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The magnetism of single atoms and molecules is governed by the atomic scale environment. In general, the reduced symmetry of the surrounding splits the $d$ states and aligns the magnetic moment along certain favorable directions. Here, we…

介观与纳米尺度物理 · 物理学 2015-11-30 Benjamin W. Heinrich , Lukas Braun , Jose I. Pascual , Katharina J. Franke

Single magnetic atoms or molecules with large single-ion magnetic anisotropy are highly desired for future applications in high-density data storage and quantum computation. Here we have synthesized an Fe-porphyrin complex on Au(111)…

介观与纳米尺度物理 · 物理学 2017-07-19 Bing Liu , Huixia Fu , Jiaqi Guan , Bin Shao , Sheng Meng , Jiandong Guo , Weihua Wang

The origin of magnetic anisotropy in magnetic compounds is a longstanding issue in solid state physics and nonmagnetic ligand ions are considered to contribute little to magnetic anisotropy. Here, we introduce the concept of ligand driven…

One-dimensional metal-organic chains often possess a complex magnetic structure susceptible to be modified by a alteration of their chemical composition. The possibility to tune their magnetic properties provides an interesting playground…

Single-ion magnetic anisotropy in molecular magnets leads to spin flip excitations that can be measured by inelastic scanning tunneling microscope (STM) spectroscopy. Here I present a semi ab initio scheme to compute the spectral features…

介观与纳米尺度物理 · 物理学 2018-08-16 David Jacob

Single-ion lanthanide-organic complexes can provide stable magnetic moments with well-defined orientation for spintronic applications on the atomic level. Here, we show by a combined experimental approach of scanning tunneling microscopy…

The oxidation and spin state of a metal-organic molecule determine its chemical reactivity and magnetic properties. Here, we demonstrate the reversible control of the oxidation and spin state in a single Fe-porphyrin molecule in the force…

The cubic lattice symmetry of ferromagnetic homogeneously disordered alloys is when a compositional modulation is imposed. This can have a profound influence on the magnetocrystalline anisotropy energy (MAE). We describe our ab-initio…

材料科学 · 物理学 2007-05-23 S. S. A. Razee , J. B. Staunton , B. Ginatempo , F. J. Pinski , E. Bruno

Perpendicular magnetic anisotropy was found to be highly sensitive to the nominal thickness and morphology of laterally heterogeneous CoPd films in the vicinity of the metal insulator transition. We used the effect to tune the anisotropy by…

材料科学 · 物理学 2022-05-04 Gregory Kopnov , Alexander Gerber

The transport properties of a large-spin molecule strongly coupled to ferromagnetic leads in the presence of transverse magnetic anisotropy are studied theoretically. The relevant spectral functions, linear-response conductance and the…

介观与纳米尺度物理 · 物理学 2015-11-13 Maciej Misiorny , Ireneusz Weymann

We theoretically analyze the influence of chemical disorder on magnetic anisotropy in Ge_{1-x}Mn_{x}Te semiconductor layers known to exhibit carrier-induced ferromagnetism and ferroelectric distortion of rhombohedral crystal lattice. Using…

材料科学 · 物理学 2015-11-30 A. Łusakowski , P. Bogusławski , T. Story

The structural and magnetic properties of Fe octaethylporphyrin (OEP) molecules on Cu(001) have been investigated by means of density functional theory (DFT) methods and X-ray absorption spectroscopy. The molecules have been adsorbed on the…

Understanding and controlling the interfacial magnetic properties of ferromagnetic thin films are crucial for spintronic device applications. However, using conventional magnetometry, it is difficult to detect them separately from the bulk…

材料科学 · 物理学 2017-06-21 Le Duc Anh , Noboru Okamoto , Munetoshi Seki , Hitoshi Tabata , Masaaki Tanaka , Shinobu Ohya

A misalignment of anisotropic crystallites causes small values of anisotropy and decreases the critical current density of textured polycrystalline superconductors. To relate the crystallite misalignment and out-plane anisotropy, the…

超导电性 · 物理学 2023-07-10 D. M. Gokhfeld , S. V. Semenov , M. I. Petrov , I. V. Nemtsev , D. A. Balaev

Controlling magnetic anisotropy is a key requirement for the fundamental understanding of molecular magnetism and is a prerequisite for numerous applications in magnetic storage, spintronics, and all-spin logic devices. In order to address…

Magnetic axis rotation (MAR) in ferromagnetic (FM) layers is crucial for strain-mediated converse magnetoelectric coupling. Employing the density functional theory (DFT), we computationally study the magnetic anisotropy of selected deformed…

材料科学 · 物理学 2022-12-02 Zefeng Cai , Ben Xu

Magnetic anisotropy phenomena in bimetallic antiferromagnets Mn$_2$Au and MnIr are studied by first-principles density functional theory calculations. We find strong and lattice-parameter dependent magnetic anisotropies of the ground state…

Magnetic anisotropy is one of the important factors in determining magnetic structures. A type of magnetic anisotropy is closely related to the symmetry of crystals. We theoretically investigate magnetic anisotropy and its related magnetic…

强关联电子 · 物理学 2024-05-22 Akane Inda , Satoru Hayami

We have constructed an analytic formula to treat the perpendicular magnetic anisotropy energy in ferromagnetic metals with low symmetry, such as C4V and C3V. We find that the anisotropy energy is proportional to a part of the expectation…

材料科学 · 物理学 2019-03-27 Yoshishige Suzuki , Shinji Miwa

Perpendicular magnetic anisotropy of the new ferromagnetic semiconductor (Ba,K)(Zn,Mn)$_{2}$As$_{2}$ is studied by angle-dependent x-ray magnetic circular dichroism measurements. The large magnetic anisotropy with the anisotropy field of…

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