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A large class of liquids have hidden scale invariance characterized by a scaling exponent. In this letter we present experimental evidence that the scaling exponent of liquid dynamics is state-point dependent for the glass-forming silicone…

软凝聚态物质 · 物理学 2019-03-07 Alejandro Sanz , Tina Hecksher , Henriette Wase Hansen , Kristine Niss , Ulf R. Pedersen

Since its initial discovery more than fifteen years ago, the thermodynamical scaling of the dynamics of supercooled liquids has been used to provide many new important insights in the physics of liquids, particularly on the link between…

软凝聚态物质 · 物理学 2019-11-04 Riccardo Casalini , Timothy C. Ransom

Based on previous works on polymers by Bauer et al. [Phys, Rev. B (2000)], this paper describes a capacitative method for measuring the dynamical expansion coefficient of a viscous liquid. Data are presented for the glass-forming liquid…

软凝聚态物质 · 物理学 2015-03-19 Kristine Niss , Ditte Gundermann , Tage Christensen , Jeppe C. Dyre

The frequency-dependent dielectric constant, shear and adiabatic bulk moduli, longitudinal thermal expansion coefficient, and longitudinal specific heat have been measured for two van der Waals glass-forming liquids,…

软凝聚态物质 · 物理学 2012-02-28 Bo Jakobsen , Tina Hecksher , Kristine Niss , Tage Christensen , Niels Boye Olsen , Jeppe C. Dyre

We present new viscosity and equation of state (EoS) results extending to high pressures for o-terphenyl, salol, and dibutylphthalate. Using these and data from the literature, we show that the three liquids all conform to density scaling;…

软凝聚态物质 · 物理学 2016-08-24 R. Casalini , S. S. Bair , C. M. Roland

The magnitude of the high frequency, static dielectric permittivity is used to determine the density of tetramethyl tetraphenyl trisiloxane, a non-associated glass-forming liquid, as a function of temperature and pressure. We demonstrate…

软凝聚态物质 · 物理学 2017-10-11 R. Casalini , C. M. Roland

We use a recently proposed method [Berthier L.; Biroli G.; Bouchaud J.P.; Cipelletti L.; El Masri D.; L'Hote D.; Ladieu F.; Pierno M. Science 2005, 310, 1797.] to obtain an approximation to the 4-point dynamic correlation function from…

软凝聚态物质 · 物理学 2009-08-27 D. Fragiadakis , R. Casalini , C. M. Roland

It was recently shown by computer simulations that a large class of liquids exhibits strong correlations in their thermal fluctuations of virial and potential energy [Pedersen et al., Phys. Rev. Lett. 100, 015701 (2008)]. Among organic…

Many glass-forming fluids exhibit a remarkable thermodynamic scaling in which dynamic properties, such as the viscosity, the relaxation time, and the diffusion constant, can be described under different thermodynamic conditions in terms of…

软凝聚态物质 · 物理学 2015-06-16 Wen-Sheng Xu , Karl F. Freed

Classification of glass-forming liquids based on the dramatic change in their properties upon approach to the glassy state is appealing, since this is the most conspicuous and often-studied aspect of the glass transition. Herein, we show…

软凝聚态物质 · 物理学 2009-11-10 R. Casalini , C. M. Roland

Pressure dependence of longitudinal relaxation time (T$_1$) due to the cell wall was observed previously at both room temperature and low temperature in valved Rb-coated refillable $^3$He gaseous cells in \cite{Zheng2}. The diffusion of…

原子物理 · 物理学 2013-03-05 C. Peng , W. Zheng , P. -H. Chu , H. Gao , Y. Zhang

The incoherent dynamic structure factor of ortho-terphenyl has been measured by neutron time-of-flight and backscattering technique in the pressure range from 0.1 MPa to 240 MPa for temperatures between 301 K and 335 K. Tagged-particle…

统计力学 · 物理学 2011-04-05 A. Toelle , H. Schober , J. Wuttke , F. Fujara

We investigate the swelling and shrinking of L_beta lamellar gel phases composed of surfactant and fatty alcohol after contact with aqueous poly(ethylene-glycol) solutions. The height change $\Delta h(t)$ is diffusion-like with a swelling…

软凝聚态物质 · 物理学 2011-05-11 David J Fairhurst , Mark E Baker , Neil Shaw , Stefan U. Egelhaaf

Tetrahedral liquids such as water and silica-melt show unusual thermodynamic behavior such as a density maximum and an increase in specific-heat when cooled to low temperatures. There is a debate in the literature whether these phenomena…

统计力学 · 物理学 2011-08-10 Itamar Procaccia , Ido Regev

We present results of theoretical description and numerical calculation of the dynamics of molecular liquids based on the Reference Interaction Site Model / Mode-Coupling Theory. They include the temperature-pressure(density) dependence of…

化学物理 · 物理学 2007-05-23 A. E. Kobryn , T. Yamaguchi , F. Hirata

We report an experimental study of carrier density (n), displacement field (D) and twist angle ({\theta}) dependence of temperature (T)-linear resistivity in twisted double bilayer graphene (TDBG). For a large twist angle…

A disordered (glassy) state has been searched in solid 3He deformed in the course of experiment employing precise measurements of pressure. The analysis of the temperature dependence of the crystal pressure measured at a constant volume…

其他凝聚态物理 · 物理学 2015-05-20 A. A. Lisunov , V. A. Maidanov , V. Yu. Rubanskiy , S. P. Rubets , E. Ya. Rudavskii , A. S. Rybalko , V. A. Tikhii

We show by atomistic simulations that, in the thermodynamic limit, the in-plane elastic moduli of graphene at finite temperature vanish with system size $ L $ as a power law $ ~ L^{-\eta_u} $ with $ \eta_u \simeq 0.325 $, in agreement with…

介观与纳米尺度物理 · 物理学 2016-01-13 J. H. Los , A. Fasolino , M. I. Katsnelson

In this paper we present an overview of results in the literature regarding the thermodynamical scaling of the dynamics of liquids and polymers as measured from high-pressure measurements. Specifically, we look at the scaling exponent…

软凝聚态物质 · 物理学 2020-01-08 Riccardo Casalini , Timothy C. Ransom

Dielectric spectroscopy measurements over a broad range of temperature and pressure were carried out on poly(oxybutylene) (POB), a type-A polymer (dielectrically-active normal mode). There are three dynamic processes appearing at lower…

软凝聚态物质 · 物理学 2009-11-10 R. Casalini , C. M. Roland
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