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We study the surface plasmon (SP) resonance energy of isolated spherical Ag nanoparticles dispersed on a silicon nitride substrate in the diameter range 3.5-26 nm with monochromated electron energy-loss spectroscopy. A significant blueshift…

We study the blueshift of the surface plasmon (SP) resonance energy of isolated Ag nanoparticles with decreasing particle diameter, which we recently measured using electron energy loss spectroscopy (EELS). As the particle diameter…

光学 · 物理学 2013-11-05 Søren Raza , Wei Yan , Nicolas Stenger , Martijn Wubs , N. Asger Mortensen

In electron energy-loss spectroscopy (EELS) of individual silver nanoparticles encapsulated in silicon nitride, we observe besides the usual dipole resonance an additional surface plasmon (SP) resonance corresponding to higher angular…

We present an electron energy loss study using energy filtered TEM of spatially resolved surface plasmon excitations on a silver nanorod of aspect ratio 14.2 resting on a 30 nm thick silicon nitride membrane. Our results show that the…

We have investigated the effects of tuning the localized surface plasmon resonances (LSPRs) of silver nanoparticles on the fluorescence intensity, lifetime, and Raman signal from nearby fluorophores. The presence of a metallic structure can…

其他凝聚态物理 · 物理学 2009-11-13 N. I. Cade , T. Ritman-Meer , D. Richards

According to the hydrodynamic Drude model, surface-plasmon resonances of metallic nanostructures blueshift owing to the nonlocal response of the metal's electron gas. The screening length characterising the nonlocal effect is often small…

光学 · 物理学 2016-07-07 Ory Schnitzer , Vincenzo Giannini , Stefan A. Maier , Richard V. Craster

Damping rates of multipolar, localized surface plasmons (SP) of gold and silver nanospheres of radii up to $1000nm$ were found with the tools of classical electrodynamics. The significant increase in damping rates followed by noteworthy…

光学 · 物理学 2012-11-21 Krystyna Kolwas , Anastasiya Derkachova

A quantum-mechanical model to calculate the electron energy-loss spectra (EELS) for the system of a closely located metallic nanoshell and a molecule has been developed. At the resonance between the molecular excitation and plasmon modes in…

原子物理 · 物理学 2014-10-07 I. Yu. Goliney , Ye. V. Onykienko

We develop a theoretical model of the surface plasmon resonance of metallic nanospheres in the size range down to the single nanometer size. Within this model we explicitly show how different microscopic mechanisms, namely quantization due…

光学 · 物理学 2013-08-26 R. Carmina Monreal , Tomasz J. Antosiewicz , S. Peter Apell

Localized surface plasmons are charge density oscillations confined to metallic nanoparticles. Excitation of localized surface plasmons by an electromagnetic field at an incident wavelength where resonance occurs results in a strong light…

偏微分方程分析 · 数学 2015-06-03 Habib Ammari , Pierre Millien , Matias Ruiz , Hai Zhang

The ability to engineer localized surface plasmon resonances at large scale usually relies on precise nanoscale patterning. Here, we demonstrate that mid-infrared plasmonic responses can instead emerge in unpatterned polysilicon films…

Inspired by recent measurements on individual metallic nanospheres that can not be explained with traditional classical electrodynamics, we theoretically investigate the effects of nonlocal response by metallic nanospheres in three distinct…

介观与纳米尺度物理 · 物理学 2014-03-07 Thomas Christensen , Wei Yan , Søren Raza , Antti-Pekka Jauho , N. Asger Mortensen , Martijn Wubs

Electron microscopy techniques such as electron energy-loss spectroscopy (EELS) facilitate the spatio-spectral characterization of plasmonic nanostructures. In this work, a time-dependent perspective is presented, which significantly…

In this paper we provide a mathematical framework for localized plasmon resonance of nanoparticles. Using layer potential techniques associated with the full Maxwell equations, we derive small-volume expansions for the electromagnetic…

数学物理 · 物理学 2015-10-28 Habib Ammari , Youjun Deng , Pierre Millien

Electromagnetic theory predicts that the optimal value of the localized plasmon resonance (LPR) wavelength for the maximal SERS enhancement factor (EF) is half the sum of the laser and Raman wavelengths. For small Raman shifts, the…

Localized surface plasmon resonances have recently attracted considerable attention due to their ability to dramatically enhance near-field optical intensities and boost nanoscale light-matter interactions. Here we demonstrate unambiguously…

光学 · 物理学 2013-01-30 Neda Ghofraniha , Pascal Andrè , Andrea Di falco , Claudio Conti

Two possible mechanisms of surface plasmon (SP) oscillations damping in metallic nanoparticles (MNPs), not connected with electron-phonon interaction are investigated theoretically: a) the radiation damping of SP, b) resonant coupling of SP…

介观与纳米尺度物理 · 物理学 2009-11-10 Armen Melikyan , Hayk Minassian

Near surface silver nanoparticles embedded in silicon oxide were obtained by 40 keV silver negative ion implantation without the requirement of an annealing step. Ion beam induced local heating within the film leads to an exo-diffusion of…

A many-body Green's function approach to the microscopic theory of plasmon-enhanced spectroscopy is presented within the context of localized surface-plasmon resonance spectroscopy and applied to investigate the coupling between…

化学物理 · 物理学 2015-05-14 David J. Masiello , George C. Schatz

Localized surface plasmon resonances (LSPRs) have recently been identified in extremely diluted electron systems obtained by doping semiconductor quantum dots. Here we investigate the role that different surface effects, namely electronic…

光学 · 物理学 2015-04-29 R. Carmina Monreal , Tomasz J. Antosiewicz , S. Peter Apell
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