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Atom-ion interactions occur through the electric dipole which is induced by the ion on the neutral atom. In a Langevin collision, in which the atom and ion overcome the centrifugal barrier and reach a short internuclear distance, their…

Self-assembled molecular structures have been intensively used in molecular electronics and spintronics. However, detailed nature of the interfaces between molecular layers and extended metallic contacts used to bias the real devices…

We present a novel method for the simulation of the vibration-induced autoionization dynamics in molecular anions in the framework of the quantum-classical surface hopping approach. Classical trajectories starting from quantum initial…

化学物理 · 物理学 2023-02-01 Kevin Issler , Roland Mitric , Jens Petersen

This paper presents the inversion symmetry breaking observed in ion-pair formation from molecular hydrogen on electron impact. We explain these observations using quantum interference of two dissociation paths coherently accessed by…

化学物理 · 物理学 2024-04-17 Akshay Kumar , Suvasis Swain , Vaibhav S. Prabhudesai

A numerical simulation of vibrational excitation of molecules was devised, and used to excite computational models of common molecules into a prescribed, pure, normal vibration mode in the ground electronic state, with varying, controlable…

天体物理学 · 物理学 2009-11-11 Renaud Papoular

Cold molecules are important for many applications, from fundamental precision measurements, quantum information processing, quantum-controlled chemistry, to understanding the cold interstellar medium. Molecular ions are known to be cooled…

We develop a microscopic approach to the consistent construction of the kinetic theory of dilute weakly ionized gases of hydrogen-like atoms. The approach is based on the framework of the second quantization method in the presence of bound…

统计力学 · 物理学 2016-12-08 Yu. V. Slyusarenko , O. Yu. Sliusarenko

We demonstrated sympathetic cooling of a single ion in a buffer gas of ultracold atoms with small mass. Efficient collisional cooling was realized by suppressing collision-induced heating. We attempt to explain the experimental results with…

原子物理 · 物理学 2018-02-07 Shinsuke Haze , Mizuki Sasakawa , Ryoichi Saito , Ryosuke Nakai , Takashi Mukaiyama

The intermolecular interactions in the title compound are investigated using self-consistent charge density functional based tight binding molecular dynamics. Emphasis is put on the analysis of correlated motions of ion pairs using ideas of…

化学物理 · 物理学 2016-03-22 Tobias Zentel , Oliver Kühn

Studying chemical reactions at very low temperatures is of importance for the understanding of fundamental physical and chemical processes. At very low energies, collisions are dominated by only a few partial waves. Thus, studies in this…

化学物理 · 物理学 2017-03-30 Dongdong Zhang , Stefan Willitsch

We consider the nonequilibrium quantum vibrations of a molecule clamped between two macroscopic leads in a current-carrying state at finite voltages. Our approach is based on the nonequilibrium Green function technique and the…

介观与纳米尺度物理 · 物理学 2007-05-23 D. A. Ryndyk , M. Hartung , G. Cuniberti

Results are presented for the dynamics arising due to a sudden quench of a boson interaction parameter with the simultaneous switching on of a commensurate periodic potential, the latter providing a source of non-linearity that can cause…

统计力学 · 物理学 2015-06-16 Marco Tavora , Aditi Mitra

A system of identical bosons with short-range (contact) interactions is studied. Their motion is confined to one dimension by a tight lateral trapping potential and, additionally, subject to a weak harmonic confinement in the longitudinal…

量子气体 · 物理学 2015-05-20 Igor E. Mazets

A model based on the strong-field and Born-Oppenheimer approximations qualitatively describes the distribution over vibrational states formed in a diatomic molecular ion following ionization of the neutral molecule by intense laser pulses.…

原子物理 · 物理学 2007-05-23 Thomas Kim Kjeldsen , Lars Bojer Madsen

Atomic quantum gases in the strong-correlation regime offer unique possibilities to explore a variety of many-body quantum phenomena. Reaching this regime has usually required both strong elastic and weak inelastic interactions, as the…

其他凝聚态物理 · 物理学 2008-06-27 N. Syassen , D. M. Bauer , M. Lettner , T. Volz , D. Dietze , J. J. Garcia-Ripoll , J. I. Cirac , G. Rempe , S. Dürr

The molecular anion C$_2^-$ has been of interest in the last few years as a candidate for laser cooling due to its electronic structure and favourable branching ratios to the ground electronic and vibrational state. Molecular hydrogen has…

Currently, molecular tunnel junctions are recognized as important active elements of various nanodevices. This gives a strong motivation to study physical mechanisms controlling electron transport through molecules. Electron motion through…

介观与纳米尺度物理 · 物理学 2013-01-24 Natalya A. Zimbovskaya

In recent years, ultracold atoms have emerged as an exceptionally controllable experimental system to investigate fundamental physics, ranging from quantum information science to simulations of condensed matter models. Here we go one step…

原子物理 · 物理学 2015-05-20 Christoph Zipkes , Lothar Ratschbacher , Stefan Palzer , Carlo Sias , Michael Köhl

We conduct experiments on two-dimensional packings of colloidal thermosensitive hydrogel particles whose packing fraction can be tuned above the jamming transition by varying the temperature. By measuring displacement correlations between…

We are interested in a kinetic equation intended to describe the interaction of particles with their environment. The environment is modeled by a collection of local vibrational degrees of freedom. We establish the existence of weak…

偏微分方程分析 · 数学 2016-03-14 Stephan De Bièvre , Arthur Vavasseur , Thierry Goudon