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Isolated hydrogen atoms absorbed on graphene are predicted to induce magnetic moments. Here we demonstrate that the adsorption of a single hydrogen atom on graphene induces a magnetic moment characterized by a ~20 meV spin-split state at…

Atomic vacancies have a strong impact in the mechanical, electronic and magnetic properties of graphene-like materials. By artificially generating isolated vacancies on a graphite surface and measuring their local density of states on the…

介观与纳米尺度物理 · 物理学 2015-05-18 M. M. Ugeda , I. Brihuega , F. Guinea , J. M. Gomez-Rodriguez

The remarkable electronic properties of graphene have fueled the vision of a graphene-based platform for lighter, faster and smarter electronics and computing applications. One of the challenges is to devise ways to tailor its electronic…

Predictions state that graphene can spontaneously develop magnetism from the Coulomb repulsion of its $\pi$-electrons, but its experimental verification has been a challenge. Here, we report on the observation and manipulation of individual…

介观与纳米尺度物理 · 物理学 2019-01-15 Jingcheng Li , Sofia Sanz , Martina Corso , Deung Jang Choi , Diego Peña , Thomas Frederiksen , Jose Ignacio Pascual

We investigate the details of the electronic structure in the neighborhoods of a carbon atom vacancy in graphene by employing magnetization-constrained density-functional theory on periodic slabs, and spin-exact, multi-reference,…

材料科学 · 物理学 2013-11-27 M. Casartelli , S. Casolo , G. F. Tantardini , R. Martinazzo

The pristine graphene is strongly diamagnetic. However, graphene with single carbon atom defects could exhibit paramagnetism with local magnetic moments ~ 1.5 per vacancy1-6. Theoretically, both the electrons and electrons of graphene…

材料科学 · 物理学 2017-02-13 Yu Zhang , Si-Yu Li , Wen-Tian Li , Jia-Bin Qiao , Wen-Xiao Wang , Long-Jin Yin , Lin He

One intriguing finding in graphene is the vacancy-induced magnetism that highlights the interesting interaction between local magnetic moments and conduction electrons. Within density functional theory, the current understanding of the…

材料科学 · 物理学 2014-07-03 Chi-Cheng Lee , Yukiko Yamada-Takamura , Taisuke Ozaki

Graphene nanoflakes are interesting because electrons are naturally confined in these quasi-zero-dimensional structures, whereas confinement in bulk graphene would require a band gap. Vacancies inside the graphene lattice lead to localized…

介观与纳米尺度物理 · 物理学 2015-04-06 Matthias Droth , Guido Burkard

We study the magnetic properties in the vicinity of a single carbon defect in a monolayer of graphene. We include the unbound $\sigma$ orbital and the vacancy induced bound $\pi$ state in an effective two-orbital single impurity model. The…

介观与纳米尺度物理 · 物理学 2018-04-25 Daniel May , Po-Wei Lo , Kira Deltenre , Anika Henke , Jinhai Mao , Yuhang Jiang , Guohong Li , Eva Y. Andrei , Guang-Yu Guo , Frithjof B. Anders

The electrostatic confinement of massless charge carriers is hampered by Klein tunneling. Circumventing this problem in graphene mainly relies on carving out nanostructures or applying electric displacement fields to open a band gap in…

Magnetic properties of a single vacancy in graphene is a relevant and still unsolved problem. The experimental results point to a clearly detectable magnetic defect state at the Fermi energy, while several calculations based on density…

介观与纳米尺度物理 · 物理学 2017-10-11 A. M. Valencia , M. J. Caldas

Magnetic properties of a single vacancy in graphene is a relevant and still much discussed problem. The experimental results point to a clearly detectable magnetic defect state at the Fermi energy, while calculations based on density…

介观与纳米尺度物理 · 物理学 2017-10-31 Ana M. Valencia , Marilia J. Caldas

The correlation between structural distortion and emergence of magnetism in graphene containing a single vacancy was investigated using first-principles calculations based on density functional theory (DFT). Our results have shown that a…

介观与纳米尺度物理 · 物理学 2015-06-12 Wendel S. Paz , Wanderlã L. Scopel , Jair C. C. Freitas

We report a strain-controlled tuning of magnetism in transition-metal-atom-decorated graphene. Our first-principles calculations demonstrate that strain can lead to a sudden change in the magnetic configuration of a transition metal (TM)…

介观与纳米尺度物理 · 物理学 2011-08-09 Bing Huang , Jaejun Yu , Su-Huai Wei

Vacancies in graphene lead to the appearance of localized electronic states with non-vanishing spin moments. Using a mean-field Hubbard model and an effective double-quantum dot description we investigate the influence of strain on…

介观与纳米尺度物理 · 物理学 2016-02-17 Daniel Midtvedt , Alexander Croy

By applying tight binding model of adatoms in graphene, we study theoretically the localized aspects of the interaction between transition metal atoms and graphene. Considering the electron-electron interaction by adding a Hubbard term in…

强关联电子 · 物理学 2018-06-14 F. Escudero , J. S. Ardenghi , L. Sourrouille , P. Jasen , A. Juan

The electronic structure, bonding and magnetism in graphene containing vacancies are studied using density-functional methods. The single-vacancy graphene ground state is spin polarized and structurally flat. The unpolarized state is non…

介观与纳米尺度物理 · 物理学 2008-07-11 M. W. C. Dharma-wardana , Marek Z. Zgierski

Each single hydrogen vacancy created at the surface of graphane gives rise to a local unpaired spin. For domains of hydrogen vacancies the situation is, however complex and depends on the size and geometry of domains, as well as whether the…

材料科学 · 物理学 2010-05-20 Hasan Sahin , Can Ataca , Salim Ciraci

We study from first principles the magnetism in graphene induced by single carbon atom defects. For two types of defects considered in our study, the hydrogen chemisorption defect and the vacancy defect, the itinerant magnetism due to the…

材料科学 · 物理学 2007-05-23 Oleg V. Yazyev , Lothar Helm

Introducing quantum confinement has uncovered a rich set of interesting quantum phenomena and allows one to directly probe the physics of confined (quasi-)particles. In most experiments, however, electrostatic potential is the only…

介观与纳米尺度物理 · 物理学 2024-03-08 Ya-Ning Ren , Yu-Chen Zhuang , Qing-Feng Sun , Lin He
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