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Magnetic hysteresis has become a crucial aspect for characterizing single-molecule magnets, but the comprehension of the coercivity mechanism is still a challenge. By using analytical derivation and quantum dynamical simulations, we reveal…

材料科学 · 物理学 2023-09-08 Lei Gu , Qiancheng Luo , Guoping Zhao , Yan-Zhen Zheng , Ruqian Wu

Single-molecule magnets (SMMs) with chemically tailorable properties are potential building blocks for quantum computing, high-density magnetic memory, and spintronics.1 2 3,4 These applications require isolated or few molecules on…

Single molecular magnets (SMMs) and Metal-Organic Frameworks (MOFs) attract significant interest due to their potential in quantum information processing, scalable quantum computing, and extended lifetimes and coherence times. The limiting…

量子物理 · 物理学 2024-07-12 Nosheen Younas , Yu Zhang , Andrei Piryatinski , Eric R Bittner

We investigate how different chemical environment influences magnetic properties of terbium(III) (Tb)-based single-molecule magnets (SMMs), using first-principles relativistic multireference methods. Recent experiments showed that Tb-based…

化学物理 · 物理学 2020-07-01 Ryan Pederson , Aleksander L. Wysocki , Nicholas Mayhall , Kyungwha Park

Modeling blocking temperature in molecular magnets has been a long standing problem in the field of molecular magnetism. We investigate this problem using a kinetic Monte Carlo (kMC) approach on an assembly of 100,000 short molecular…

强关联电子 · 物理学 2021-06-23 Sumit Haldar , S. Ramasesha

Single-molecule magnets (SMMs) are promising candidates for molecular-scale data storage and processing due to their strong magnetic anisotropy and long spin relaxation times. However, as temperature rises, interactions between electronic…

材料科学 · 物理学 2024-12-11 Soumi Haldar , Lorenzo A. Mariano , Alessandro Lunghi , Laura Gagliardi

This article takes a broad view of the understanding of magnetic bistability and magnetic quantum tunneling in single-molecule magnets (SMMs), focusing on three families of relatively simple, low-nuclearity transition metal clusters: spin S…

The interplay of strong single-ion anisotropy and magnetic interactions often give rise to novel magnetic behavior and can provide additional routes for controlling magnetization dynamics. However, novel effects arising from interactions…

Single-molecule magnets (SMMs) exhibiting open hysteresis loops may potentially apply to molecule-based information processing and storage. However, the capacity to retain magnetic memory is always limited by zero-field quantum tunneling of…

In this work we study theoretically the coupling of single molecule magnets (SMMs) to a variety of quantum circuits, including microwave resonators with and without constrictions and flux qubits. The main results of this study is that it is…

介观与纳米尺度物理 · 物理学 2013-09-27 M. D. Jenkins , T. Hümmer , M. J. Martínez-Pérez , J. García-Ripoll , D. Zueco , F. Luis

Single-molecule magnets are among the most promising platforms for achieving molecular-scale data storage and processing. Their magnetisation dynamics are determined by the interplay between electronic and vibrational degrees of freedom,…

It is shown that dipolar and weak superexchange interactions between the spin systems of single-molecule magnets (SMM) play an important role in the relaxation of magnetization. These interactions can reduce or increase resonant tunneling.…

介观与纳米尺度物理 · 物理学 2009-11-07 W. Wernsdorfer , S. Bhaduri , R. Tiron , D. N. Hendrickson , G. Christou

Single-molecule magnets (SMMs) are molecules that can function as nanoscale magnets with potential use as magnetic memory bits. While SMMs can retain magnetization at low temperatures, characterizing them on surface and at room temperature…

The role of spin polarized reservoirs in quantum tunneling of magnetization and relaxation processes in a single molecular magnet (SMM) is investigated theoretically. The SMM is exchange-coupled to the reservoirs and also subjected to a…

介观与纳米尺度物理 · 物理学 2016-08-16 Maciej Misiorny , Józef Barnas

The magnetization reversal in a single molecular magnet (SMM) weakly coupled to an electrode with spin-dependent splitting of chemical potentials (spin bias) is theoretically investigated by means of the rate equation. A microscopic…

介观与纳米尺度物理 · 物理学 2009-05-14 Hai-Zhou Lu , Bin Zhou , Shun-Qing Shen

Magnetic switching of a single molecular magnet (SMM) due to spin-polarized current flowing between ferromagnetic metallic electrodes is investigated theoretically. Magnetic moments of the electrodes are assumed to be collinear and parallel…

介观与纳米尺度物理 · 物理学 2016-08-16 Maciej Misiorny , Józef Barnas

A new family of supramolecular, antiferromagnetically exchange-coupled dimers of single-molecule magnets (SMMs) has recently been reported [W. Wernsdorfer, N. Aliaga-Alcalde, D.N. Hendrickson, and G. Christou, Nature 416, 406 (2002)]. Each…

介观与纳米尺度物理 · 物理学 2009-11-10 R. Tiron , W. Wernsdorfer , D. Foguet-Albiol , N. Aliaga-Alcalde , G. Christou

The first measurements of magnetization hysteresis loops on diluted single crystal of [(Pc)2Ho]-TBA+ (Pc: phthalocyaninato, TBA: tetrabutylammonium) in the subkelvin temperature range are reported. Characteristic staircase-like structure…

介观与纳米尺度物理 · 物理学 2007-05-23 N. Ishikawa , M. Sugita , W. Wernsdorfer

Single-molecule magnets weakly coupled to two ferromagnetic leads act as memory devices in electronic circuits---their response depends on history, not just on the instantaneous applied voltage. We show that magnetic anisotropy introduces a…

介观与纳米尺度物理 · 物理学 2012-09-24 Carsten Timm , Massimiliano Di Ventra

The discovery a decade ago that individual molecules can function as magnetizable magnets provided a new, 'bottom-up' approach to nanoscale magnetic materials, and such molecules have since been called single-molecule magnets (SMMs). Each…

介观与纳米尺度物理 · 物理学 2007-05-23 A. J. Tasiopoulos , A. Vinslava , W. Wernsdorfer , K. A. Abboud , G. Christou
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