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Spin-orbit coupling in heavy 5$d$ metal oxides, in particular, iridates have received tremendous interest in recent years due to the realization of exotic electronic and magnetic phases. Here, we report the synthesis, structural, magnetic,…

强关联电子 · 物理学 2022-10-26 Harish Kumar , M. Köpf , A. Ullrich , M. Klinger , A. Jesche , C. A. Kuntscher

Materials with formula of A2B2O7 is a famous family with more than 300 compounds, and have abundant properties, like ferroelectric, multiferroic, and photocatalyst properties, etc. Generally, two structures dominate this family, which are…

The ground state of the quantum spin ice candidate magnet Yb2Ti2O7 is known to be sensitive to weak disorder at the 1 percent level which occurs in single crystals grown from the melt. Powders produced by solid state synthesis tend to be…

强关联电子 · 物理学 2016-03-09 J. Gaudet , K. A. Ross , E. Kermarrec , N. P. Butch , G. Ehlers , H. A. Dabkowska , B. D. Gaulin

Crystal growth experiments (micro-pulling down or Czochralski methods, respectively) and DTA/TG measurements with Fe2+ containing olivines (fayalite--forsterite solid solution) and with FeO (wustite) are performed. For both substances the…

材料科学 · 物理学 2008-01-16 D. Klimm , S. Ganschow

Density Functional Theory calculations have been performed to obtain lattice parameters, elastic constants, and electronic properties of ideal pyrochlores with the composition A$_2$B$_2$O$_7$ (where A=La,Y and B=Ti,Sn,Hf, Zr). Some thermal…

材料科学 · 物理学 2009-11-11 J. M. Pruneda , Emilio Artacho

We report on the synthesis of LiCrTe$_2$ single crystals and on their anisotropic magnetic properties. We have obtained these single crystals by employing a Te/Li-flux synthesis method. We find LiCrTe$_2$ to crystallize in a TlCdS$_2$ -type…

Single crystals of a novel ruthenate, Ca2Ru2O7, were obtained. An X-ray diffraction study on a single crystal revealed that this material crystallizes in a pyrochlore structure with a lattice parameter, a = 10.197 Angstroms. The magnetic…

材料科学 · 物理学 2009-11-11 Taiya Munenaka , Hirohiko Sato

Non-Fermi liquid behavior in some fermionic systems have attracted significant interest in last few decades. Certain pyrochlore iridates with stronger spin-orbit coupling strength have recently been added to the list. Here, we provide…

We present an interpretation of zero field diffuse neutron scattering and of high field magnetisation data at very low temperature in the frustrated pyrochlore system Tb2Ti2O7. This material has antiferromagnetic exchange interactions and…

强关联电子 · 物理学 2013-12-16 P. Bonville , A. Gukasov , I. Mirebeau , S. Petit

We investigated the high temperature decomposition behavior of wurtzite phase Ti$_{1-x}$Al$_{x}$N films using experimental methods and first-principles calculations. Single phase metastable wurtzite Ti$_{1-x}$Al$_{x}$N (x = 0.65, 0.75, 085…

In this work we present a new chemical route to synthesize Tm2Mn2O7 pyrochlore, a compound which is thermodynamically unstable at ambient pressure. Differently from the reported in the past high pressure synthesis of the same compound…

The availability of large high-quality single crystals is an important prerequisite for many studies in solid-state research. The optical floating-zone technique is an elegant method to grow such crystals, offering potential to prepare…

Dark blue single crystals of Al$_{1.75}^{3+}$ Ti$_{1.0}^{4+}$ Ti$_{0.25}^{3+}$O$_5$ were grown with a novel synthesis method based on the reaction of a Ti3+/Ti4+ containing langbeinite melt and Al$_2$O$_3$. The obtained needles crystallize…

材料科学 · 物理学 2022-12-02 Davor Tolj , WenHua Bi , Yong Liu , Ivica Zivkovic , Henrik M. Ronnow , Arnaud Magrez

Time-of-flight neutron powder diffraction and specific heat measurements were used to study the nature of thermal expansion in rhenium trioxide, an electrically conducting oxide with cubic symmetry. The temperature evolution of the lattice…

Iron oxide nano particles with nominal Fe2O3 stoichiometry were synthesized by a wet, soft chemical method with the heat treatment temperatures from 250{\deg}C to 900{\deg}C in air. The variation in the structural properties of the nano…

材料科学 · 物理学 2011-11-29 Debajeet K. Bora , Artur Braun , Selma Erat , Olga Safonova , Thomas Graule , Edwin C. Constable

We report on growth-mode transitions in the growth of SrRuO3 thin films on atomically flat Ti4+ single-terminated SrTiO3 (111) substrates, investigated by reflection high-energy electron diffraction and atomic force microscopy. Over the…

材料科学 · 物理学 2010-02-03 Jaewan Chang , Yoon-Seok Park , Jong-Woo Lee , Sang-Koog Kim

We report a detailed study of structural and magnetic properties of the pyrochlore-type (Bi2-xPrx)Ru2O7 series. Eleven compositions with 0 <= x <= 2 were prepared by solid state reaction at 1050 degrees C and found to form a solid solution…

材料科学 · 物理学 2008-12-16 Siwar Zouari , Rafik Ballou , Abdelwaheb Cheikh-Rouhou , Pierre Strobel

We report high resolution single crystal x-ray diffraction measurements of the frustrated pyrochlore magnet Tb2Ti2O7, collected using a novel low temperature pulsed magnet system. This instrument allows characterization of structural…

We report on the growth of stoichiometric Sr$_2$IrO$_4$ single crystals, which allow us to unveil their intrinsic magnetic properties. The effect of different growth conditions has been investigated for crystals grown by the flux method. We…

强关联电子 · 物理学 2016-04-27 N. H. Sung , H. Gretarsson , D. Proepper , J. Porras , M. Le Tacon , A. V. Boris , B. Keimer , B. J. Kim

The antiferromagnetic pyrochlore material NaCaCo$_2$F$_7$ is a thermal spin liquid over a broad temperature range (~ 140 K down to $T_F = 2.4 $K), in which magnetic correlations between Co$^{2+}$ dipole moments explore a continuous manifold…

强关联电子 · 物理学 2017-04-26 K. A. Ross , J. M. Brown , R. J. Cava , J. W. Krizan , S. E. Nagler , J. A. Rodriguez-Rivera , M. B. Stone