相关论文: The principle underlying antiaromaticity

Cononsolvency is a phenomenon for which the solubility of a macromolecule decreases or even vanishes in the mixture of two good solvents. Although it has been widely applied in physicochemical, green chemical and pharmaceutical industry,…

The hypothesis that matter is made of some ultimate and indivisible objects, together the restricted relativity principle, establishes a constraint on the kind of variables we are allowed to use for the variational description of elementary…

In this work, we present ab initio cavity QED methods which include interactions with a static magnetic field and nuclear spin degrees of freedom using different treatments of the quantum electromagnetic field. We derive explicit…

When applied to matter and antimatter states, the Pauli master equation (PME) may have two forms: time-symmetric, which is conventional, and time-antisymmetric, which is suggested in the present work. The symmetric and antisymmetric forms…

Symmetry plays a central role in many areas of modern physics. Here we show that it also underpins the dual particle and wave nature of quantum systems. We begin by noting that a classical point particle breaks translational symmetry…

The role of anharmonicity on superconductivity has often been disregarded in the past. Recently, it has been recognized that anharmonic decoherence could play a fundamental role in determining the superconducting properties (electron-phonon…

A generalized Anderson model for a magnetic impurity in an interacting one-dimensional electron gas is studied via a mapping onto a classical Coulomb gas. For weak potential scattering, the local-moment parameter regime expands as repulsive…

Quantum asymmetry is a physical resource which coincides with the amount of coherence between the eigenspaces of a generator responsible for phase encoding in interferometric experiments. We highlight an apparently counter-intuitive…

We study the response to an external perturbation of the energy levels of a disordered metallic particle, by means of the Brownian-motion model introduced by Dyson in the theory of random matrices, and reproduce the results of a recent…

Theoretical frameworks used to qualitatively and quantitatively describe nuclear dynamics in solids are often based on the harmonic approximation. However, this approximation is known to become inaccurate or to break down completely in many…

Reciprocity is a universal principle that has a profound impact on many areas of physics. A fundamental phenomenon in condensed-matter physics, optical physics and acoustics, arising from reciprocity, is the constructive interference of…

Jahn-Teller theorem, proposed in 1937, predicts a distortional instability for a molecule that has symmetry based degenerate electronic states. In 1939 Krishnan emphasized the importance of this theorem for the arrangement of water…

In algebraic quantum field theory the (inverse) temperature is shown to be a macroscopic \textit{order parameter} to parametrize mutually disjoint thermal \textit{sectors} arising from the \textit{broken scale invariance} under…

The concept of complexity appears in virtually all areas of knowledge. Its intuitive meaning shares similarities across fields, but disagreements between its details hinders a general definition, leading to a plethora of proposed…

In the search of material properties out-of-equilibrium, the non-equilibrium steady states induced by electric current are an appealing research direction where unconventional states may emerge. However, the unavoidable Joule heating caused…

Symmetry plays a crucial role in shaping the theories of fundamental forces. For example, general covariance -- the equivalence of all possible coordinate systems of spacetime -- dictates the law of gravity. Here, we extend this concept to…

We introduce the theoretical framework we use to study the bewildering variety of phases in condensed--matter physics. We emphasize the importance of the breaking of symmetries, and develop the idea of an order parameter through several…

A consistent theory, which describes the incoherent scattering of classically moving relativistic particles by the nuclei of crystal planes without any phenomenological parameter is presented. The basic notions of quantum mechanics are…

The anharmonic lattice dynamics of oxide and halide perovskites play a crucial role in their mechanical and optical properties. Raman spectroscopy is one of the key methods used to study these structural dynamics. However, despite decades…

We consider charge and thermal transport properties of magnetically active paramagnetic molecular dimer. Generic properties for both transport quantities are reduced currents in the ferro- and anti-ferromagnetic regimes compared to the…