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Self-consistent field theory (SCFT) has proven to be a powerful tool for modeling equilibrium microstructures of soft materials, particularly for multiblock polymers. A very successful approach to numerically solving the SCFT set of…

软凝聚态物质 · 物理学 2017-01-04 David M. Ackerman , Kris Delaney , Glenn H. Fredrickson , Baskar Ganapathysubramanian

Self-consistent field theory (SCFT) is one of the most widely-used framework in studying the equilibrium phase behaviors of inhomogenous polymers. For liquid crystalline polymeric systems, the main numerical challenges of solving SCFT…

数值分析 · 数学 2024-09-16 Zhijuan He , Kai Jiang , Liwei Tan , Xin Wang

In this paper, we develop an adaptive high-order surface finite element method (FEM) incorporating the spectral deferred correction method for chain contour discretization to solve polymeric self-consistent field equations on general curved…

数值分析 · 数学 2021-08-03 Kai Jiang , Xin Wang , Jianggang Liu , Huayi Wei

Self-consistent field theory (SCFT) is one of the useful methods to simulate phase separated structures of multi-component polymer systems. In this article, we propose an SCFT for semiflexible polymer melts, where the basic equations for…

软凝聚态物质 · 物理学 2025-03-04 Yutaka Oya , Toshihiro Kawakatsu

The self-consistent field theory (SCFT) is a powerful framework for the study of the phase behavior and structural properties of many-body systems. In particular, polymeric SCFT has been successfully applied to inhomogeneous polymeric…

软凝聚态物质 · 物理学 2019-01-31 An-Chang Shi

We present numerical calculations of lamellar phases of block copolymers at patterned surfaces. We model symmetric di-block copolymer films forming lamellar phases and the effect of geometrical and chemical surface patterning on the…

软凝聚态物质 · 物理学 2016-02-18 Xingkun Man , David Andelman , Henri Orland

Self-consistent field theory (SCFT) and strong segregation theory (SST) are used to explore the parameter space governing the self-assembly of cylinder forming block copolymers (BCPs) on a modulated substrate. The stability of in-plane…

材料科学 · 物理学 2018-11-16 Karim Gadelrab , Alfredo Alexander-Katz

Diblock copolymers blended with homopolymer may self-assemble into spherical, cylindrical or lamellar aggregates. Transitions between these structures may be driven by varying the homopolymer molecular weight or the molecular weight or…

统计力学 · 物理学 2011-06-28 M. J. Greenall , D. M. A. Buzza , T. C. B. McLeish

We investigate equilibrium microstructures exhibited by diblock copolymers in confined 3D geometries. We perform Self-Consistent Field Theory (SCFT) simulations using a finite-element based computational framework (Ackerman et al. 2017),…

软凝聚态物质 · 物理学 2019-10-22 Ananth Tenneti , David M Ackerman , Baskar Ganapathysubramanian

An efficient pseudo-spectral numerical method is introduced for calculating a self-consistent field (SCF) approximation for the linear susceptibility of ordered phases in block copolymer melts (sometimes referred to as the random phase…

软凝聚态物质 · 物理学 2009-11-13 Amit Ranjan , Jian Qin , David C. Morse

We present a self-consistent field theory (SCFT) study of spherical micelle formation in a blend of poly(styrene-butadiene) diblocks and homopolystyrene. The micelle core radii, corona thicknesses and critical micelle concentrations are…

软凝聚态物质 · 物理学 2011-06-28 M. J. Greenall , D. M. A. Buzza , T. C. B. McLeish

Self-Consistent Field Theory is applied to a film of cylindrical-forming block copolymer subject to a surface field which tends to align the cylinders parallel to electrical plates, and to an external electric field tending to align them…

软凝聚态物质 · 物理学 2009-11-11 Chin-Yet Lin , M. Schick

This work presents a general and unified theory describing block copolymer self-assembly in the presence of free surfaces and nanoparticles in the context of Self-Consistent Filed Theory. Specifically, the derived theory applies to free and…

软凝聚态物质 · 物理学 2021-12-17 Daniil Bochkov , Ivana Bagaric , Gaddiel Ouaknin , Frederic Gibou

In this paper we study a system of advection-diffusion equations in a bulk domain coupled to an advection-diffusion equation on an embedded surface. Such systems of coupled partial differential equations arise in, for example, the modeling…

数值分析 · 数学 2014-12-09 Sven Gross , Maxim A. Olshanskii , Arnold Reusken

The self-consistent field theory is a popular and highly successful theoretical framework for studying equilibrium (co)polymer systems at the mesoscopic level. Dynamic density functionals allow one to use this framework for studying…

软凝聚态物质 · 物理学 2021-02-15 Friederike Schmid , Bing Li

The Intrinsic Surface Finite Element Method (ISFEM) was recently proposed to solve Partial Differential Equations (PDEs) on surfaces. ISFEM proceeds by writing the PDE with respect to a local coordinate system anchored to the surface and…

数值分析 · 数学 2024-10-08 Elena Bachini , Mario Putti

We compare two theoretical approaches to dielectric diblock copolymer melts in an external electric field. The first is a relatively simple analytic expansion in the relative copolymer concentration, and includes the full electrostatic…

软凝聚态物质 · 物理学 2012-01-31 Yoav Tsori , David Andelman , Chin-Yet Lin , M. Schick

Disordered hyperuniform (DHU) systems are recently discovered exotic states of matter, where (normalized) large-scale density fluctuations are completely suppressed as in crystals, even though the systems are isotropic and lack conventional…

软凝聚态物质 · 物理学 2024-03-26 Duyu Chen , Michael A. Klatt , Glenn H. Fredrickson

The paper introduces an adaptive version of the stabilized Trace Finite Element Method (TraceFEM) designed to solve low-regularity elliptic problems on level-set surfaces using a shape-regular bulk mesh in the embedding space. Two…

数值分析 · 数学 2024-08-21 Timo Heister , Maxim A. Olshanskii , Vladimir Yushutin

This paper concerns the analytic structure of the self-consistent field theory (SCFT) energy functional of multicomponent block copolymer systems which contain more than two chemically distinct blocks. The SCFT has enjoyed considered…

计算物理 · 物理学 2013-10-07 Kai Jiang , Weiquan Xu , Pingwen Zhang
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