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According to the Wulff construction the shape of the equilibrium crystal is determined by the surface tension considered as a function of the interface orientation. We present some (conjectured) approximate solutions and some rigorous…

统计力学 · 物理学 2012-06-19 Salvador Miracle-Sole

This chapter discusses the equilibrium crystal shape (ECS) from a physical perspective, beginning with a historical introduction to the Wulff theorem. It takes advantage of excellent prior reviews, particularly in the late 1980's, recapping…

统计力学 · 物理学 2015-01-12 Theodore L. Einstein

The shape of an equilibrium crystal is obtained, according to the Gibbs thermodynamic principle, by minimizing the total surface free energy associated to the crystal-medium interface. To study the solution to this problem, known as the…

统计力学 · 物理学 2013-07-22 Salvador Miracle-Sole

Crystal morphologies are important for the design and functionality of devices based on low-dimensional nanomaterials. The equilibrium crystal shape (ECS) is a key quantity in this context. It is determined by surface energies, which are…

材料科学 · 物理学 2015-08-26 Hong Li , Lutz Geelhaar , Henning Riechert , Claudia Draxl

The present work revisits the classical Wulff problem restricted to crystalline integrands, a class of surface energies that gives rise to finitely faceted crystals. The general proof of the Wulff theorem was given by J.E. Taylor (1978) by…

偏微分方程分析 · 数学 2021-02-26 Thaicia Stona de Almeida

Geometrical constructions, such as the tangent construction on the molar free energy for determining whether a particular composition of a solution, is stable, are related to similar tangent constructions on the orientation-dependent…

材料科学 · 物理学 2007-05-23 J. W. Cahn , W. C. Carter

We present two-dimensional crystallization results in the square lattice for finite particle systems consisting of two different atomic types. We identify energy minimizers of configurational energies featuring two-body short-ranged…

统计力学 · 物理学 2020-04-22 Manuel Friedrich , Leonard Kreutz

We consider nematic liquid crystals in a bounded, convex polyhedron described by a director field n(r) subject to tangent boundary conditions. We derive lower bounds for the one-constant elastic energy in terms of topological invariants.…

数学物理 · 物理学 2009-11-10 A Majumdar , JM Robbins , M Zyskin

We investigate connections between the continuum and atomistic descriptions of deformable crystals, using certain interesting results from number theory. The energy of a deformed crystal is calculated in the context of a lattice model with…

数学物理 · 物理学 2020-07-02 Phoebus Rosakis

We use surface tension to distinguish between phases with isotropic internal structure from phases which are microscopically anisotropic. There are many interesting open problems, especially in two dimensions, and in phase coexistence.

数学物理 · 物理学 2017-07-28 Charles Radin

Given recipe of qualitative, kinetic modelling by geometric methods of three-dimensional dendritic crystals. Characteristic features of the perturbations appearing on the surface of a spherical body, leading to different scenarios of the…

材料科学 · 物理学 2018-10-05 Alexander S. Prokhoda

We study the stability of closed, not necessarily smooth, equilibrium surfaces of an anisotropic surface energy for which the Wulff shape is not necessarily smooth. We show that if the Cahn Hoffman field can be extended continuously to the…

微分几何 · 数学 2011-10-20 Bennett Palmer

The finite size and interface effects on equilibrium crystal shape (ECS) have been investigated for the case of a surface free energy density including step stiffness and inverse-square step-step interactions. Explicitly including the…

材料科学 · 物理学 2009-11-11 M. Degawa , F. Szalma , E. D. Williams

Here, we propose a comprehensive first-principle atomistic approach to predict the Wulff-Kaischew equilibrium shape of crystals heterogeneously integrated on a dissimilar material. This method uses both reconstructed surface and interface…

The calculation of the discrete atomistic energy of a crystal near the continuum limit encounters difficulties caused by the geometric discrepancy between the continuum region occupied by the body, and the discrete collection of lattice…

数学物理 · 物理学 2016-05-06 Phoebus Rosakis

Surface energies for different GaAs surface orientations have been calculated as a function of the chemical potential. We use an energy density formalism within the first-principles pseudopotential density-functional approach. The…

mtrl-th · 物理学 2009-10-30 N. Moll , A. Kley , E. Pehlke , M. Scheffler

The topology and the geometry of a surface play a fundamental role in determining the equilibrium configurations of thin films of liquid crystals. We propose here a theoretical analysis of a recently introduced surface Frank energy, in the…

数学物理 · 物理学 2015-06-18 Antonio Segatti , Michael Snarski , Marco Veneroni

Topological spin textures emerging in magnetic materials usually appear in crystalline states. A long-standing dilemma is whether we should understand these emergent crystals as gathering particles or coupling waves, the answer of which…

介观与纳米尺度物理 · 物理学 2018-12-18 Yangfan Hu

Quantum states naturally represent symmetry groups, though often in a projective sense. Intriguingly, the projective nature of crystalline symmetries has remained underexplored until very recently. A series of groundbreaking theoretical and…

介观与纳米尺度物理 · 物理学 2025-09-25 Chen Zhang , Shengyuan A. Yang , Y. X. Zhao

It is shown theoretically that a one-dimensional crystal with time reversal symmetry is characterized by a Z_{2} topological invariant that predicts the existence or otherwise of edge states. This is confirmed experimentally through the…

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