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A remarkable amount of theoretical research has been carried out to elucidate the physical origins of the recently observed long-lived quantum coherence in the electronic energy transfer process in biological photosynthetic systems.…

量子物理 · 物理学 2015-03-19 Sangwoo Shim , Patrick Rebentrost , Stéphanie Valleau , Alan Aspuru-Guzik

Biomolecular light-harvesting antennas operate as nanoscale devices in a regime where the coherent interactions of individual light, matter and vibrational quanta are non-perturbatively strong. The complex behaviour arising from this could,…

量子物理 · 物理学 2020-07-28 A. W. Chin , B. Le Dé , E. Mangaud , O. Atabek , M. Desouter-Lecomte

Protein electrostatics tune excitation energies in the Photosystem II reaction center (PSII-RC), yet a fully quantum-mechanical many-body description of how the surrounding protein environment renormalizes excitons has remained…

化学物理 · 物理学 2026-02-25 Tucker Allen , Barry Y. Li , Nadine C. Bradbury , Daniel Neuhauser

We investigate the charge re-distribution upon optical excitation of various necked homodimer CQDMs using single particle emission spectroscopy. By tuning the hybridization of the electron wavefunction at a fixed center-to-center distance…

介观与纳米尺度物理 · 物理学 2023-06-27 Somnath Koley , Jiabin Cui , Yossef. E. Panfil , Yonatan Ossia , Adar Levi , Einav Scharf , Lior Verbitsky , Uri Banin

Recently, exciton-photon strong coupling has been proposed as a means to control and enhance energy transfer in ensembles of organic molecules. Here, we demonstrate that the exciton dynamics in an archetypal purple bacterial photosynthetic…

Two-dimensional optical spectroscopy experiments have shown that exciton transfer pathways in the Fenna-Matthews-Olson (FMO) photosynthetic complex differ drastically under reduced and oxidised conditions, suggesting a functional role for…

In transition metal dichalcogenides layers of atomic scale thickness, the electron-hole Coulomb interaction potential is strongly influenced by the sharp discontinuity of the dielectric function across the layer plane. This feature results…

Active control of dark long-lived excitonic states in molecular aggregates using local electric fields is a pivotal challenge for advancing nanoscale optoelectronics and quantum device engineering. This experimental study investigates the…

Exciton dissociation via the excitonic Mott transition (EMT) governs the high-density optical response of semiconductors and sets fundamental limits for optoelectronic devices. The EMT is conventionally linked to the onset of population…

We study carrier interaction induced many-body effects on the excitonic optical properties of highly photoexcited one-dimensional semiconductor quantum wire systems by solving the dynamically screened Bethe-Salpeter equation using realistic…

强关联电子 · 物理学 2009-11-07 D. W. Wang , S. Das Sarma

The concept of \textit{optical} exciton - a photo-excited bound electron-hole pair within a crystal - is routinely used to interpret and model a wealth of excited-state phenomena in semiconductors. Beside originating sub-band gap signatures…

材料科学 · 物理学 2022-09-21 Fulvio Paleari , Andrea Marini

Natural organisms such as photosynthetic bacteria, algae, and plants employ complex molecular machinery to convert solar energy into biochemical fuel. An important common feature shared by most of these photosynthetic organisms is that they…

生物物理 · 物理学 2018-08-29 Seogjoo J. Jang , Benedetta Mennucci

Simulating the irreversible quantum dynamics of exciton and electron transfer problems poses a nontrivial challenge. Because the irreversibility of the system dynamics is a result of quantum thermal activation and dissipation caused by the…

化学物理 · 物理学 2021-03-30 Seiji Ueno , Yoshitaka Tanimura

In this paper we analyze the dynamics of single-excitation states, which model the scattering of a single photon from multiple two level atoms. For short times and weak atom-field couplings we show that the atomic amplitudes are given by a…

数学物理 · 物理学 2021-10-15 Jeremy Hoskins , Jason Kaye , Manas Rachh , John Schotland

Excitons are vital in the photophysics of materials, especially in low-dimensional systems. The conceptual and quantitative understanding of excitonic effects in nonlinear optical (NLO) processes is more challenging compared to linear ones.…

材料科学 · 物理学 2026-02-26 Jiawei Ruan , Y. -H. Chan , Steven G. Louie

The rigorous quantum mechanical description of the collective interaction of many molecules with the radiation field is usually considered numerically intractable, and approximation schemes must be employed. Standard spectroscopy usually…

化学物理 · 物理学 2023-05-10 Bingyu Cui , Maxim Sukharev , Abraham Nitzan

In a previous paper [Phys.Rev.E 83, 051911] we have shown that the results of a quantum-mechanical calculation of electronic energy transfer (EET) over aggregates of coupled monomers can be described also by a model of interacting classical…

量子物理 · 物理学 2012-05-18 A. Eisfeld , J. S. Briggs

The system-environment interaction is simulated by light propagating in coupled photonic waveguides. The profile of the electromagnetic field provides intuitive physical insight to study the Markovian and non-Markovian dynamics of open…

量子物理 · 物理学 2013-12-16 Chang-Ling Zou , Xiang-Dong Chen , Xiao Xiong , Fang-Wen Sun , Xu-Bo Zou , Zheng-Fu Han , Guang-Can Guo

The use of ultra-short laser pulses to pump and probe materials activates a wealth of processes which involve the coherent and non coherent dynamics of interacting electrons out of equilibrium. Non equilibrium (NEQ) many body perturbation…

介观与纳米尺度物理 · 物理学 2018-08-15 Davide Sangalli , Enrico Perfetto , Gianluca Stefanucci , Andrea Marini