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Based on {\em ab initio} density functional calculations, we propose $\gamma$-P and $\delta$-P as two additional stable structural phases of layered phosphorus besides the layered $\alpha$-P (black) and $\beta$-P (blue) phosphorus…

材料科学 · 物理学 2015-06-22 Jie Guan , Zhen Zhu , David Tománek

Surface resonance states are electronic states localized near the surface while remaining hybridized with bulk bands. These states can strongly modify the electric-field response of semiconductors. Here, we demonstrate using scanning…

介观与纳米尺度物理 · 物理学 2026-03-03 Dongming Zhao , Byeongin Lee , Junho Bang , Claudia Felser , Jian-Feng Ge , Doohee Cho

The objective of this work is to study the effects of charge redistribution, applied layer-normal electric fields, applied strain, and layer engineering on the band alignment of Black Phosphorus (BP)/Molybdenum disulphide (MoS2)…

材料科学 · 物理学 2022-12-28 Nupur Navlakha , Priyamvada Jadaun , Leonard F. Register , Sanjay K. Banerjee

Preceding the current interest in layered materials for electronic applications, research in the 1960's found that black phosphorus combines high carrier mobility with a fundamental band gap. We introduce its counterpart, dubbed few-layer…

介观与纳米尺度物理 · 物理学 2014-04-25 Han Liu , Adam T. Neal , Zhen Zhu , David Tomanek , Peide D. Ye

We investigate the optical absorption and transmission of few-layer phosphorene in the framework of ab initio density functional simulations and many-body perturbation theory at the level of random phase approximation. In bilayer…

介观与纳米尺度物理 · 物理学 2018-11-13 Zahra Torbatian , Reza Asgari

We investigate the electronic and optical properties of monolayer and stacking dependent bilayer blue phosphorus in the framework of density functional theory (DFT) and tight-binding approximations. We extract the hopping parameters of TB…

介观与纳米尺度物理 · 物理学 2016-07-27 Y. Mogulkoc , M. Modarresi , A. Mogulkoc , Y. O. Ciftci

The double carrier transport has been observed in thin film black phosphorus (BP) field effect transistor (FET) devices in highly electron doped region. BP thin films with typical thickness of 15 nm were encapsulated by hexagonal boron…

介观与纳米尺度物理 · 物理学 2018-11-08 Kohei Hirose , Toshihito Osada , Kazuhito Uchida , Toshihiro Taen , Kenji Watanabe , Takashi Taniguchi , Yuichi Akahama

We report measurements of the infrared optical response of thin black phosphorus under field-effect modulation. We interpret the observed spectral changes as a combination of an ambipolar Burstein-Moss (BM) shift of the absorption edge due…

Electro-optical modulators, which use an electric voltage (or an electric field) to modulate a beam of light, are essential elements in present-day telecommunication devices. Using a self-consistent tight-binding approach combined with the…

介观与纳米尺度物理 · 物理学 2019-07-24 L. L. Li , B. Partoens , W. Xu , F. M. Peeters

Two-dimensional layered materials have attracted tremendous attentions due to their extraordinary physical and chemical properties. Using first-principles calculations and Boltzmann transport theory, we give an accurate prediction of the…

介观与纳米尺度物理 · 物理学 2019-02-13 Z. Z. Zhou , H. J. Liu , D. D. Fan , G. H. Cao , C. Y. Sheng

Anisotropy describes the directional dependence of a material's properties such as transport and optical response. In conventional bulk materials, anisotropy is intrinsically related to the crystal structure, and thus not tunable by the…

材料科学 · 物理学 2017-02-10 Ting Cao , Zhenglu Li , Diana Y. Qiu , Steven G. Louie

Two-dimensional (2D) semiconducting transition metal dichalcogenides (TMDCs) and black phosphorus (BP) have beneficial electronic, optical, and physical properties at the few-layer limit. As atomically thin materials, 2D TMDCs and BP are…

材料科学 · 物理学 2016-03-30 Christopher R. Ryder , Joshua D. Wood , Spencer A. Wells , Mark C. Hersam

Black Phosphorus (BP) has gained renewed attention due to its singular anisotropic electronic and optical properties that might be exploited for a wide range of technological applications. In this respect, the thermal properties are…

材料科学 · 物理学 2017-04-20 Cesar E. P. Villegas , A. R. Rocha , Andrea Marini

Optical devices capable of suppressing diffraction nature of light are of great technological importance to many nanophotonic applications. One important technique to achieve diffractionless optics is to exploit field canalization effect.…

光学 · 物理学 2021-12-16 Po-Han Chang , Charles Lin , Amr S. Helmy

We report first principles theoretical investigations of possible metal contacts to monolayer black phosphorus (BP). By analyzing lattice geometry, five metal surfaces are found to have minimal lattice mismatch with BP: Cu(111), Zn(0001),…

介观与纳米尺度物理 · 物理学 2015-02-03 Kui Gong , Lei Zhang , Wei Ji , Hong Guo

We report a scalable approach to synthesize a large-area (up to 4 mm) thin black phosphorus (BP) film on a flexible substrate. We first deposited a red phosphorus (RP) thin-film on a flexible polyester substrate, followed by its conversion…

Vertical integration of two-dimensional materials has recently emerged as an exciting method for the design of novel electronic and optoelectronic devices. Using density functional theory, we investigatethe structural and electronic…

材料科学 · 物理学 2015-06-25 Yongqing Cai , Gang Zhang , Yong-Wei Zhang

The competition between the electron-hole Coulomb attraction and the three-dimensional dielectric screening dictates the optical properties of layered semiconductors. In low-dimensional materials, the equilibrium dielectric environment can…

Wave polarization contains valuable information for electromagnetic signal processing and the ability to manipulate it can be extremely useful in photonic devices. In this work, we propose designs comprised of one of the emerging and…

Black phosphorous is a layered material having a high capacity of 2596 mAh/g as a battery electrode, however it suffers from cracking due to high volume expansion during lithiation. These cracks causes loss of electrical contact in the…

材料科学 · 物理学 2020-07-21 Burak Ozdemir