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Using molecular dynamics simulations, we study the slow dynamics of supercooled liquids confined in a random matrix of immobile obstacles. We study the dynamical crossover from glass-like to Lorentz-gas-like behavior in terms of the density…

软凝聚态物质 · 物理学 2011-05-30 Kang Kim , Kunimasa Miyazaki , Shinji Saito

Many systems, including polymers and molecular liquids, when adequately cooled and/or compressed, solidify into a disordered solid, i.e., a glass. The~transition is not abrupt, featuring progressive decrease of the microscopic mobility and…

软凝聚态物质 · 物理学 2019-11-19 Francesco Puosi , Antonio Tripodo , Dino Leporini

We investigate the heterogeneous dynamics in a model, where chemical gelation and glass transition interplay, focusing on the dynamical susceptibility. Two independent mechanisms give raise to the correlations, which are manifested in the…

软凝聚态物质 · 物理学 2017-05-09 Antonio de Candia , Annalisa Fierro , Raffaele Pastore , Massimo Pica Ciamarra , Antonio Coniglio

One of the hallmarks of molecular dynamics in deeply supercooled liquids is the non-exponential character of the relaxation functions. It has been a long standing issue if 'universal' features govern the lineshape of glassy dynamics…

Metallic glasses are promising materials with unique mechanical and thermal properties, but their atomic-scale dynamics remain challenging to understand. In this work, we develop a unified approach to investigate the glass transition and…

材料科学 · 物理学 2025-02-07 Anh D. Phan , Do T. Nga , Ngo T. Que , Hailong Peng , Thongchanh Norhourmour , Le M. Tu

Dynamic and structural heterogeneities play an important role in glass transition phenomena and in the formation of amorphous structures. Since structure and dynamics are mutually related, it is expected that there exists some relation…

We report a molecular dynamics (MD) study of the collective dynamics of a simple monatomic liquid -interacting through a two body potential that mimics that of lithium- across the liquid-glass transition. In the glassy phase we find…

无序系统与神经网络 · 物理学 2009-11-07 T. Scopigno , G. Ruocco , F. Sette , G. Viliani

We study the nature of the glass transition by cooling model atomistic glass formers at constant rate from a temperature above the onset of glassy dynamics to $T=0$. Motivated by the East model, a kinetically constrained lattice model with…

统计力学 · 物理学 2018-04-16 Alexander Hudson , Kranthi K. Mandadapu

The attenuation rate of vibrational excitations in various metallic liquids and glasses has been reported to change from the quadratic dependence on wavevector at low wavevectors to the linear dependence at high wavevectors. However, the…

无序系统与神经网络 · 物理学 2021-10-22 Jaeyun Moon , Takeshi Egami

Analysis of temperature dependence of structural relaxation time in supercooled liquids revealed a qualitatively distinct feature - a sharp, cusp-like maxumum in the second derivative of its logarithm. It suggests that the super-Arrhenius…

软凝聚态物质 · 物理学 2016-01-20 V. N. Novikov , A. P. Sokolov

Employing wide-angle neutron spin echo spectroscopy, we measured the Q-dependent coherent intermediate scattering function of the prototypical ionic glass former Ca0.4K0.6(NO3)1.4, in the equilibrium and supercooled liquid states beyond the…

In this paper the phenomenon of dynamic heterogeneity in supercooled liquid systems is considered in terms of the recently proposed gauge theory of glass transition. The physical interpretation of the dynamic scaling is considered. It is…

统计力学 · 物理学 2015-06-23 Mikhail Vasin

We use computer simulations to study the microscopic dynamics of an athermal assembly of soft particles near the fluid-to-solid, jamming transition. Borrowing tools developed to study dynamic heterogeneity near glass transitions, we…

材料科学 · 物理学 2010-06-24 Claus Heussinger , Ludovic Berthier , Jean-Louis Barrat

Supercooled liquids display dynamics that are inherently heterogeneous in space. This essentially means that at temperatures below the melting point, particle dynamics in certain regions of the liquid can be orders of magnitude faster than…

软凝聚态物质 · 物理学 2021-01-04 Dipanwita Ghoshal , Ashwin Joy

Short-timescale atomic rearrangements are fundamental to the kinetics of glasses and frequently dominated by one atom moving significantly (a rearrangement), while others relax only modestly. The rates and directions of such rearrangements…

材料科学 · 物理学 2022-11-17 Ajay Annamareddy , Bu Wang , Paul M. Voyles , Dane Morgan

Investigating million-atom systems for very long simulation times, we demonstrate that the collective density-density correlation time ($\tau_{\alpha}$) in simulated supercooled water and silica becomes wavevector independent ($q^0$) when…

统计力学 · 物理学 2019-05-20 Philip H. Handle , Lorenzo Rovigatti , Francesco Sciortino

The liquid and supercooled states of water show a series of anomalies whose nature is debated. A key role is attributed to the formation of structural aggregates induced by critical phenomena occurring deep in the supercooled region; the…

化学物理 · 物理学 2013-12-18 A. Taschin , P. Bartolini , R. Eramo , R. Righini , R. Torre

We study supercooled dynamics in quantum hard-sphere liquid using quantum mode-coupling formulation. In the moderate quantum regime, classical cage effects lead to slower dynamics compared to strongly quantum regime, where tunneling…

统计力学 · 物理学 2021-02-03 Ankita Das , Eran Rabani , Kunimasa Miyazaki , Upendra Harbola

Modern detector technology and highly brilliant fourth-generation synchrotrons allow to improve the temporal resolution in time-resolved diffraction studies. Profiting from this, we applied temperature scanning X-ray photon correlation…

Using molecular dynamics simulations we investigate the finite-size dependence of the dynamical properties of a diatomic supercooled liquid. The simplicity of the molecule permits us to access the microsecond time scale. We find that the…

软凝聚态物质 · 物理学 2017-12-06 Sonia Taamalli , Julia Hinds , Samuel Migirditch , Victor Teboul