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The striking anomalies in physical properties of supercooled water that were discovered in the 1960-70s, remain incompletely understood and so provide both a source of controversy amongst theoreticians, and a stimulus to experimentalists…

化学物理 · 物理学 2016-05-31 Sander Woutersen , Michiel Hilbers , Zuofeng Zhao , C. Austen Angell

The effect of a rigid, non-polar and nonmesogenic solute biphenyl ((C_{6}H_{5}-C_{6}H_{5})) on the divergence of the bend elastic constant K_{33} of (4,4^{\prime}) -n-octyl-cyanobiphenyl (8CB) near the smecticA-nematic transition is…

软凝聚态物质 · 物理学 2009-11-07 Sudeshna DasGupta , Soumen Kumar Roy

In this work we numerically study the switching dynamics of a 2D cholesteric emulsion droplet immersed in an isotropic fluid under an electric field, which is either uniform or rotating with constant speed. The overall dynamics depend…

软凝聚态物质 · 物理学 2017-09-13 Federico Fadda , Giuseppe Gonnella , Davide Marenduzzo , Enzo Orlandini , Adriano Tiribocchi

We theoretically investigate the threshold for the director reorientation from the homeotropic state to the hybrid homeotropic-planar state and vice versa in a cell filled with a flexoelectric nematic liquid crystal (NLC) subjected to an…

软凝聚态物质 · 物理学 2021-03-30 O. S. Tarnavskyy , M. F. Ledney

We numerically investigate the phase behavior of thick shells of cholesteric liquid crystals with tangential anchoring at the shell boundary. For achiral liquid crystal, we demonstrate a thickness-dependent transition from a configuration…

软凝聚态物质 · 物理学 2025-01-03 Arda Bulut , Yusuf Sariyar , Giuseppe Negro , Livio Nicola Carenza

When liquids are classified using Tg -scaled Arrhenius plots of relaxation times (or relative rates of entropy increase above Tg) across a "strong-fragile" spectrum of behaviors, the "strong" liquids have always appeared rather…

软凝聚态物质 · 物理学 2015-06-12 C. Austen Angell , Mahin Hemmati

Engineering phase change materials (PCM) to realize superior data storage devices requires a detailed understanding of crystallization kinetics and its temperature dependence. The temperature dependence of crystallization differs distinctly…

材料科学 · 物理学 2021-03-12 Julian Pries , Julia Sehringer , Shuai Wei , Pierre Lucas , Matthias Wuttig

Recent experiments have demonstrated that the glass transition temperature of thin polymer films can be shifted as compared to the same polymer in the bulk, the amplitude and the sign of this effect depending on the interaction between the…

统计力学 · 物理学 2007-05-23 D. Long , P. Sotta

Molecular dynamics simulations are performed to study the [100] and [111] orientations of the crystal-melt interface between an ordered two-component hard sphere with a NaCl structure and its coexisting binary hard-sphere fluid. The…

化学物理 · 物理学 2009-11-07 Rachel Sibug-Aga , Brian B. Laird

Numerical heat and mass transfer analysis of a configuration where a cool liquid hydrocarbon is suddenly introduced to a hotter gas at supercritical pressure shows that a well-defined phase equilibrium can be established before substantial…

流体动力学 · 物理学 2022-04-25 Jordi Poblador-Ibanez , William A. Sirignano

Phase behavior of liquid crystals is of long-standing interest due to numerous applications, with one of the key issues being how the presence of impurities affects the liquid crystalline order. Here we study the orientational order of…

软凝聚态物质 · 物理学 2019-10-15 Pritam Kumar Jana , Julien Lam , Nagma Parveen , Mikko J Alava , Lasse Laurson

We provide experimental evidence that photoalignment at the nematic liquid crystal (NLC) - polymer interface can not be simply considered as a two-dimensional process. Moreover, our experiments clearly indicate that the photoaligning…

软凝聚态物质 · 物理学 2019-03-14 Tibor Tóth-Katona , István Jánossy

Random (disordered) components in the surface anchoring of the smectic-A liquid crystalline film in general modify the thermal pseudo-Casimir interaction. Anchoring disorder of the quenched type is in general decoupled from the thermal…

软凝聚态物质 · 物理学 2020-10-01 Fahimeh Karimi Pour Haddadan , Ali Naji , Rudolf Podgornik

We investigated both numerically and experimentally the dynamics of individual ZnO nanowires immersed in an in-plane switching (IPS) 4-Cyano-4-pentylbiphenyl (5CB) liquid crystal cell under switching electric fields. Comparing the motion of…

材料科学 · 物理学 2016-12-16 Yin Tao , Yiu Ho Tam

The intriguing role of the presence of solutes in the activity of a self-propelling droplet is investigated. A system of self-propelling micron sized 4-pentyl-4-biphenylcarbonitrile (5CB) droplets in an aqueous solution of…

软凝聚态物质 · 物理学 2021-02-24 Prateek Dwivedi , Bishwa Ranjan Si , Dipin S. Pillai , Rahul Mangal

Above a critical temperature known as the Leidenfrost point (LFP), a heated surface can suspend a liquid droplet above a film of its own vapor. The insulating vapor film can be highly detrimental in metallurgical quenching and thermal…

流体动力学 · 物理学 2021-02-16 Tom Y. Zhao , Neelesh A. Patankar

We report the observation of a premelting transition at chemically sharp solid-liquid interfaces using molecular-dynamics simulations. The transition is observed in the solid-Al/liquid-Pb system and involves the formation of a liquid…

材料科学 · 物理学 2015-06-12 Yang Yang , Mark Asta , Brian B. Laird

We use molecular dynamics computer simulations and nuclear magnetic resonance experiments to investigate the dynamics of water at interfaces of molecular roughness and low mobility. We find that, when approaching such interfaces, the…

软凝聚态物质 · 物理学 2014-07-22 Markus Rosenstihl , Kerstin Kämpf , Felix Klameth , Matthias Sattig , Michael Vogel

Controlled crystallization, melting and vitrification are important fundamental processes in nature and technology. However, the microscopic details of these fundamental phenomena still lack understanding, in particular how the cooling rate…

软凝聚态物质 · 物理学 2024-07-08 M. P. M. Schelling , T. W. J. Verouden , T. C. M. Stevens , J. -M. Meijer

So far the problem of interface behavior upon phase transition has not yet acquired a satisfactory mathematical formulation due to a variety of the physical phenomena involved. Analytical solutions exist only for elementary problems…

统计力学 · 物理学 2011-08-12 Alex Guskov