相关论文: Nonrelativistic energy levels of helium atom
The helium ground state nonrelativistic energy with 24 significant digits is presented. The calculations are based on variational expansion with randomly chosen exponents. This data can be used as a benchmark for other approaches for many…
Considering the nuclear motion, the authors give out the nonrelativistic ground energy of a helium atom by using a simple but effective variational wave function with a flexible parameter $k$. Based on this result, the relativistic and…
The $m \alpha^6$ correction to energy is expressed in terms of an effective Hamiltonian $H^{(6)}$ for an arbitrary state of helium. Numerical calculations are performed for $n=2$ levels, and the previous result for the $2^3P$ centroid is…
The nonrelativistic energy of low lying rovibrational levels of HT, DT, and \T\ is determined to an absolute accuracy of $10^{-7}-10^{-8}$ cm$^{-1}$ using the variational method with the four-body nonadiabatic James-Coolidge functions. The…
Energy levels of the $1sns$ and $1snp$ states of ions along the helium isoelectronic sequence from carbon to uranium are calculated, with $n=3$-$7$. The computation is performed within the relativistic configuration-interaction method,…
Highly precise variational calculations of non-relativistic energies of the (2p^2)^3P^e state of Helium atom are presented.We get an upper bound energy E=-0.71050015565678 a.u.,the lowest yet obtained.
The technique of quantum electrodynamics (QED) calculations of energy levels in the helium atom is reviewed. The calculations start with the solution of the Schr\"odinger equation and account for relativistic and QED effects by perturbation…
We present a new computational method for the determination of energy levels in four-particle systems like H$_2$, HD, and HeH$^+$ using explicitly correlated exponential basis functions and analytic integration formulas. In solving the…
We calculate the energies of ground and three low lying excited states of confined helium atom centered in an impenetrable spherical box. We perform the calculation by employing variational method with two-parameter variational forms for…
Accurate predictions for hydrogen molecular levels require the treatment of electrons and nuclei on an equal footing. While nonrelativistic theory has been effectively formulated this way, calculation of relativistic and quantum…
Using singlet S states of the helium atom as an example, I describe precise calculation of energy levels in few-electron atoms. In particular, a complete set of effective operators is derived which generates O(m*alpha^6) relativistic and…
It is shown that the non-relativistic ground state energy of helium-like and lithium-like ions with static nuclei can be interpolated in full physics range of nuclear charges $Z$ with accuracy of not less than 6 decimal digits (d.d.) or 7-8…
On the basis of variational method we study energy levels of pionic helium $(\pi-e-He)$ and kaonic helium $(K-e-He)$ with an electron in ground state and a meson in excited state with principal and orbital quantum numbers $n\sim l+1\sim…
Recent experiments on the laser-induced resonant annihilation provide a precise measurement of transition energies of antiprotonic helium atoms. Relativistic corrections of an order of $\alpha ^2$ to the pure Coulomb interaction will be…
Rigorous quantum electrodynamical calculation is presented for energy levels of the 1^1S, 2^1S, 2^3S, 2^1P_1, and 2^3P_{0,1,2} states of helium-like ions with the nuclear charge Z=3...12. The calculational approach accounts for all…
The total energies and various bound state properties of the excited $2^1S(L = 0)-$states in two-electron helium atoms, including the ${}^{\infty}$He, ${}^4$He and ${}^3$He atoms, are determined to very high numerical accuracy. The…
The energetically lowest five states of a helium atom are: He($1^1S$), He($2^3S$), He($2^1S$), He($2^3P$), and He($2^1P$). Long-range interaction coefficients $C_3$, $C_6$, $C_8$, $C_9$, and $C_{10}$ for all $S-S$ and $S-P$ pairs of these…
The hydrogen plasma is studied at temperatures T ~ 10^4 - 10^6 K using the free energy minimization method. A simple analytic free energy model is proposed which is accurate at densities up to 1 g/cc and yields convergent internal partition…
The practical usefulness of Relativistic Schr\"odinger Theory (RST) is tested by calculating approximately the energy difference between the excited singlet state $1s2s {}^1S_0$ and the ground state $1s^2 {}^1S_0$ of the helium-like ions…
We perform quantum electrodynamic calculations of the ionization energy of the $1s3d$ states of the $^4$He atom, including a complete evaluation of the $m\alpha^6$ correction. We find a large contribution from the nonradiative part of this…