present a rigorous finite element method to calculate circular dichroism (CD) in various systems consisting of nanostructures and oriented chiral molecules with electric quadrupole transitions. The interaction between oriented molecule…

光学 · 物理学 2017-12-27 Weixuan Zhang , Tong Wu , Rongyao Wang , Xiangdong Zhang

Oxygen defective cerium oxides exhibits a non classical giant electromechanical response that is superior to lead based electrostrictors. In this work, we report the key role of acceptor dopants, with different size and valence Mg2+, Sc3+,…

We discuss the effect of the local field polarization in metallic nanostructures where large field enhancements can be induced by excitation of localized surface plasmons. To demonstrate the importance of these effects, we study a few model…

化学物理 · 物理学 2007-05-23 E. C. Le Ru , P. G. Etchegoin

Nanoparticle sintering remains a critical challenge in heterogeneous catalysis. In this work, we present a unified deep potential (DP) model for Cu nanoparticles on three Al$_2$O$_3$ surfaces ($\gamma$-Al$_2$O$_3$(100),…

材料科学 · 物理学 2025-01-30 Jiayan Xu , Shreeja Das , Amar Deep Pathak , Abhirup Patra , Sharan Shetty , Detlef Hohl , Roberto Car

Cerium oxide nanoparticles have been shown to mimic oxidoreductase enzymes by catalyzing the decomposition of organic substrates and reactive oxygen species. This mimicry can be found in superoxide radicals and hydrogen peroxides, harmful…

The behavior of saturated aqueous sodium chloride solutions under a constant external electric field (E) was studied by molecular dynamics (MD) simulation. Our dynamic MD simulations have indicated that the irreversible nucleation process…

软凝聚态物质 · 物理学 2016-01-20 Gan Ren , Yanting Wang

We optimize the superconducting properties of Sm-based oxypnictide (Sm1111: SmFeAsO0.80F0.20) by using the Spark Plasma Sintering (SPS) technique under various synthesis conditions, including heating temperatures ranging from 600 to 1000…

超导电性 · 物理学 2025-06-02 Mohammad Azam , Tatiana Zajarniuk , Konrad Kwatek , Paolo Mele , Shiv J. Singh

Degenerately doped semiconductor nanocrystals (NCs) exhibit a localized surface plasmon resonance (LSPR) in the infrared range of the electromagnetic spectrum. Unlike metals, semiconductor NCs offer tunable LSPR characteristics enabled by…

Flash sintering is an approach allowing reducing the sintering time to mere seconds. To improve the microstructures and the properties of flash sintered specimens, this process has been successfully adapted to pressure assisted sintering…

化学物理 · 物理学 2020-11-24 Charles Manière , Guillaume Riquet , Sylvain Marinel

Nanomaterials made of the cerium oxides CeO$_2$ and Ce$_2$O$_3$ have a broad range of applications, from catalysts in automotive, industrial or energy operations to promising materials to enhance hadrontherapy effectiveness in oncological…

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