相关论文: The principle underlying antiaromaticity

We show that, in presence of a complex spectrum, antiresonances act as a precursor for dephasing enabling the crossover to a fully decoherent transport even within a unitary Hamiltonian description. This general scenario is illustrated here…

The uncertainty principle is fundamentally rooted in the algebraic asymmetry between observables. We introduce a new class of uncertainty relations grounded in the resource theory of asymmetry, where incompatibility is quantified by an…

In the context of the relationship between physics of cosmological dark matter and symmetry of elementary particles a wide list of dark matter candidates is possible. New symmetries provide stability of different new particles and their…

The energy difference between two iso-electronic systems can be accurately approximated by the alchemical first order Hellmann-Feynmann derivative for the averaged Hamiltonian. This approximation is exact up to third order because…

Perovskite oxides are already widely used in industry and have huge potential for novel device applications thanks to the rich physical behaviour displayed in these materials. The key to the functional electronic properties exhibited by…

In this article, we investigate the Variational Principle and develop thermodynamic formalism for correspondences. We define the measure-theoretic entropy for transition probability kernels and topological pressure for correspondences.…

The idea of a thermalized non-equilibrated state of matter offers a conceptually new understanding of the strong angular asymmetry. In this compact review we present some clarifications, corrections and further developments of the approach,…

By bridging graphene and benzene through a well-defined sequence of polycyclic aromatic hydrocarbons and their inherent shell structure, J. Phys. Chem. C, 2018, 122, 17526, it is shown that graphene is actually a coherent arrangement of…

We present a first-principles derivation of spatial atomic-sublevel decoherence near dielectric and metallic surfaces. The theory is based on the electromagnetic-field quantization in absorbing dielectric media. We derive an expression for…

A simple model is considered for an open system consisting of an aggregation of magnetic particles (like greigite) in the presence of a magnetic field (H), and interacting linearly with a bath of 3D harmonic oscillators. Using the…

We investigate the origin of asymmetry in the measured current-voltage (I-V) characteristics of molecules with no inherent spatial asymmetry. We establish that such molecules can exhibit asymmetric I-V characteristics due to unequal…

The Raman intensity can be well described by the famous Albrecht equation that consists of A and B terms. It is well known that the contribution from Albrecht's A term can be neglected without loss of accuracy for far off-resonant Raman…

Common intuition tells us that if one part of a connected system is cooled continuously, the other parts should also cool down. This intuition can be given a microscopic foundation for the case of a generic quantum system coupled to a…

Symmetry plays a key role in determining the physical properties of materials. By Neumann's principle, the properties of a material are invariant under the symmetry operations of the space group to which the material belongs. Continuous…

We report a theoretical calculation on the persistent currents of disordered normal-metal rings. It is shown that the diamagnetic responses of the rings in the vicinity of the zero magnetic field are attributed to multiple backward…

Quantum correlations and other phenomena characteristic to a quantum world can be understood as simply consequences of a principle derived from the postulates of Quantum Mechanics. This explanatory principle states that these phenomena…

Non-relativistic quantum mechanics was originally formulated to describe particles. Using ideas from the geometric quantization approach, we show how the concept of antiparticles can and should be introduced in the non-relativistic case…

The finite-basis, pair formulation of the Spectral Theory of chemical bonding is briefly surveyed. Solutions of the Born-Oppenheimer polyatomic Hamiltonian totally antisymmetric in electron exchange are obtained from diagonalization of an…

The aim of this work is to provide a possible philosophical motivation to the variational principles of physics in general and a possible way to unify the axiomatizations of mechanics theories. The leitmotif of this work is a dialectical…

Two statements by von Neumann and a thought-experiment by Peres prompts a discussion on the notions of one-shot distinguishability, orthogonality, semi-permeable diaphragm, and their thermodynamic implications. In the first part of the…